scholarly journals Densification of Ceramic Matrix Composite Preforms by Si2N2O Formed by Reaction of Si with SiO2 under High Nitrogen Pressure. Part 1: Materials Synthesis

2021 ◽  
Vol 5 (7) ◽  
pp. 178
Author(s):  
Brice Taillet ◽  
René Pailler ◽  
Francis Teyssandier
Keyword(s):  
Heating Rate ◽  
Ceramic Matrix Composite ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Nitrogen Pressure ◽  
Major Influence ◽  
High Nitrogen ◽  
Joule Effect ◽  
The Matrix ◽  
High Nitrogen Pressure

Ceramic matrix composites (CMCs) have been designed and developed for extreme operating environments. The aim of the present study is to look for a rapid densification process providing a high level of material performance. The fibrous preform was made of Hi-Nicalon S fibers woven in a 3D interlock weave. The matrix was composed of Si2N2O prepared inside the CMCs by reacting a mixture of Si and SiO2 under high nitrogen pressure (1 to 3 MPa). Silica was either impregnated by slurry or obtained by oxidation of silicon grains inside the preform. The synthesis reaction was initiated by heating the impregnated preform by means of a carbon resistor submitted to Joule effect. Composition, homogeneity and porosity of the formed matrix were studied and interpreted as a function of the experimental parameters (nitrogen pressure, heating rate of the preform) as well as the recorded thermal history of the process. The present results show that the matrix formation is almost completed in less than one minute. Melting of silicon has a major influence on the process. Competition was observed between the formation of Si3N4 and Si2N2O, which could be mainly controlled by the heating rate of the preform and the nitrogen partial pressure.

scholarly journals Densification of Ceramic Matrix Composite Preforms by Si2N2O Formed by Reaction of Si with SiO2 under High Nitrogen Pressure. Part 2: Materials Properties

2021 ◽  
Vol 5 (7) ◽  
pp. 179
Author(s):  
Brice Taillet ◽  
René Pailler ◽  
Francis Teyssandier
Keyword(s):  
Elastic Modulus ◽  
Yield Strength ◽  
Room Temperature ◽  
Outer Part ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Nitrogen Pressure ◽  
High Nitrogen ◽  
Yield Strain ◽  
High Nitrogen Pressure

Ceramic matrix composites (CMCs) have been prepared and optimized as already described in part I of this paper. The fibrous preform made of Hi-Nicalon S fibers was densified by a matrix composed of Si2N2O prepared inside the CMC by reacting a mixture of Si and SiO2 under high nitrogen pressure. This part describes the oxidation resistance and mechanical properties of the optimized CMC. The CMC submitted to oxidation in wet oxygen at 1400 °C for 170 h exhibited an oxidation gradient from the surface to almost the center of the sample. In the outer part of the sample, Si2N2O, Si3N4 and SiC were oxidized into silica in the cristobalite-crystallized form. The matrix microstructure looks similar to the original one at the center of the sample, while at the surface large pores are observed and the fiber/matrix interphase is consumed by oxidation. The elastic modulus and the hardness measured at room temperature by nano-indentation are, respectively, 100 and 8 GPa. The elastic modulus measured at room temperature by tensile tests ranges from 150 to 160 GPa and the ultimate yield strength from 320 to 390 MPa, which corresponds to a yield strain of about 0.6%. The yield strength identified by acoustic emission is about 40 MPa.

A Three-Phase Shear-Lag Model for Longitudinal Cracking of a Ceramic Matrix Composite Ply With Thick Fiber Coatings

2015 ◽  
Vol 83 (1) ◽  
Author(s):  
Lucas R. Hansen ◽  
Anthony M. Waas
Keyword(s):  
Ceramic Matrix Composite ◽  
Stress Transfer ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Matrix Cracking ◽  
Material System ◽  
Shear Lag ◽  
Thick Fiber ◽  
The Matrix ◽  
Lag Model

During progressive cracking of cross-ply ceramic matrix composites (CMCs), load is transferred from the fiber to the matrix in the longitudinal (0 deg) ply via shear through a compliant interphase layer, also referred to as the coating. In the material system of interest, this coating has significant thickness relative to the fiber diameter. The damage process in the cross-ply CMC is observed to be as follows: (1) elastic deformation, (2) cracking of the transverse plies, (3) matrix cracking within the longitudinal plies, (4) failure of longitudinal fibers, and (5) pullout of the cracked fibers from the matrix. In this paper, the focus is on the longitudinal (0 deg) ply. Existing shear-lag models do not fully represent either the stress transfer through the coating or the true accumulations of shear and normal stresses in the matrix. In the current study, a model is developed that takes into account both of these factors to provide a more accurate, analytical representation of the stress distribution and progressive damage accumulation in a longitudinal CMC ply.

