scholarly journals A Novel Procedure of Total Organic Carbon Analysis for Water Samples Containing Suspended Solids with Alkaline Extraction and Homogeneity Evaluation by Turbidity

Author(s):  
Han-Saem Lee ◽  
Jin Hur ◽  
Yu-Hoon Hwang ◽  
Hyun-Sang Shin

This study was conducted to develop and validate a more reliable total organic carbon (TOC) analytical procedure for water samples containing suspended solids (SS). The effects of the combined ultrasonic and alkaline pretreatment (CULA) on the TOC measurement were studied in water samples containing SS from three origins (algae, sewage particles, and soil) under different analytical conditions (SS concentration, oxidation methods, and sieve size). The applicability of turbidity as a homogeneity index was also evaluated. With CULA, TOC recovery remained high (>80%) for SS concentration ranges up to four times larger than ultrasonic pretreatment alone (UL) due to enhanced particulate organic carbon (POC) solubilization, and did not significantly differ depending on the oxidation methods, at low SS concentrations, or with varying sieve sizes. In particular, the turbidity change rate (i.e., NTU5/NTU0) of the pretreated water sample showed a high correlation with TOC precision (r2 = 0.73, p < 0.01), which suggests that turbidity can be used as an indicator of sample homogeneity. A novel TOC analytical procedure is expected to be useful for more accurate assessments of the impact of particulate pollutants on water quality than current methods, and for the analysis of the carbon cycle, including POCs, in the environment.

2019 ◽  
Vol 42 (6) ◽  
pp. 259-267
Author(s):  
Kazuhide HAYAKAWA ◽  
Yoshinori HIROSE ◽  
Takahiro OKAMOTO ◽  
Syo-ichi HICHIRI ◽  
Tomoyuki OHARA ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3784 ◽  
Author(s):  
Violetta Kozik ◽  
Krzysztof Barbusinski ◽  
Maciej Thomas ◽  
Agnieszka Sroda ◽  
Josef Jampilek ◽  
...  

The potential implementation of Envifer®, a commercial product containing potassium ferrate (40.1% K2FeO4), for the purification of highly contaminated tannery wastewater from leather dyeing processes was proposed. The employment of the Taguchi method for optimization of experiments allowed the discoloration (98.4%), chemical oxygen demand (77.2%), total organic carbon (75.7%), and suspended solids (96.9%) values to be lowered using 1.200 g/L K2FeO4 at pH 3 within 9 min. The application of the central composite design (CCD) and the response surface methodology (RSM) with the use of 1.400 g/L K2FeO4 at pH 4.5 diminished the discoloration, the chemical oxygen demand, the total organic carbon, and suspended solids within 9 min. The Taguchi method is suitable for the initial implementation, while the RSM is superior for the extended optimization of wastewater treatment processes.


2017 ◽  
Vol 13 (3) ◽  
pp. 167
Author(s):  
Husnah Husnah ◽  
Eko Prianto ◽  
Siti Nurul Aida

