scholarly journals Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles

Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 4014 ◽  
Author(s):  
Abubakr Ayub ◽  
Costante M. Invernizzi ◽  
Gioele Di Marcoberardino ◽  
Paolo Iora ◽  
Giampaolo Manzolini

This study aims to provide a thermodynamic comparison between supercritical CO2 cycles and ORC cycles utilizing flue gases as waste heat source. Moreover, the possibility of using CO2 mixtures as working fluids in transcritical cycles to enhance the performance of the thermodynamic cycle is explored. ORCs operating with pure working fluids show higher cyclic thermal and total efficiencies compared to supercritical CO2 cycles; thus, they represent a better option for high-temperature waste heat recovery provided that the thermal stability at a higher temperature has been assessed. Based on the improved global thermodynamic performance and good thermal stability of R134a, CO2-R134a is investigated as an illustrative, promising working fluid mixture for transcritical power cycles. The results show that a total efficiency of 0.1476 is obtained for the CO2-R134a mixture (0.3 mole fraction of R134a) at a maximum cycle pressure of 200 bars, which is 15.86% higher than the supercritical carbon dioxide cycle efficiency of 0.1274, obtained at the comparatively high maximum pressure of 300 bars. Steam cycles, owing to their larger number of required turbine stages and lower power output, did not prove to be a suitable option in this application.

2013 ◽  
Vol 136 (1) ◽  
Author(s):  
Saeb M. Besarati ◽  
D. Yogi Goswami

A number of studies have been performed to assess the potential of using supercritical carbon dioxide (S-CO2) in closed-loop Brayton cycles for power generation. Different configurations have been examined among which recompression and partial cooling configurations have been found very promising, especially for concentrating solar power (CSP) applications. It has been demonstrated that the S-CO2 Brayton cycle using these configurations is capable of achieving more than 50% efficiency at operating conditions that could be achieved in central receiver tower type CSP systems. Although this efficiency is high, it might be further improved by considering an appropriate bottoming cycle utilizing waste heat from the top S-CO2 Brayton cycle. The organic Rankine cycle (ORC) is one alternative proposed for this purpose; however, its performance is substantially affected by the selection of the working fluid. In this paper, a simple S-CO2 Brayton cycle, a recompression S-CO2 Brayton cycle, and a partial cooling S-CO2 Brayton cycle are first simulated and compared with the available data in the literature. Then, an ORC is added to each configuration for utilizing the waste heat. Different working fluids are examined for the bottoming cycles and the operating conditions are optimized. The combined cycle efficiencies and turbine expansion ratios are compared to find the appropriate working fluids for each configuration. It is also shown that combined recompression-ORC cycle achieves higher efficiency compared with other configurations.


Energies ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5886
Author(s):  
Xinxing Lin ◽  
Chonghui Chen ◽  
Aofang Yu ◽  
Likun Yin ◽  
Wen Su

To efficiently recover the waste heat of mobile engine, two advanced transcritical power cycles, namely split cycle and dual pressure cycle, are employed, based on the recuperative cycle. Performances of the two cycles are analyzed and compared through the development of thermodynamic models. Under given gas conditions, seven high-temperature working fluids, namely propane, butane, isobutane, pentane, isopentane, neopentane, and cyclopentane, are selected for the two cycles. At the design system parameters, the highest work 48.71 kW, is obtained by the split cycle with butane. For most of fluids, the split cycle has a higher work than the dual pressure cycle. Furthermore, with the increase of turbine inlet pressure, net work of the split cycle goes up firstly and then decreases, while the work of dual pressure cycle increases slowly. For the split cycle, there exists a split ratio to get the maximum network. However, for the dual pressure cycle, the larger the evaporation temperature, the higher the net work. On this basis, system parameters are optimized by genetic algorithm to maximize net work. The results indicate that the highest work 49.96 kW of split cycle is obtained by pentane. For the considered fluids, except cyclopentane, split cycle always has a higher work than dual pressure cycle. Due to the higher net work and fewer system components, split cycle is recommended for the engine waste heat recovery.


Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 370 ◽  
Author(s):  
Giovanni Manente ◽  
Mário Costa

The supercritical CO2 power cycle (s-CO2) is receiving much interest in the utilization of waste heat sources in the medium-to-high temperature range. The low compression work and highly regenerative layout result in high thermal efficiencies, even at moderate turbine inlet temperatures. The capability of heat extraction from the waste heat source is, however, limited because the heat input takes place over a limited temperature range close to the maximum cycle temperature. Accordingly, novel s-CO2 layouts have been recently proposed, aimed at increasing the heat extraction from the heat source while preserving as much as possible the inherently high thermal efficiency. Among these, the most promising ones feature dual expansion, dual recuperation, and partial heating. This work concentrates on the conceptual design of these novel s-CO2 layouts using a systematic approach based on the superimposition of elementary thermodynamic cycles. The overall structure of the single flow split with dual expansion (also called cascade), partial heating, and dual recuperated cycles is decomposed into elementary Brayton cycles to identify the building blocks for the achievement of a high performance in the utilization of waste heat sources. A thermodynamic optimization is set up to compare the performance of the three novel layouts for utilization of high temperature waste heat at 600 °C. The results show that the single flow split with a dual expansion cycle provides 3% and 15% more power compared to the partial heating and dual recuperated cycles, respectively, and 40% more power compared to the traditional single recuperated cycle used as the baseline. The separate evaluation of thermal efficiency and heat recovery effectiveness shows the main reasons behind the achievement of the highest performance, which are peculiar to each novel layout.


