scholarly journals Influence of Component Ratio on Thermal and Mechanical Properties of Terpenoid-Sulfur Composites

2021 ◽  
Vol 5 (10) ◽  
pp. 257
Author(s):  
Charini P. Maladeniya ◽  
Rhett C. Smith
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Waste Product ◽  
Weight Fraction ◽  
Mechanical Analysis ◽  
Differential Scanning Calorimetric ◽  
Component Ratio ◽  
Thermal And Mechanical Properties ◽  
Calorimetric Analysis ◽  
Monomer Feed

Terpenoids are potentially sustainable replacements for petrochemical olefins. Sulfur is a waste product produced in large quantities from fossil fuel refining. Several composites with attractive properties have recently been made from terpenoids and sulfur. This report details the extent to which the ratio of sulfur to terpenoid and the terpenoid olefin content influences the thermal and mechanical properties of such terpenoid-sulfur composites. The terpenoids selected were diunsaturated geraniol and triunsaturated farnesol that, upon their inverse vulcanization with elemental sulfur, yield composites GerSx and FarSx, respectively (x = wt % sulfur). The wt % sulfur in the monomer feed was varied from 30–95 for this study, providing twelve materials. Mechanical analysis of these materials was undertaken by compressive and tensile strength techniques. Differential scanning calorimetric analysis revealed both polymeric and orthorhombic sulfur present in the materials with glass transition temperatures (Tg) of −37 °C to −13 °C and melt temperatures (Tm) of 119 to 104 °C. The crystallinity of composites decreases as the weight fraction of sulfur decreases and composites having the highest olefin content exhibit no detectable crystalline microstructures. The compressive strength of the materials showed increasing strength for higher olefin-content materials for both GerSx (with compressive strength of up to 32 MPa) and FarSx (with compressive strength of up to 43 MPa). The improved strength with increasing olefin content levels off at around 80–85% of terpenoid, after which point both tensile and compressive strength diminish.

scholarly journals Effects of Bacillus subtilis biocementation on the mechanical properties of mortars

2019 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
N. SCHWANTES-CEZARIO ◽  
M. F. PORTO ◽  
G. F. B. SANDOVAL ◽  
G. F. N. NOGUEIRA ◽  
A. F. COUTO ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Calcium Carbonate ◽  
Cementitious Materials ◽  
Mechanical Analysis ◽  
Sem Analysis ◽  
Subtilis Strain ◽  
Cement Mortars ◽  
Water To Cement Ratio ◽  
Mixing Water

Abstract This study aims to evaluate the influence of B. subtilis AP91 spores addition on the mechanical properties of mortars. B. subtilis strain AP91, isolated from rice leaves of the needle variety, which has an early cycle of production, was used at the concentration of 105 spores/mL in mortars with cement-to-sand ratio of 1:3 (by weight) and water-to-cement ratio (w/c) of 0.63. These spores were added in two different ways: in the mixing water and by immersion in a solution containing bacterial spores. Scanning Electron Microscope (SEM) analysis showed crystals with calcium peaks on the EDS, which possibly indicates the presence of bioprecipitated calcium carbonate. The results obtained in the mechanical analysis showed that the bioprecipitation of CaCO3 by B. subtilis strain AP91 was satisfactory, particularly when the spores were added in the mixing water, increasing the compressive strength up to 31%. Thus, it was concluded that the addition of B. subtilis AP91 spores in the mixing water of cement mortars induced biocementation, which increased the compressive strength. This bioprecipitation of calcium carbonate may very well have other advantageous consequences, such as the closure of pores and cracks in cementitious materials that could improve durability properties, although more research is still needed on this matter.

