scholarly journals Percolation Conduction of Carbon Nanocomposites

2020 ◽  
Vol 21 (20) ◽  
pp. 7634
Author(s):  
Grigorii S. Bocharov ◽  
Alexander V. Eletskii
Keyword(s):  
Carbon Nanoparticles ◽  
Electron Tunneling ◽  
Model Description ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Carbon Nanocomposites ◽  
New Class ◽  
Ohmic Behavior ◽  
Calculation Results ◽  
Small Additive

Carbon nanocomposites present a new class of nanomaterials in which conducting carbon nanoparticles are a small additive to a non-conducting matrix. A typical example of such composites is a polymer matrix doped with carbon nanotubes (CNT). Due to a high aspect ratio of CNTs, inserting rather low quantity of nanotubes (on the level of 0.01%) results in the percolation transition, which causes the enhancement in the conductivity of the material by 10–12 orders of magnitude. Another type of nanocarbon composite is a film produced as a result of reduction of graphene oxide (GO). Such a film is consisted of GO fragments whose conductivity is determined by the degree of reduction. A distinctive peculiarity of both types of nanocomposites relates to the dependence of the conductivity of those materials on the applied voltage. Such a behavior is caused by a non-ideal contact between neighboring carbon nanoparticles incorporated into the composite. The resistance of such a contact depends sharply on the electrical field strength and therefore on the distance between neighboring nanoparticles. Experiments demonstrating non-linear, non-Ohmic behavior of both above-mentioned types of carbon nanocomposites are considered in the present article. There has been a model description presented of such a behavior based on the quasi-classical approach to the problem of electron tunneling through the barrier formed by the electric field. The calculation results correspond qualitatively to the available experimental data.

scholarly journals Demulsification of Liquid Membrane Emulsion using High Voltage Glass Coated Electrode in Batch System

2017 ◽  
Vol 10 (1) ◽  
Author(s):  
N. Othman ◽  
A. Ahmad ◽  
M. A. Piramali
Keyword(s):  
High Voltage ◽  
Liquid Membrane ◽  
Alternate Current ◽  
Cost Effective ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Oil Emulsion ◽  
Internal Phase ◽  
The Stability ◽  
Time Required

Demulsification is one of the key processes in emulsion liquid membrane application. This study involved the effect of electrical field on demulsification of water in oil using batch high voltage demulsifier system. This technique widely used because of its advantages of easy manipulation of applied field direction and strength, offers cost–effective separation and minimal environmental impact combined with mechanical simplicity. Influence of various values of frequency (400–1500 Hz) and voltage was studied experimentally using Alternate Current (AC) High Voltage Demulsifier with insulated electrode. The emulsion consists of kerosene as organic phase, sulfuric acid as internal phase and span 80 (3 and 5 w/v %) as a surfactant. The effect of emulsion preparation such as homogenizer speed, internal phase and surfactant concentrations on the stability of water–in–oil emulsion was also investigated. The results showed that the attractive forces between the water droplets under an electrical field increase by raising the applied electrical field strength. Meanwhile, the time required for the emulsion to separate and coalescence under electrical field increased when the stability of emulsion increased.

scholarly journals Catalysis with carbon nanoparticles

RSC Advances ◽  
2019 ◽  
Vol 9 (47) ◽  
pp. 27659-27664 ◽  
Author(s):  
Caterina Testa ◽  
Agatino Zammataro ◽  
Andrea Pappalardo ◽  
Giuseppe Trusso Sfrazzetto
Keyword(s):  
Carbon Nanoparticles ◽  
New Class ◽  
Catalytic Applications

Carbon nanoparticles represent a new class of nanocatalysts able to catalyze different reactions. This review collects the catalytic applications of these nanoparticles.

Electrohydrodynamic Printing via Spinneret with Conductive Probe

2013 ◽  
Vol 562-565 ◽  
pp. 1155-1160
Author(s):  
Yi Hong Lin ◽  
Guang Qi He ◽  
Hai Yan Liu ◽  
Jin Wei ◽  
Jian Yi Zheng ◽  
...  
Keyword(s):  
Field Strength ◽  
Applied Voltage ◽  
Industrial Application ◽  
Control Level ◽  
Direct Write ◽  
Electrical Field ◽  
Nano Structure ◽  
Electrical Field Strength ◽  
Electrohydrodynamic Printing ◽  
The Stability

Stability jet ejection and precision deposition are the two keys for industrial application of electrohydrodynamic printing. In this paper, inserted conductive probe is utilized to gain stability jet, which would increase the electrical field strength, reduce the back flow, onset and sustaining voltage. Lower applied voltage would enhance the stability of electrospun jet, in which fine jet can be used to direct-write orderly Micro/Nano-structure. With the guidance and constrain of inserted probe, the oscillating angle range of electrohydrodynamic jet is decreased to 3°from 15°, and the width of printed structures is 21μm in average that is much narrower than that printed from spinneret without probe (74μm in average). Spinneret with tip provides a good way to improve the control level of electrohydrodynamic printing, which would accelerate the industrial application of electrohydrodynamic printed Micro/Nano structure.