Sungai Musi merupakan sungai besar mengaliri wilayah Sumatera Selatan, Lampung, dan Bengkulu , dan bervariasi dalam pemanfaatannya, khususnya di bagian hilir, didominasi oleh kegiatan industri yang membuang limbahnya ke Sungai Musi. Kajian pengaruh industri terhadap Sungai Musi telah dilakukan, namun sebatas analisis fisik dan kimia lingkungan dan belum mengarah kepada pengaruhnya terhadap organisme air. Organisme air adalah indikator penting perubahan lingkungan karena organisme khususnya organisme dasar (benthos) menyimpan sejarah proses-proses terjadi di perairan. Riset yang bertujuan untuk mengetahui kualitas perairan Sungai Musi bagian hilir ditinjau dari karakteristik fisik dan kimia dan struktur makrozoobenthos telah dilakukan di Sungai Musi, Sumatera Selatan pada bulan Mei dan September 2006. Riset dilakukan bersifat survei lapangan. Delapan stasiun ditentukan di Sungai Musi bagian hilir berdasarkan pada perbedaan mikrohabitat. Stasiun riset masing masing antara lain Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, dan Sungsang. Pada masing masing stasiun, dilakukan pengambilan contoh air untuk parameter fisika, kimia, dan makrobenthos. Contoh air diambil dari atas perahu motor pada kedalaman 1,0 m dari permukaan air dengan menggunakan kemmerer water sampler. Sebagian contoh dianalisis di lapangan (suhu, pH, dan oksigen terlarut) dan sebagian lagi yaitu jumlah padatan tersesuspensi (total suspended solids), jumlah padatan terlarut (total dissolved solids), jumlah karbon organik (total organic carbon), organik karbon terlarut (dissolved organic carbon), konsumsi oksigen biologi (biochemical oxygen demand), nitrat, dan fosfat dianalisis di laboratorium kimia. Contoh makrozoobenthos diambil pada 10 titik di masing-masing stasiun, dengan menggunakan ekman dredge dengan bukaan mulut 400 cm2. Contoh makrobenthos pada masingmasing titik tersebut disortir dengan menggunakan saringan dan kemudian digabungkan (dikomposit) dan diawetkan dengan formalin 10%. Data kualitas air dianalisis dengan principle component analysis dan kelimpahan makrozoobenthos dianalisis dengan analisis cluster. Kualitas perairan di Sungai Musi bagian hilir dikelompokkan atas 2 yang mengalami tekanan berat yaitu dari Sejagung sampai dengan Pulau Burung dan tekanan ringan yaitu dari Upang sampai dengan Muara Sungai Musi. Kelompok pertama dicirikan oleh nilai konsentrasi total dissolved solids, total organic carbon, dan dissolved organic carbon yang tinggi diiringi dengan kelimpahan makrozoobenhthos yang rendah serta didominasi oleh Tubifex sp. Kelompok ke-2 dari Upang sampai dengan Muara Sungai Musi dicirikan oleh nilai konsentrasi total suspended solids yang tinggi, dengan kelimpahan makrozoobenthos yang tinggi dan didominasi oleh Gammarus. Musi River is a large river , crossing three provinces, South Sumatra, Lampung and Bengkulu, and differeing in types and levels of its resources ultization, particularly at the down stream of Musi River, mostly dominated by industries activities producing a waste which flows to the river. Several studies on the effect of industries on the Musi River have been conducted , however , limmieted on physical dan chemical aspects of the water, not yet to evaluate its effect on aquatic organism. Aquatic organism such macrozoobenthos is important indicator of environmental changes since this organism records the history of processes occurred in the water. Study to assess water quality of the down stream Musi River based on physical, chemical water characteristics and macrozoobenthos community structure was conducted at may and september 2006 in Musi River located in South Sumatera Province of Indonesia. The study used inventory field survey. Eight sampling sites; Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, and Sungsang were selected based on the microhabitat difference. water sampling for physical and chemical parameters and sediment, and  macrozoobenthos were carried in each sampling site. Water sample was collected at a depth of 1.0 m from the water surface by using kemmerer water sampler. Some water quality parameters such as temperature, pH, and dissolved oxygen) were directly analyzed in the field, while the others such as total suspended solids, total dissolved solids, total organic carbon, dissolved organic carbon, biochemical oxygen demand, nitrate, and phosphate were analyzed in laboratory. Macrozoobenthos was collected at ten sampling points in each sampling sites using Ekman Dredge of 400 cm2 mouth opening. Macrozoobenthos from ten sampling points was composited, sorted and preserved with formalin 10%. Water quality parameters were analyzed with principle component analysis while macrozoobenthos abundance was analyzed with cluster. Results revealed that water quality at the down stream Musi River was classified into two groups. The first group was the heavy degraded sites from Sejagung to Pulau Burung, characterized by having high concentration of total dissolved solids, total organic carbon, and dissolved organic carbon, low abundance of macrozoobenthos with Tubifex sp. as the dominant species. The second group was light degraded sites from Upang to the mouth of Musi River, characterized by high concentration of total suspended solids and high macrozoobenthos abundance with Gammarus sp. as the dominant species.


