scholarly journals Granite Hydrolysis to Form Deep Brines

Energies ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 2180 ◽  
Author(s):  
Patrick Brady ◽  
Carlos Lopez ◽  
Dave Sassani
Keyword(s):  
Water Availability ◽  
High Salinity ◽  
Reaction Path ◽  
End Point ◽  
Diffusion Limited ◽  
Pitzer Coefficients ◽  
Precise Analysis ◽  
Silicate Dissolution ◽  
Explicit Consideration ◽  
Compositional Variations

Reaction path calculations suggest that water fixation by zeolite and chlorite formation can account for much of the high salinity of deep brines in contact with deep granites, as well as their Ca/Na ratios, which reflect the rock-dominated chemistry of such brines. Resultant brines, undiluted by the influx of shallower fresher waters, are likely to be at equilibrium with laumontite, chlorite, calcite, dolomite, anhydrite/gypsum, K-feldspar, quartz, plagioclase, and possibly halite. The growth of laumontite and chlorite consumes water, causing the concentration of residual salts to increase during the formation of such brines. In these analyses, the major trends suggest that these fundamental processes drive this outcome naturally. Predicted phase assemblages and end-point water compositions are relatively unaffected by the chemistry of the starting/reacting fluid. Additionally, mineralogical and mineral compositional variations both appear to have no major impact on brine formational trends. More precise analysis involves the use of Pitzer coefficients and considers Br/Cl exchange in the alteration phases. Explicit consideration of silicate dissolution points to water availability as a key control over granite alteration. Diffusion-limited water availability appears to lead to stagnant systems dominated by the increasing brine density and Ca/Na ratios with depth. Alteration phases tend to decrease permeability and porosity, further isolating such systems from the flow of shallower dilute fluids.

scholarly journals Biotechnological Applications Derived from Microorganisms of the Atacama Desert

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Armando Azua-Bustos ◽  
Carlos González-Silva
Keyword(s):  
Water Availability ◽  
High Salinity ◽  
Atacama Desert ◽  
Biotechnological Applications ◽  
Analog Model ◽  
The Past ◽  
Basic Understanding ◽  
Domains Of Life ◽  
Immense Potential

The Atacama Desert in Chile is well known for being the driest and oldest desert on Earth. For these same reasons, it is also considered a good analog model of the planet Mars. Only a few decades ago, it was thought that this was a sterile place, but in the past years fascinating adaptations have been reported in the members of the three domains of life: low water availability, high UV radiation, high salinity, and other environmental stresses. However, the biotechnological applications derived from the basic understanding and characterization of these species, with the notable exception of copper bioleaching, are still in its infancy, thus offering an immense potential for future development.

Use of 2½ D imaging in analysis of NiTi martensite

1978 ◽  
Vol 36 (1) ◽  
pp. 610-611
Author(s):  
G. M. Michal
Keyword(s):  
Memory Effect ◽  
Monoclinic Phase ◽  
Reaction Path ◽  
Structural Characteristics ◽  
Salient Feature ◽  
Martensite Phase ◽  
Orientation Relationships ◽  
Low Symmetry ◽  
Hydride Phases ◽  
Unusual Shape

Several TEM investigations have attempted to correlate the structural characteristics to the unusual shape memory effect in NiTi, the consensus being the essence of the memory effect is ostensible manifest in the structure of NiTi transforming martensitic- ally from a B2 ordered lattice to a low temperature monoclinic phase. Commensurate with the low symmetry of the martensite phase, many variants may form from the B2 lattice explaining the very complex transformed microstructure. The microstructure may also be complicated by the enhanced formation of oxide or hydride phases and precipitation of intermetallic compounds by electron beam exposure. Variants are typically found in selfaccommodation groups with members of a group internally twinned and the twins themselves are often observed to be internally twinned. Often the most salient feature of a group of variants is their close clustering around a given orientation. Analysis of such orientation relationships may be a key to determining the nature of the reaction path that gives the transformation its apparently perfect reversibility.