Fully Developed Flow of Power-Law Fluid Through a Cylindrical Microfluidic Pipe: Pressure Drop and Electroviscous Effects

2008 ◽  
Author(s):  
Ram P. Bharti ◽  
Dalton J. E. Harvie ◽  
Malcolm R. Davidson
Keyword(s):  
Pressure Drop ◽  
Field Strength ◽  
Charge Density ◽  
Power Law ◽  
Maximum Velocity ◽  
Shear Thickening ◽  
Shear Thinning ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Fluid Behaviour

Pressure drop and electroviscous effects in the axisymmetric, steady, fully developed, pressure-driven flow of incompressible power-law fluids through a cylindrical microchannel at low Reynolds number (Re = 0.01) have been investigated. The Poisson-Boltzmann equation (describing the electrical potential) and the momentum equations in conjunction with electrical force and power-law fluid rheology have been solved numerically using the finite difference method. The pipe wall is considered to have uniform surface charge density (S = 4) and the liquid is assumed to be a symmetric electrolyte solution. In particular, the influence of the dimensionless inverse Debye length (K = 2, 20) and power-law flow behaviour index (n = 0.2, 1, 1.8) on the EDL potential, ion concentrations and charge density profiles, induced electrical field strength, velocity and viscosity profiles and pressure drop have been studied. As expected, the local EDL potential, local charge density and electrical field strength increases with decreasing K and/or increasing S. The velocity profiles cross-over away from the charged pipe wall with increasing K and/or decreasing n. The maximum velocity at the center of the pipe increases with increasing n and/or increasing S and/or decreasing K. The shear-thinning fluid viscosity is strongly dependent on K and S, whereas the shear-thickening viscosity is very weakly dependent on K and S. For fixed K, as the fluid behaviour changes from Newtonian (n = 1) to shear-thinning (n < 1), the induced electrical field strength increases and maximum velocity reduces. On the other hand, the change in fluid behaviour from Newtonian (n = 1) to shear-thickening (n > 1) decreases the electrical field strength and increases the maximum velocity. The non-Newtonian effects on maximum velocity and pressure drop are stronger in shear-thinning fluids at small K and large S, the shear-thickening fluids show opposite influence. Electroviscous effects enhance with decreasing K and/or increasing S. The electroviscous effects show complex dependence on the non-Newtonian tendency of the fluids. The shear-thickening (n > 1) fluids and/or smaller K show stronger influence on the pressure drop and thus, enhance the electroviscous effects than that in shear-thinning (n < 1) fluids and/or large K where EDL is very thin.

Comparative study on electro-microfiltration (EMF) of water containing different carbon nanotubes (CNTs)

2013 ◽  
Vol 67 (6) ◽  
pp. 1247-1253 ◽  
Author(s):  
Yu-Hsiang Weng ◽  
Hsin-Chieh Wu ◽  
Kung-Cheh Li
Keyword(s):  
Carbon Nanotubes ◽  
Field Strength ◽  
Removal Efficiency ◽  
Pure Water ◽  
Applied Pressure ◽  
Convective Transport ◽  
Single Wall Carbon Nanotubes ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Electrical Voltage

Disposal and penetration of carbon nanotubes (CNTs) into the environment have raised increasing concerns over the years. In this study, a laboratory scale electro-microfiltration (EMF) was used to treat water containing single wall carbon nanotubes (SWCNTs) and multi-wall carbon nanotubes (MWCNTs). The goal was to examine and compare the performance during EMF of SWCNT and MWCNT. The results showed that the initial flux was increased as the applied electrical voltage increased. At an applied pressure of 49 kPa, the final flux was comparable to pure water flux when the applied electrical field strength was greater than the critical electrical field strength (Ecritical). In addition, dissolved organic carbon (DOC) removal efficiency increased as the electrical voltage increased. Due to high convective transport of organic matter toward the membrane at 98 kPa, a decrease in DOC removal efficiency with increasing electrical field strength was observed. Overall, the fluxes and DOC removal efficiencies for EMF of SWCNT and MWCNT were not significantly different with a 95% confidence.

scholarly journals Space/Interface Charge Analysis of the Multi-Layer Oil Gap and Oil Impregnated Pressboard Under the Electrical-Thermal Combined Stress

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1099 ◽  
Author(s):  
Runhao Zou ◽  
Jian Hao ◽  
Ruijin Liao
Keyword(s):  
Field Strength ◽  
Charge Density ◽  
Total Charge ◽  
Insulation System ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Interface Charge ◽  
Combined Action ◽  
Paper Insulation ◽  
Main Curve

In oil-paper insulation systems, it is easy to accumulate space/interface charge under a direct current (DC) electrical field. At present, direct measurement of space/interface charge for a thick multi-layer insulation system is not possible. It is necessary to study the multi-layer oil-paper insulation system via simulation method. In this paper, the space/interface charge simulation based on the bipolar charge transport model and a simulation parameter using FEM for the multi-layer oil–paper insulation system was proposed. The influence of electrical field strength, temperature, and the combined influence of the electrical field strength and temperature on the space/interface charge behaviors were analyzed, respectively. A new method for calculating the space/interface charge density and the total charge quantity of the multi-layer oil-paper insulation under the combined action of electrical field strength and temperature was presented. Results show that the interface charge density absolute value and the total charge quantity at steady state both increases with the electrical field strength and temperature in an exponential way, respectively. Besides, temperature has a more significant influence on the charge density and the total charge quantity than the electrical field strength. The electrical field strength–temperature shifting factor αT’ was introduced for the translation of the charge density curves or the total charge quantity curves to construct the charge density main curve or the total charge quantity main curve under the combined action of electrical field strength and temperature. The equations for calculating the charge density or the total charge quantity of the multi-layer oil-paper insulation was provided, which could be used to calculate the charge density or the total charge quantity under the combined action of electrical field strength and temperature.

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