scholarly journals Diachronous Redistribution of Hf and Nd Isotopes at the Crystal Scale—Consequences for the Isotopic Evolution of a Poly-Metamorphic Crustal Terrane

Geosciences ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 36
Author(s):  
Adrien Vezinet ◽  
Emilie Thomassot ◽  
Yan Luo ◽  
Chiranjeeb Sarkar ◽  
D. Graham Pearson
Keyword(s):  
Metamorphic Rocks ◽  
Nd Isotopes ◽  
Nd Isotope ◽  
Isotopic Evolution ◽  
Metamorphic Terrane ◽  
O Isotope ◽  
Pt Path ◽  
Hand Specimen ◽  
North Atlantic Craton

In metamorphic rocks, mineral species react over a range of pressure–temperature conditions that do not necessarily overlap. Mineral equilibration can occur at varied points along the metamorphic pressure–temperature (PT) path, and thus at different times. The sole or dominant use of zircon isotopic compositions to constrain the evolution of metamorphic rocks might then inadvertently skew geological interpretations towards one aspect or one moment of a rock’s history. Here, we present in-situ U–Pb/Sm–Nd isotope analyses of the apatite crystals extracted from two meta-igneous rocks exposed in the Saglek Block (North Atlantic craton, Canada), an Archean metamorphic terrane, with the aim of examining the various signatures and events that they record. The data are combined with published U–Pb/Hf/O isotope compositions of zircon extracted from the same hand-specimens. We found an offset of nearly ca. 1.5 Gyr between U-Pb ages derived from the oldest zircon cores and apatite U–Pb/Sm–Nd isotopic ages, and an offset of ca. 200 Ma between the youngest zircon metamorphic overgrowths and apatite. These differences in metamorphic ages recorded by zircon and apatite mean that the redistribution of Hf isotopes (largely hosted in zircon) and Nd isotopes (largely hosted in apatite within these rocks), were not synchronous at the hand-specimen scale (≤~0.001 m3). We propose that the diachronous redistribution of Hf and Nd isotopes and their parent isotopes was caused by the different PT conditions of growth equilibration between zircon and apatite during metamorphism. These findings document the latest metamorphic evolution of the Saglek Block, highlighting the role played by intra-crustal reworking during the late-Archean regional metamorphic event.

Understanding the role of accessory minerals in the Sm-Nd isotopic evolution of ancient rocks: An in-situ LA-(MC)-ICP-MS approach

2020 ◽  
Author(s):  
Johannes Hammerli
Keyword(s):  
Hf Isotope ◽  
Nd Isotope ◽  
Accessory Minerals ◽  
Icp Ms ◽  
Isotopic Evolution ◽  
Magma Sources ◽  
Mantle Reservoir ◽  
Isotope System

<p>The long-lived radiogenic isotope systems Lu-Hf and Sm-Nd have been widely used by geochemists to study magma sources and crustal residential times of (igneous) rocks in order to understand how early crust formed and to model the production rate and volume of continental crust on global and regional-scales during the last ~4.4 Ga. However, while throughout most of Earth’s history Nd and Hf isotope signatures in terrestrial rocks are well correlated due to their very similar geochemical behavior, some of Earth’s oldest rocks show an apparent inconsistency in their Nd and Hf isotope signatures. While Hf isotopes in early Archean rocks are generally (near) chondritic, Nd isotope signatures can be distinctly super- or sub-chondritic. The super-chondritic Nd isotope values in Eoarchean samples would suggest that these rocks are derived from a mantle reservoir depleted by prior crust extraction. The chondritic Hf isotope values, on the other hand, support a mantle source from which no significant volume of crust had been extracted. While a range of different processes, some of them speculative, might explain this Hf-Nd isotope paradox, recent research [1, 2] has shown that relatively simple, post-magmatic, open-system processes can explain decoupling of the typically correlative Hf-Nd isotope signatures. This talk will focus on the importance of identifying Nd-bearing accessory minerals in (Archean) rocks to understand how the Sm-Nd isotope system is controlled and how in situ isotope and trace element analyses by LA-(MC)-ICP-MS in combination with detailed petrographic observations help to understand when and via which processes the two isotope systems become decoupled. Reconstructing the isotopic evolution of the different isotope systems since formation of the protoliths has important implications for our understanding of early crust formation and questions some of the proposed current models for early crust extraction from the mantle.</p><p> </p><p>[1] Hammerli et al. (2019) Chem. Geol 2; [2] Fisher et al. (2020) EPSL</p>

scholarly journals O–H–Sr–Nd isotope constraints on the origin of the Famatinian magmatic arc, NW Argentina