Microdomains in BaFeO3-y (0.35 < y < 0.50)

1990 ◽  
Vol 48 (4) ◽  
pp. 780-781
Author(s):  
M. Vallet-Regí ◽  
M. Parras ◽  
J.M. González-Calbet ◽  
J.C. Grenier
Keyword(s):  
Electron Diffraction ◽  
Chemical Analysis ◽  
Monoclinic Phase ◽  
Orthorhombic Phase ◽  
Total Iron ◽  
Zone Axis ◽  
Electron Micrograph ◽  
X Ray Diffraction ◽  
X Ray ◽  
Compositional Variations

BaFeO3-y compositions (0.35<y<0.50) have been investigated by means of electron diffraction and microscopy to resolve contradictory results from powder X-ray diffraction data.The samples were obtained by annealing BaFeO2.56 for 48 h. in the temperature range from 980°C to 1050°C . Total iron and barium in the samples were determined using chemical analysis and gravimetric methods, respectively.In the BaFeO3-y system, according to the electron diffraction and microscopy results, the nonstoichiometry is accommodated in different ways as a function of the composition (y):In the domain between BaFeO2.5+δBaFeO2.54, compositional variations are accommodated through the formation of microdomains. Fig. la shows the ED pattern of the BaFeO2.52 material along thezone axis. The corresponding electron micrograph is seen in Fig. 1b. Several domains corresponding to the monoclinic BaFeO2.50 phase, intergrow with domains of the orthorhombic phase. According to that, the ED pattern of Fig. 1a, can be interpreted as formed by the superposition of three types of diffraction maxima : Very strong spots corresponding to a cubic perovskite, a set of maxima due to the superposition of three domains of the monoclinic phase along [100]m and a series of maxima corresponding to three domains corresponding to the orthorhombic phase along the [100]o.

End Point

2020 ◽  
Author(s):  
Keyword(s):  
End Point

Settler Colonialism and the Revolutionary War

2019 ◽  
Vol 41 (4) ◽  
pp. 7-35
Author(s):  
Andrea Lynn Smith
Keyword(s):  
New York ◽  
Settler Colonialism ◽  
Revolutionary War ◽  
The State ◽  
The Public ◽  
150Th Anniversary ◽  
End Point ◽  
Indian Land ◽  
Indian Relations ◽  
Major General

The centerpiece of New York State’s 150th anniversary of the Sullivan Expedition of 1779 was a pageant, the “Pageant of Decision.” Major General John Sullivan’s Revolutionary War expedition was designed to eliminate the threat posed by Iroquois allied with the British. It was a genocidal operation that involved the destruction of over forty Indian villages. This article explores the motivations and tactics of state officials as they endeavored to engage the public in this past in pageant form. The pageant was widely popular, and served the state in fixing the expedition as the end point in settler-Indian relations in New York, removing from view decades of expropriations of Indian land that occurred well after Sullivan’s troops left.

Impact of water availability on winter wheat ( Triticum aestivum L.) yield characteristics

2010 ◽  
Vol 59 (1) ◽  
pp. 151-156 ◽  
Author(s):  
H. Klupács ◽  
Á. Tarnawa ◽  
I. Balla ◽  
M. Jolánkai
Keyword(s):  
Winter Wheat ◽  
Water Supply ◽  
Water Availability ◽  
Grain Quality ◽  
Physiological Condition ◽  
Triticum Aestivum L ◽  
Annual Precipitation ◽  
Average Depth ◽  
Experimental Site ◽  
Yield Quality

Water supply of crop plants is the most essential physiological condition influencing quality and quantity performance of grain yield. In a 12-year experimental series of winter wheat agronomic trials run at the Nagygombos experimental site (Hungary) the effect of water availability has been studied. The location represents the typical average lowland conditions of the country, the annual precipitation of the experimental site belonging to the 550–600 mm belt of the Northern edges of the Great Hungarian Plain, while the average depth of groundwater varies between 2 to 3 metres. Crop years with various precipitation patterns have had different impacts on crop yield quality and quantity. Yield figures were in positive correlation with annual precipitation in general. Water availability had diverse influence on quality manifestation. Good water supply has often resulted in poorer grain quality, especially wet gluten and Hagberg values have been affected by that. Drought reduced the amount of yield in general, but contributed to a better quality manifestation in some of the crop years.

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