Modeling of the Transition Layer in Ceramic Matrix Composites from Coal Wastes and Clay

2020 ◽  
Vol 299 ◽  
pp. 37-42
Author(s):  
O.A. Fomina ◽  
Andrey Yu. Stolboushkin
Keyword(s):  
Transition Layer ◽  
Raw Materials ◽  
Ceramic Matrix Composite ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Coal Waste ◽  
Matrix Composites ◽  
Carbonaceous Particles ◽  
The Core ◽  
Coal Wastes

A model of the transition layer between the shell and the core of a ceramic matrix composite from coal waste and clay has been developed. The chemical, granulometric and mineral compositions of the beneficiation of carbonaceous mudstones and clay were studied. The technological and ceramic properties of raw materials for the samples manufacturing were determined. The method of manufacturing multilayer ceramic samples from coal waste, clay and their mixture is given. The number of transition layers in the contact zone between the clay shell and the core from coal wastes is determined. The deformation and swelling phenomena of model samples from coal wastes, clay, and their mixtures were revealed at the firing temperature of more than 1000 °C. The formation of a reducing ambient in the center of the sample with insufficient air flow is shown. The influence of the carbonaceous particles amount and the ferrous form iron oxide in the coal wastes on the processes of expansion of multilayer samples during firing has been established.

Chemically activated combustion synthesis of AlON under high nitrogen pressure

2021 ◽  
Vol 232 ◽  
pp. 111560
Author(s):  
Tigran G. Akopdzhanyan ◽  
Sergey I. Rupasov ◽  
Stepan Vorotilo
Keyword(s):  
Combustion Synthesis ◽  
Nitrogen Pressure ◽  
High Nitrogen ◽  
High Nitrogen Pressure

The influence of erbium on the physical properties of GaN crystals grown from N solution in Ga at high nitrogen pressure

2000 ◽  
Vol 18 (1-6) ◽  
pp. 35-39
Author(s):  
H. Teisseyre ◽  
T. J. Ochalski ◽  
P. Perlin ◽  
T. Suski ◽  
M. Leszczynski ◽  
...  
Keyword(s):  
Physical Properties ◽  
Nitrogen Pressure ◽  
High Nitrogen ◽  
High Nitrogen Pressure

scholarly journals Exposure of Ceramics and Ceramic Matrix Composites in Simulated and Actual Combustor Environments

2000 ◽  
Vol 122 (2) ◽  
pp. 212-218 ◽  
Author(s):  
Karren L. More ◽  
Peter F. Tortorelli ◽  
Mattison K. Ferber ◽  
Larry R. Walker ◽  
James R. Keiser ◽  
...  
Keyword(s):  
Ceramic Matrix Composite ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Surface Damage ◽  
Operating Conditions ◽  
Matrix Composites ◽  
Long Term Stability ◽  
Recession Rates ◽  
Combustor Liner

A high-temperature, high-pressure, tube furnace has been used to evaluate the long term stability of different monolithic ceramic and ceramic matrix composite materials in a simulated combustor environment. All of the tests have been run at 150 psia, 1204°C, and 15 percent steam in incremental 500 h runs. The major advantage of this system is the high sample throughput; >20 samples can be exposed in each tube at the same time under similar exposure conditions. Microstructural evaluations of the samples were conducted after each 500 h exposure to characterize the extent of surface damage, to calculate surface recession rates, and to determine degradation mechanisms for the different materials. The validity of this exposure rig for simulating real combustor environments was established by comparing materials exposed in the test rig and combustor liner materials exposed for similar times in an actual gas turbine combustor under commercial operating conditions. [S0742-4795(00)02402-9]

Ceramic Matrix Composite Materials for Engine Exhaust Systems on Next-Generation Vertical Lift Vehicles

2018 ◽  
Vol 140 (10) ◽  
Author(s):  
Michael J. Walock ◽  
Vann Heng ◽  
Andy Nieto ◽  
Anindya Ghoshal ◽  
Muthuvel Murugan ◽  
...  
Keyword(s):  
Ceramic Matrix Composite ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Thermal Exposure ◽  
Gas Flows ◽  
Matrix Composites ◽  
Engine Exhaust ◽  
Ir Camera ◽  
Before And After ◽  
Ceramic Components