Effect of Carbon Nanotube on Electrical, Thermal and Mechanical Properties of Epoxy

2007 ◽  
Author(s):  
Yuanxin Zhou ◽  
Peixuan Wu ◽  
Zhongyang Cheng ◽  
Biddut Kanti Dey ◽  
Shaik Jeelani
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Carbon Nanotube ◽  
High Speed ◽  
Mechanical Test ◽  
High Vacuum ◽  
Mechanical Analysis ◽  
Thermal And Mechanical Properties ◽  
Multi Walled Carbon Nanotubes ◽  
Mechanical Agitator

In this study, electrical, thermal and mechanical properties of multi-walled carbon nanotubes (CNTs) reinforced Epon 862 epoxy have been evaluated. Firstly, 0.1 wt%, 0.2 wt%, 0.3 wt%, and 0.4 wt% CNT were infused into epoxy through a high intensity ultrasonic liquid processor and then mixed with EpiCure curing agent W using a high speed mechanical agitator. The trapped air and reaction volatiles were removed from the mixture using a high vacuum. Neat epoxy sample also was made as reference. Electrical conductivity, dynamic mechanical analysis (DMA, three point bending tests and fracture tests were performed on unfilled, CNT-filled epoxy to identify the loading effect on the properties of composites. Experimental results show significant improvement in electric conductivity. The resistivity of epoxy decreased to 15Ωm with 0.4% CNT. DMA studies revealed that filling the carbon nanotube into epoxy can produce a 90% enhancement in storage modulus and a 17° C increase in Tg, but CNT has little effect on decomposing temperature. Mechanical test results showed that modulus increased with higher CNT loading percentages, but the 0.3 wt% CNT-infusion system showed the maximum strength and fracture toughness enhancement. The decrease in strength and fracture toughness in 0.4% CNT/epoxy was attributed to poor dispersions of nanotubes in the composite.

Thermal and Mechanical Properties of Cyclized Polybutadiene Dielectrics

1986 ◽  
Vol 76 ◽  
Author(s):  
C. W. Wilkins ◽  
H. E. Bair ◽  
M. G. Chan ◽  
R. S. Hutton
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Physical And Mechanical Properties ◽  
Mechanical Analysis ◽  
Infrared Analysis ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
The Difference ◽  
Thermal Mechanical Analysis ◽  
Lower Glass Transition Temperature

ABSTRACTWe have studied some of the physical and mechanical properties of cyclized polybutadiene (CBR) dielectrics by dynamic mechanical analysis, thermal mechanical analysis, thermogravimetry, infrared analysis, and differential scanning calorimetry. Of interest is the difference in properties between thin (<30 μm) films which have been cured under vacuum and those which have been cured in air. Our results indicate that curing under vacuum prevents oxidation and reduces crosslinking. Vacuum cured films have 20% smaller moduli and 200 lower glass transition temperature than do films produced in air.

Mechanical and Thermal Properties of Carbon-Nanofiber Infused Polyurethane Foam

2008 ◽  
Author(s):  
Md. Atiqur Bhuiyan ◽  
Mahesh V. Hosur ◽  
Yaseen Farooq ◽  
Shaik Jeelani
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanofibers ◽  
Polyurethane Foam ◽  
High Speed ◽  
Carbon Nanofiber ◽  
Mechanical Analysis ◽  
Mechanical And Thermal Properties ◽  
Diphenylmethane Diisocyanate ◽  
Thermal And Mechanical Properties ◽  
Mechanical Agitator

In this study, thermal and mechanical properties of carbon nanofiber infused polyurethane foam were investigated. Low density liquid polyurethane foam composed of Diphenylmethane Diisocyanate (Part A) and Polyol (Part B) was doped with carbon nanofibers (CNF). A high-intensity ultrasonic liquid processor was used to obtain a homogeneous mixture of Diphenylmethane Diisocyanate (Part A) and carbon nanofibers (CNF). The CNF were infused into the Part A of the polyurethane foam through sonic cavitation. The modified foams containing nanoparticles were mixed with Part B (Polyol) using a high-speed mechanical agitator. The mixture was then cast into pre-heated rectangular aluminum molds to form the nano-phased foam panels. Flexure, static and high strain rate compression, and dynamic mechanical analysis (DMA) were performed on neat, 0.2 wt%, 0.4 wt% and 0.6 wt% CNF filled polyurethane foam to identify the effect of adding CNF on the thermal and mechanical properties. The highest improvement on thermal and mechanical properties was obtained with 0.2 wt% loading of CNF. Morphology of the samples was studied through X-ray diffraction.