Author(s):  
Saeb M. Besarati ◽  
D. Yogi Goswami

A number of studies have been performed to assess the potential of using supercritical carbon dioxide (S-CO2) in closed-loop Brayton cycles for power generation. Different configurations have been examined among which recompression and partial cooling configurations have been found very promising, especially for concentrating solar power (CSP) applications. It has been demonstrated that the S-CO2 Brayton cycle using these configurations is capable of achieving more than 50% efficiency at operating conditions that could be achieved in central receiver tower type CSP systems. Although this efficiency is high, it might be further improved by considering an appropriate bottoming cycle utilizing waste heat from the top S-CO2 Brayton cycle. The organic Rankine cycle (ORC) is one alternative proposed for this purpose, however, its performance is substantially affected by the selection of the working fluid. In this paper, a simple S-CO2 Brayton cycle, a recompression S-CO2 Brayton cycle, and a partial cooling S-CO2 Brayton cycle are first simulated and compared with the available data in the literature. Then, an ORC is added to each configuration for utilizing the waste heat. Different working fluids are examined for the bottoming cycles and the operating conditions are optimized. The combined cycle efficiencies and turbine expansion ratios are compared to find the appropriate working fluids for each configuration. It is also shown that combined recompression-ORC cycle achieves higher efficiency compared with other configurations.


2020 ◽  
Vol 71 (1) ◽  
pp. 113-121
Author(s):  
Alexandru Racovitza ◽  
Horatiu Pop ◽  
Valentin Apostol ◽  
Tudor Prisecaru ◽  
Daniel Taban

The present works deals with waste heat recovery from internal combustion engines using Rankine cycle systems where working fluid are organic liquids (ORC). The first part of the paper presents the ORC technology as one of the most suitable procedure for waste heat recovery from exhaust gas of internal combustion engine (ICE). The particular engine considered in the present work is a turbocharged compression ignition engine mounted on an experimental setup. The working fluids for ORC system are: isobutene, propane, RE245fa2, RE245cb2, R245fa, R236fa, R365mfc, R1233zd(E), R1234yf and R1234ze(Z). Experimental data derived from the experimental setup has been used for 40%, 55% and 70% engine load. This papers focusses on superheating increment, on thermal efficiency and on net power output, obtained with each working fluids in Rankine cycle. Results point out the superheating increment that gives the highest thermal efficiency for each working fluid. The highest thermal efficiency is achieved in case of using R1233zd(E) as working fluid. In case of using R1233zd(E) as working fluid at 40 % load of the engine, the output power of the Rankine cycle is 3.6 kW representing 6.2 %, from the rated power at this load; at 55% load it is 5.7 kW representing 6.7 % the rated power and at 70% it is 6.7 kW representing 6.5 % from the rated power. Future perspectives are given.


Author(s):  
Derek Young ◽  
Spencer C. Gibson ◽  
Todd M. Bandhauer

Abstract Low grade waste heat recovery presents an opportunity to utilize typically wasted energy to reduce overall energy consumption and improve system efficiencies. In this work, the technoeconomic performance of a turbocompression cooling system (TCCS) driven by low grade waste heat in the engine coolant of a large marine diesel generator set is investigated. Five different working fluids were examined to better understand the effects of fluid characteristics on system performance: R134a, R245fa, R1234ze(E), R152a, and R600a. A coupled thermodynamic, heat exchanger, and economic simulation was developed to calculate the simple payback period of the waste heat recovery system, which was minimized using a search and find optimization routine with heat exchanger effectiveness as the optimization parameter. A sensitivity study was performed to understand which heat exchanger effectiveness had the largest impact on payback period. Of the five working fluids examined, a TCCS with R152a as the working fluid had the lowest payback period of 1.46 years with an initial investment of $181,846. The R152a system was most sensitive to the two-phase region of the power cycle condenser. The R1234ze(E) system provided the largest return on investment over a ten year lifetime of $1,399,666.


2020 ◽  
Vol 197 ◽  
pp. 06023
Author(s):  
Antonio Mariani ◽  
Biagio Morrone ◽  
Maria Vittoria Prati ◽  
Andrea Unich

Waste heat recovery can be a key solution for improving the efficiency of energy conversion systems. Organic Rankine Cycles (ORC) are a consolidated technology for achieving such target, ensuring good efficiencies and flexibility. ORC systems have been mainly adopted for stationary applications, where the limitations of layout, size and weight are not stringent. In road transportation propulsion systems, the integration between the powertrain and the ORC system is difficult but still possible. The authors investigated an ORC system bottoming a spark ignited internal combustion engine (ICE) powering a public transport bus. The bus, fuelled by natural gas, was tested in real driving conditions. Exhaust gas mass flow rate and temperature have been measured for calculating the thermal power to be recovered in the ORC plant. The waste heat was then used as energy input in a model simulating the performance of an ORC system. The heat transfer between the exhaust gases and the ORC fluid is crucial for the ORC performance. For this reason, attention was paid to considering the interaction between hot fluid temperature and ORC maximum pressure. ORC performance in terms of real cycle efficiency and power produced were calculated considering n-Pentane as working fluid. The fuel consumption was reduced from 271.5 g/km to 261.4 g/km over the driving cycle, corresponding to 3.7% reduction.


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