Future gas turbine engines will operate at significantly higher temperatures (∼1800 °C) than current engines (∼1400 °C) for improved efficiency and power density. As a result, the current set of metallic components (titanium-based and nickel-based superalloys) will be replaced with ceramics and ceramic matrix composites (CMCs). These materials can survive the higher operating temperatures of future engines at significant weight savings over the current metallic components, i.e., advanced ceramic components will facilitate more powerful engines. While oxide-based CMCs may not be suitable candidates for hot-section components, they may be suitable for structural and/or exhaust components. However, a more thorough understanding of the performance under relevant environment of these materials is needed. To this end, this work investigates the high-temperature durability of a family of oxide–oxide CMCs (Ox–Ox CMCs) under an engine-relevant environment. Flat Ox–Ox CMC panels were cyclically exposed to temperatures up to 1150 °C, within 240 m/s (∼0.3 M) gas flows and hot sand impingement. Front and backside surface temperatures were monitored by a single-wavelength (SW) pyrometer and thermocouple, respectively. In addition, an infrared (IR) camera was used to evaluate the damage evolution of the samples during testing. Flash thermography nondestructive evaluation (NDE) was used to elucidate defects present before and after thermal exposure.

Micromechanics Approach for the Overall Elastic Properties of Ceramic Matrix Composites Incorporating Defect Structures

2020 ◽  
Author(s):  
Rajesh S. Kumar
Keyword(s):  
Elastic Properties ◽  
Volume Fraction ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Volume Shrinkage ◽  
Matrix Composites ◽  
Defect Structures ◽  
Linear Elastic ◽  
Elastic Tensor ◽  
The Matrix

Abstract Initial mechanical behavior of Ceramic Matrix Composites (CMCs) is linear until the proportional limit. This initial behavior is characterized by linear elastic properties, which are anisotropic due to the orientation and arrangement of fibers in the matrix. The linear elastic properties are needed during various phases of analysis and design of CMC components. CMCs are typically made with ceramic unidirectional or woven fiber preforms embedded in a ceramic matrix formed via various processing routes. The matrix processing of interest in this work is that formed via Polymer Impregnation and Pyrolysis (PIP). As this process involves pyrolysis process to convert a pre-ceramic polymer into ceramic, considerable volume shrinkage occurs in the material. This volume shrinkage leads to significant defects in the final material in the forms of porosity of various size, shape, and volume fraction. These defect structures can have a significant impact on the elastic and damage response of the material. In this paper, we develop a new micromechanics modeling framework to study the effects of processing-induced defects on linear elastic response of a PIP-derived CMC. A combination of analytical and computational micromechanics approaches is used to derive the overall elastic tensor of the CMC as a function of the underlying constituents and/or defect structures. It is shown that the volume fraction and aspect ratio of porosity at various length-scales plays an important role in accurate prediction of the elastic tensor. Specifically, it is shown that the through-thickness elastic tensor components cannot be predicted accurately using the micromechanics models unless the effects of defects are considered.

scholarly journals Effects of Nonuniform Fiber Geometries on the Microstructural Fracture Behavior of Ceramic Matrix Composites

2019 ◽  
Vol 2019 ◽  
pp. 1-15 ◽  
Author(s):  
Hye-gyu Kim ◽  
Wooseok Ji ◽  
Nam Choon Cho ◽  
Jong Kyoo Park
Keyword(s):  
Optimization Algorithm ◽  
Fracture Behavior ◽  
Ceramic Matrix Composite ◽  
Ceramic Matrix Composites ◽  
Ceramic Matrix ◽  
Shear Loading ◽  
Matrix Composites ◽  
Specific Loading ◽  
Smeared Crack Approach ◽  
Smeared Crack

Microstructural fracture behavior of a ceramic matrix composite (CMC) with nonuniformly distributed fibers is studied in the presentation. A comprehensive numerical analysis package to study the effect of nonuniform fiber dimensions and locations on the microstructural fracture behavior is developed. The package starts with an optimization algorithm for generating representative volume element (RVE) models that are statistically equivalent to experimental measurements. Experimentally measured statistical data are used as constraints while the optimization algorithm is running. Virtual springs are utilized between any adjacent fibers to nonuniformly distribute the coated fibers in the RVE model. The virtual spring with the optimization algorithm can efficiently generate multiple RVEs that are statistically identical to each other. Smeared crack approach (SCA) is implemented to consider the fracture behavior of the CMC material in a mesh-objective manner. The RVEs are subjected to tension as well as the shear loading conditions. SCA is capable of predicting different fracture patterns, uniquely defined by not only the fiber arrangement but also the specific loading type. In addition, global stress-strain curves show that the microstructural fracture behavior of the RVEs is highly dependent on the fiber distributions.

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