2020 ◽  
Vol 157 (12) ◽  
pp. 2067-2080 ◽  
Author(s):  
P. Alasino ◽  
C. Casquet ◽  
C. Galindo ◽  
R. Pankhurst ◽  
C. Rapela ◽  
...  
Keyword(s):  
Metamorphic Rocks ◽  
Crustal Material ◽  
Nd Isotopes ◽  
Nd Isotope ◽  
Sierras Pampeanas ◽  
Mafic Rocks ◽  
Oxygen Isotope Exchange ◽  
Magmatic Arc ◽  
Zircon Crystallization ◽  
Major Process

AbstractWe report a study of whole-rock O–H–Sr–Nd isotopes of Ordovician igneous and metamorphic rocks exposed at different crustal palaeodepths along c. 750 km in the Sierras Pampeanas, NW Argentina. The isotope compositions preserved in the intermediate rocks (mostly tonalite) (average δ18O = +8.7 ± 0.5‰, δD = −73 ± 14‰, 87Sr/86Srt = 0.7088 ± 0.0001 and εNdt = −4.5 ± 0.6) show no major difference from those of most of the mafic rocks (average δ18O = +8 ± 0.8‰, δD = −84 ± 18‰, 87Sr/86Srt = 0.7082 ± 0.0016 and εNdt = −4 ± 1.1), suggesting that most of their magmas acquired their crustal characteristics in the mantle. The estimate of assimilation of crustal material (δ18O = +12.2 ± 1.7‰, δD = −89 ± 21‰, 87Sr/86Srt = 0.7146 ± 0.0034 and εNdt = −6.9 ± 0.7) by the tonalite is in most samples within the range 10–20%. Felsic magmas that reached upper crustal levels had isotope values (δ18O = +9.9 ± 1.5‰, δD= −76 ± 5‰, 87Sr/86Srt = 0.7067 ± 0.0010, εNdt = −3.5 ± 1.4) suggesting that they were not derived by fractionation of the contaminated intermediate magmas, but evolved from different magma batches. Some rocks of the arc, both igneous (mostly gabbro and tonalite) and metamorphic, underwent restricted interaction with meteoric fluids. Reported values of δ18O of magmatic zircons from the Famatinian arc rocks (+6 to +9‰) are comparable to our δ18O whole-rock data, indicating that pervasive oxygen isotope exchange in the lower crust was not a major process after zircon crystallization.

MKED1: A new titanite standard for in situ analysis of Sm–Nd isotopes and U–Pb geochronology

2016 ◽  
Vol 425 ◽  
pp. 110-126 ◽  
Author(s):  
Carl Spandler ◽  
Johannes Hammerli ◽  
Peng Sha ◽  
Hannah Hilbert-Wolf ◽  
Yi Hu ◽  
...  
Keyword(s):  
In Situ Analysis ◽  
Nd Isotopes

Revised stratigraphy of the Mesozoic rocks of southern Cyprus

1980 ◽  
Vol 117 (6) ◽  
pp. 547-563 ◽  
Author(s):  
R. E. Swarbrick ◽  
A. H. F. Robertson
Keyword(s):  
Oceanic Crust ◽  
Continental Margin ◽  
Late Cretaceous ◽  
Sedimentary Cover ◽  
Igneous Rocks ◽  
Late Triassic ◽  
Metamorphic Rocks ◽  
Southern Cyprus

SummaryRecent resurgence of interest in the Mesozoic rocks of SW and southern Cyprus necessitates redefinition of the Mesozoic sedimentary and igneous rocks in line with modern stratigraphical convention. Two fundamentally different rocks associations are present, the Troodos Complex, not redefined, a portion of late Cretaceous oceanic crust, and the Mamonia Complex, the tectonically dismembered remnants of a Mesozoic continental margin. Based on earlier work, the Mamonia Complex is divided into two groups, each subdivided into a number of subsidiary formations and members. The Ayios Photios Group is wholly sedimentary, and records the evolution of a late Triassic to Cretaceous inactive continental margin. The Dhiarizos Group represents Triassic alkalic volcanism and sedimentation adjacent to a continental margin. Several other formations not included in the two groups comprise sedimentary mélange and metamorphic rocks. The Troodos Complex possesses an in situ late Cretaceous sedimentary cover which includes two formations of ferromanganiferous pelagic sediments, radiolarites and volcaniclastic sandstones. The overlying Cainozoic calcareous units are not redefined here.