Improve the thermal and mechanical properties of foam polystyrene by gebrile soil

2020 ◽  
Vol 27 (4) ◽  
pp. 8-12
Author(s):  
montajb Al-khodary ◽  
sabah AL-sibai ◽  
moaffaq Tellawi
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Thermal Insulation ◽  
Permissible Limit ◽  
Strength Increase ◽  
Thermal And Mechanical Properties ◽  
Polystyrene Foam ◽  
Natural Materials ◽  
Foam Polystyrene ◽  
Insulation Materials

n this research we tried to improve the thermal insulation efficiency of polystyrene foam by adding some natural materials. The gebrile soil was selected for several reasons, including abundance and ease of processing before the addition - There are many previous researches for soil treatment -. We have found at ratio 20%(The proportion of the soil in the compound) the coefficient of conduction is low and then rises after this percentage As for the absorption of water it increases by increasing the soil, but at this ratio the absorption is within the permissible limit according to the specifications required for the insulation materials and also compressive strength increase with the increasing of the soil ratio because of increasing of mechanical links between the polycarbonate and polystyrene particles and composite-material’s density increasing in general.

Pad Degradation During CMP Process: Effect of Soak in Slurry and Water on Thermal and Mechanical Properties of the CMP Pads

2003 ◽  
Vol 767 ◽  
Author(s):  
A. Tregub ◽  
G. Ng ◽  
M. Moinpour
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Thermal Gravimetric Analysis ◽  
Mechanical Analysis ◽  
Gravimetric Analysis ◽  
Thermal And Mechanical Properties ◽  
Thermal Gravimetric ◽  
Scanning Calorimetry ◽  
Modulated Differential Scanning Calorimetry ◽  
Thermal Mechanical Analysis

AbstractSoak of polyurethane-based CMP pads in tungsten slurry and de-ionized water and its effect on retention of thermal and mechanical properties of the pads was studied using Dynamic Mechanical Analysis (DMA), Thermal Mechanical Analysis (TMA), Thermal Gravimetric Analysis (TGA), and Modulated Differential Scanning Calorimetry (MDSC). Simultaneous cross-linking and plastisizing due to soak were established using DMA and MDSC analysis. The stable operating temperature range and its dependence on soak time were determined using TMA analysis. Substantial difference in diffusion behavior of the “soft” and “hard” pads was discovered: diffusion into the hard pads followed Fickian law [1], while diffusion into the multi-layer soft pads was dominated by the fast filling of the highly porous pad surface with liquid.During a traditional CMP process, which involves application of polishing pads and slurry, the pad properties can be substantially and irreversibly changed as the result of slurry/rinse water absorption.The retention of the pad properties after exposure was monitored using such thermal and mechanical techniques, as Thermal Mechanical Analysis (TMA), Dynamical Mechanical Analysis (DMA), Modulated Differential Scanning Calorimetry (MDSC), Thermal Gravimetric Analysis (TGA).

Curing behavior, thermal, and mechanical properties of N,N′-(4,4′-diphenylmethane)bismaleimide/2,2′-diallylbisphenol A/3-allyl-5,5-dimethylhydantoin resin system

2019 ◽  
Vol 32 (6) ◽  
pp. 631-644
Author(s):  
Xiangyu Liu ◽  
Ling Li ◽  
Zibing Chen ◽  
Xianfa Duan ◽  
Yongjian Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermomechanical Property ◽  
Mechanical Analysis ◽  
Alder Reaction ◽  
Resin System ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Curing Behavior ◽  
Energy Formula ◽  
Diallylbisphenol A