2021 ◽  
Vol 48 (3) ◽  
Author(s):  
Carlos A Ríos ◽  
Mayra A Vargas ◽  
Mario García

In ANH-CR-Montecarlo-1X well located in the southern sector of the Cesar-Ranchería basin, Colombia, rocks of the middle Cretaceous outcrop, which have been defined as belonging to the Cogollo Group. The present study concerns with the diagenetic evolution and thermal maturity of this geological unit, integrating petrographic techniques (thin section microscopy and scanning electron microscopy), geochemistry (total organic carbon and pyrolysis rock-eval) and basic petrophysics, to establish the thermal maturity and the potential of rocks as reservoirs of conventional and unconventional hydrocarbons. The results of petrographic and diagenetic analysis revealed that the rocks compositionally correspond to quartz sandstones and graywackes and carbonate rocks to mudstones and wackestones; which were affected by diagenetic processes such as compaction, mineral neoformations distinguishing minerals from the group of clays that cover the grains of the framework, and other types of precipitates of cements such as silica, ferrous and non-ferrous carbonate, some of these present partial and/or total dissolution, for which secondary porosity is recognized, also metasomatisms, where processes of chloritization and illitization of the argillaceous matrix are observed, alteration of feldspars to ferrous and non-ferrous carbonate, which affects the porosity and permeability of the rock; and recrystallization from micrite to sparite and carbonate precipitation in calcareous rocks. The study also showed that the rocks were more affected by compaction than precipitation of the different cements. The research contributes to the understanding of the impact of diagenetic processes on porosity, as well as their spatial and temporal distribution, providing diagenetic paragenesis for both siliciclastic and carbonatic rocks. When we classifying siliciclastic rocks as potential reservoir rocks, low potential results were obtained as conventional reservoirs but has good potential as non-conventional reservoirs (tight sandstones), this respect to porosity and permeability data. The geochemical studies in the calcareous rocks exhibited low to good content of total organic carbon, overmaturity state and a low generation potential with type III and IV kerogens.


2020 ◽  
Vol 42 (3) ◽  
Author(s):  
Tran Thanh Thai ◽  
Nguyen Thi My Yen ◽  
Hoang Nghia Son ◽  
Ngo Xuan Quang

Multi-correlation between bio-indices of nematode communities and ecological parameters in mangrove-shrimp farming ponds in Tam Giang commune, Nam Can District, Ca Mau Province, Vietnam were investigated. In which, diversities of nematode communities and several environmental variables in eight ponds were considered to process. Our findings underlined the high diversity of nematode communities in mangrove-shrimp farming ponds compared to other mangrove habitats. Nematode diversities provided more oppotunity in natural food for shrimp. Single correlation analyses showed that the species richness index correlated significantly to three variables (salinity, total organic carbon, and total nitrogen), the Margalef diversity index correlated to two variables (salinity, total organic carbon), and the expected number of species for 50 individuals index correlated with one variable (salinity). Results of multi-correlation analyses between the nematode bio-indices and the environmental variables were completely different from those of single-correlation analyses. In multi-correlation analyses, the species richness and the Margalef diversity index correlated to two variables (salinity, total organic carbon), Pielou’s evenness index and Hill indices correlated with dissolved oxygen, also the Hurlbert index correlated to total organic carbon. Hence, it is necessary to pay attention to the impact of complex interactions between the multi-environmental variables and nematode communities. This research aims to explain the differences between single- and multi-correlation for evaluation of the effects of environmental factors on nematodes as well as aquatic organisms. 


2014 ◽  
Vol 11 (6) ◽  
pp. 9341-9378
Author(s):  
E. Gourdin ◽  
S. Huon ◽  
O. Evrard ◽  
O. Ribolzi ◽  
T. Bariac ◽  
...  