Lower Palaeozoic and Precambrian igneous rocks from eastern England, and their bearing on late Ordovician closure of the Tornquist Sea: constraints from U-Pb and Nd isotopes

1993 ◽  
Vol 130 (6) ◽  
pp. 835-846 ◽  
Author(s):  
S. R. Noble ◽  
R. D. Tucker ◽  
T. C. Pharaoh
Keyword(s):  
Volcanic Rocks ◽  
Igneous Rocks ◽  
Calc Alkaline ◽  
Nd Isotopes ◽  
Nd Isotope ◽  
Magmatic Arc ◽  
The North ◽  
Basement Rocks ◽  
Continental Arc ◽  
Lower Palaeozoic

AbstractThe U-Pb isotope ages and Nd isotope characteristics of asuite of igneous rocks from the basement of eastern England show that Ordovician calc-alkaline igneous rocks are tectonically interleaved with late Precambrian volcanic rocks distinct from Precambrian rocks exposed in southern Britain. New U-Pb ages for the North Creake tuff (zircon, 449±13 Ma), Moorby Microgranite (zircon, 457 ± 20 Ma), and the Nuneaton lamprophyre (zircon and baddeleyite, 442 ± 3 Ma) confirm the presence ofan Ordovician magmatic arc. Tectonically interleaved Precambrian volcanic rocks within this arc are verified by new U-Pb zircon ages for tuffs at Glinton (612 ± 21 Ma) and Orton (616 ± 6 Ma). Initial εNd values for these basement rocks range from +4 to - 6, consistent with generation of both c. 615 Ma and c. 450 Ma groups of rocksin continental arc settings. The U-Pb and Sm-Nd isotope data support arguments for an Ordovician fold/thrust belt extending from England to Belgium, and that the Ordovician calc-alkaline rocks formed in response to subductionof Tornquist Sea oceanic crust beneath Avalonia.

Simultaneous determination of Sm–Nd isotopes, trace-element compositions and U–Pb ages of titanite using a laser-ablation split-stream technique with the addition of water vapor

2021 ◽  
Author(s):  
Le Zhang ◽  
Jia-Lin Wu ◽  
Yanqiang Zhang ◽  
Ya-Nan Yang ◽  
Pengli He ◽  
...  
Keyword(s):  
Rare Earth ◽  
Water Vapor ◽  
Laser Ablation ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Simultaneous Determination ◽  
Nd Isotopes ◽  
Trace Element Contents

Titanite is a widespread accessory nesosilicate with high trace-element contents including rare-earth elements, Th, and U, and is thus suitable for in situ isotopic and trace-element analyses and U–Pb dating....

Evolution of geodynamics since the Archean: Significant change at the dawn of the Phanerozoic

Geology ◽  
2020 ◽  
Vol 48 (5) ◽  
pp. 488-492 ◽  
Author(s):  
M. Brown ◽  
C.L. Kirkland ◽  
T.E. Johnson
Keyword(s):  
Ultrahigh Pressure ◽  
Secular Change ◽  
Metamorphic Rocks ◽  
Data Sets ◽  
Ultrahigh Pressure Metamorphism ◽  
Slab Breakoff ◽  
Wide Range ◽  
O Isotope ◽  
Global Data Sets ◽  
Global Data

Abstract A time-series analysis of thermobaric ratios (temperature/pressure [T/P]) for Paleoarchean to Cenozoic metamorphic rocks identified significant shifts in mean T/P that may be related to secular change in the geodynamics on Earth. Thermobaric ratios showed significant (>95% confidence) change points at 1910, 902, 540, and 515 Ma, recording drops in mean T/P, and at 1830, 604, and 525 Ma, recording rises in mean T/P. Highest mean T/P occurred during the Mesoproterozoic, and lowest mean T/P occurred from the Cambrian to the Oligocene. Correlated changes were seen between T/P and global data sets of time-constrained hafnium (Hf) and oxygen (O) isotope compositions in zircon. The range of correlated variation in T/P, Hf, and O was larger during the formation of Rodinia than Columbia. Large changes and a wide range for these variables continued through the Phanerozoic, during which a statistically significant 83 m.y. frequency of T/P excursions recorded the high tempo of orogenic activity associated with the separation, migration, and accretion of continental terranes during the formation of Pangea. Since the early Tonian, the decreasing mean T/P of metamorphism, widespread appearance of blueschist and ultrahigh-pressure metamorphism, and wide fluctuations in Hf and O isotope compositions document a change to the modern plate-tectonic regime, characterized by widespread continental subduction and deeper slab breakoff than in the Proterozoic.

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