The 3-allyl-5,5-dimethylhydantoin (ADMH) was synthesized and characterized by Fourier transform infrared spectroscopy, 1H-nuclear magnetic resonance (NMR), and 13C-NMR spectroscopy. Then, the ADMH was used to modify the N, N′-(4,4′-diphenylmethane)bismaleimide (BDM)/2,2′-diallylbisphenol A (DABPA) resin to obtain the BDM/DABPA/ADMH resin system (BDA). The curing behavior was investigated by non-isothermal differential scanning calorimetry and the activation energy ([Formula: see text]) was obtained by Kissinger and Ozawa models. The thermomechanical property was measured by dynamic mechanical analysis. Analysis of the data revealed the complexity of the curing reaction, which was firstly dominated by the Ene reaction of allyl and C=C double bond at low and medium temperatures and was further governed by the Diels–Alder reaction and the anionic imide oligomerization occurred at high temperatures. The results demonstrated that 1-BDA had the best thermal and mechanical properties exhibiting excellent modification effect of ADMH.

scholarly journals Cross-Linkable Epoxidized Maleinated Castor Oil: A Renewable Resin Alternative to Unsaturated Polyesters

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Yeşim Müge Şahin ◽  
Gökhan Çaylı ◽  
Jesmi Çavuşoğlu ◽  
Emre Tekay ◽  
Sinan Şen
Keyword(s):  
Mechanical Properties ◽  
Castor Oil ◽  
Unsaturated Polyester ◽  
Mechanical Analysis ◽  
Carboxyl Groups ◽  
Spectroscopic Techniques ◽  
Thermal And Mechanical Properties ◽  
Unsaturated Polyesters ◽  
H Nmr ◽  
And Storage

As an alternative resin to conventional synthetic unsaturated polyesters (UPEs), epoxidized maleinated castor oil (EMACO) was synthesized in two steps. For this purpose, castor oil was reacted with maleic anhydride at 70°C to obtain maleinated castor oil (MACO). Then, epoxidation of MACO was carried out by using a mixture of formic acid and hydrogen peroxide at 0–5°C. Then, the free carboxyl groups of the synthesized EMACO were further reacted with free epoxide groups of EMACO at 90°C. At the end of the reaction, an unsaturated polyester precursor-prepolymer was obtained (P-EMACO). FTIR and1H NMR spectroscopic techniques were used to characterize the monomers synthesized. The P-EMACO was then mixed with styrene and cross-linked in the presence of AIBN at 50°C. Thermal and mechanical properties of the final cross-linked product were investigated by thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA) techniques. The degradation onset temperature of the material at which cross-linked X-EMACO loses 5% of its weight was found to be 209°C. Its dynamicTgand storage modulus at 25°C were determined as 72°C and 1.08 GPa, respectively. These results are higher than some of the different oil based polymers reported in the literature.

Effect of Fly Ash on Thermal and Mechanical Properties of Expanded Perlite Insulation Product

2012 ◽  
Vol 204-208 ◽  
pp. 4151-4155
Author(s):  
Zhan Bing Li ◽  
Xiu Wen Wu ◽  
Xiao Chao Chen
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Fly Ash ◽  
Moisture Content ◽  
National Standards ◽  
Dihydrogen Phosphate ◽  
Thermal And Mechanical Properties ◽  
Expanded Perlite ◽  
Mass Percentage

Expanded perlite insulation samples were prepared with expanded perlite as aggregate, aluminum dihydrogen phosphate as binder and fly ash as addition by mixing, molding, drying and calcination. The effects of fly ash mass percentage on the compressive strength, thermal conductivity, moisture content and density of the samples were studied. The results indicated that the combination properties of adding 10 % fly ash were the best among the all samples according to the national standards (GB/T10303-2001) No 350 Qualified of expanded perlite insulation products. Its compressive strength, thermal conductivity, moisture content and density were 0.456 Mpa, 0.08165 W/ (m K), 0.02 mass % and 259 kg/m3, respectively.

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