Abstract. Tropical rivers of Southeast Asia are characterized by high specific carbon yields and supplies to the ocean. The origin and dynamics of particulate organic matter were studied in the Houay Xon River catchment located in northern Laos during the first erosive flood of the rainy season in May 2012. The partly cultivated catchment is equipped with three successive gauging stations draining areas ranging between 0.2 and 11.6 km2 on the main stem of the permanent stream, and two additional stations draining 0.6 ha hillslopes. In addition, the sequential monitoring of rainwater, overland flow and suspended organic matter compositions was realized at 1 m2 plot scale during a single storm. The composition of particulate organic matter (total organic carbon, total nitrogen, δ13C and δ15N) was determined for suspended sediment, soil surface and subsurface samples collected in the catchment (n = 57, 65 and 11 respectively). Hydrograph separation of event water was conducted using water electric conductivity and δ18O data measured for rainfall, overland flow and river water base flow (n = 9, 30 and 57, respectively). The composition of particulate organic matter indicates that upstream suspended sediments were mainly derived from cultivated soils labelled by their C3 vegetation cover (upland rice, fallow vegetation and teak plantations) but that collapsed riverbanks, characterized by C4 vegetation occurrence (Napier grass), significantly contributed to sediment yields during water level rise and at the downstream station. The highest runoff coefficient (11.7%), sediment specific yield (433 kg ha−1), total organic carbon specific yield (8.3 kg C ha−1) and overland flow contribution (78–100%) were found for the reforested areas covered by teak plantations. Total organic carbon specific yields were up to 2.6-fold higher (at downstream station) than the annual ones calculated 10 years earlier, before the expansion of teak plantations in the catchment. They may be attributed both to the sampling period at the onset of the rainy season (following field clearing by slash and burn) and to the impact of land use change during the past decade.


Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2470 ◽  
Author(s):  
Aleksandra Ukalska-Jaruga ◽  
Bożena Smreczak

Polycyclic aromatic hydrocarbons (PAHs) exhibit persistence in soils, and most of them are potentially mutagenic/carcinogenic and teratogenic for human beings but also influence the growth and development of soil organisms. The PAHs emitted into the atmosphere are ultimately deposited (by dry or wet deposition processes) onto the soil surface where they tend to accumulate. Soil organic matter (SOM) plays an important role in the fate and transformation processes of PAHs, affecting their mobility, availability, and persistence. Therefore, the aim of this research was to investigate the influence of SOM fractional diversification (fulvic acids—FA, humic acids—HA, and humins—HN) on PAH availability and persistence in soils. Twenty soil samples (n = 20) were collected from upper horizons (0–30 cm) of agricultural soils exposed to anthropogenic emissions from industrial and domestic sources. The assessment of PAH concentrations included the determination of medium-molecular-weight compounds from the US EPA list: fluoranthene—FLA, pyrene—PYR, benz(a)anthracene—BaA, and chrysene—CHR. The assessment was conducted using the GC-MS/MS technique. Three operationally defined fractions were investigated: total extractable PAHs (TE-PAHs) fraction, available/bioavailable PAHs (PB-PAHs) fraction, and nonavailable/residual PAHs (RE-PAHs) fraction, which was calculated as the difference between total and available PAHs. TE-PAHs were analyzed by dichloromethane extraction, while PB-PAHs were analyzed with a hydrophobic β-cyclodextrin solution. SOM was characterized by total organic carbon content (Turin method) and organic carbon of humic substances including FA, HA, HN (IHSS method). Concentrations of PAHs differed between soils from 193.5 to 3169.5 µg kg−1, 4.3 to 226.4 µg kg−1, and 148.6 to 3164.7 µg kg−1 for ∑4 TE-PAHs, ∑4 PB-PAHs, and ∑4 RE-PAHs, respectively. The ∑4 PB-PAHs fraction did not exceed 30% of ∑4 TE-PAHs. FLA was the most strongly bound in soil (highest content of RE-FLA), whereas PYR was the most available (highest content of PB-PYR). The soils were characterized by diversified total organic carbon (TOC) concentration (8.0–130.0 g kg−1) and individual SOM fractions (FA = 0.4–7.5 g kg−1, HA = 0.6–13.0 g kg−1, HN = 0.9–122.9 g kg−1). FA and HA as the labile fraction of SOM with short turnover time strongly positively influenced the potential ∑4 PAH availability (r = 0.56 and r = 0.52 for FA and HA, respectively). HN, which constitutes a stable fraction of organic matter with high hydrophobicity and poor degradability, was strongly correlated with ∑4 RE-PAHs (r = 0.75), affecting their persistence in soil.


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