scholarly journals The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique

Materials ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 167 ◽  
Author(s):  
Leire Ruiz-Rubio ◽  
Leyre Pérez-Álvarez ◽  
Julia Sanchez-Bodón ◽  
Valeria Arrighi ◽  
José Luis Vilas-Vilela
Keyword(s):  
Voronoi Tessellation ◽  
Contact Guidance ◽  
Polymeric Thin Films ◽  
Styrene Copolymers ◽  
Breath Figure ◽  
Wide Range ◽  
Breath Figure Method ◽  
Patterned Films ◽  
Figure Technique ◽  
Potential Use

Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture.

Role of Cardiac MRI in Detecting Familial Hypertrophic Cardiomyopathy: Review

2016 ◽  
Vol 1 (1) ◽  
pp. 4
Author(s):  
Marymol Koshy ◽  
Bushra Johari ◽  
Mohd Farhan Hamdan ◽  
Mohammad Hanafiah
Keyword(s):  
Hypertrophic Cardiomyopathy ◽  
Magnetic Resonance ◽  
Genetic Disorder ◽  
Familial Hypertrophic Cardiomyopathy ◽  
Non Invasive ◽  
Wide Range ◽  
Proper Diagnosis ◽  
Magnetic Resonance Imaging Mri ◽  
Potential Use

Hypertrophic cardiomyopathy (HCM) is a global disease affecting people of various ethnic origins and both genders. HCM is a genetic disorder with a wide range of symptoms, including the catastrophic presentation of sudden cardiac death. Proper diagnosis and treatment of this disorder can relieve symptoms and prolong life. Non-invasive imaging is essential in diagnosing HCM. We present a review to deliberate the potential use of cardiac magnetic resonance (CMR) imaging in HCM assessment and also identify the risk factors entailed with risk stratification of HCM based on Magnetic Resonance Imaging (MRI).

1,4-Diazepines: A Review on Synthesis, Reactions and Biological Significance

2019 ◽  
Vol 16 (5) ◽  
pp. 709-729 ◽  
Author(s):  
Muhammad A. Rashid ◽  
Aisha Ashraf ◽  
Sahibzada S. Rehman ◽  
Shaukat A. Shahid ◽  
Adeel Mahmood ◽  
...  
Keyword(s):  
Biological Activities ◽  
Biological Significance ◽  
Biological Evaluation ◽  
Wide Range ◽  
Pharmaceutical Industries ◽  
Biological Aspects ◽  
Synthetic Routes ◽  
Biological Attributes ◽  
Synthesis Reactions ◽  
Potential Use

Background:1,4-Diazepines are two nitrogen containing seven membered heterocyclic compounds and associated with a wide range of biological activities. Due to its medicinal importance, scientists are actively involved in the synthesis, reactions and biological evaluation of 1,4-diazepines since number of decades.Objective:The primary purpose of this review is to discuss the synthetic schemes and reactivity of 1,4- diazepines. This article also describes biological aspects of 1,4-diazepine derivatives, that can be usefully exploited for the pharmaceutical sector.Conclusion:This review summarizes the abundant literature on synthetic routes, chemical reactions and biological attributes of 1,4-diazepine derivatives. We concluded that 1,4-diazepines have significant importance due to their biological activities like antipsychotic, anxiolytic, anthelmintic, anticonvulsant, antibacterial, antifungal and anticancer. 1,4-diazepine derivatives with significant biological activities could be explored for potential use in the pharmaceutical industries.

scholarly journals The OsERF115/AP2EREBP110 Transcription Factor Is Involved in the Multiple Stress Tolerance to Heat and Drought in Rice Plants

2021 ◽  
Vol 22 (13) ◽  
pp. 7181
Author(s):  
Seong-Im Park ◽  
Hyeok Jin Kwon ◽  
Mi Hyeon Cho ◽  
Ji Sun Song ◽  
Beom-Gi Kim ◽  
...  
Keyword(s):  
Stress Tolerance ◽  
Transcriptional Activation ◽  
Individual Plant ◽  
Hormone Signaling ◽  
Combined Stress ◽  
Drought Treatment ◽  
Wide Range ◽  
The Individual ◽  
Potential Use ◽  
Multiple Stress Tolerance

The AP2/EREBP family transcription factors play important roles in a wide range of stress tolerance and hormone signaling. In this study, a heat-inducible rice ERF gene was isolated and functionally characterized. The OsERF115/AP2EREBP110 was categorized to Group-IIIc of the rice AP2/EREBP family and strongly induced by heat and drought treatment. The OsERF115/AP2EREBP110 protein targeted to nuclei and suppressed the ABA-induced transcriptional activation of Rab16A promoter in rice protoplasts. Overexpression of OsERF115/AP2EREBP110 enhanced thermotolerance of seeds and vegetative growth stage plants. The OsERF115/AP2EREBP110 overexpressing (OE) plants exhibited higher proline level and increased expression of a proline biosynthesis P5CS1 gene. Phenotyping of water use dynamics of the individual plant indicates that the OsERF115/AP2EREBP110-OE plant exhibited better water saving traits under heat and drought combined stress. Our combined results suggest the potential use of OsERF115/AP2EREBP110 as a candidate gene for genetic engineering approaches to develop heat and drought stress-tolerant crops.

scholarly journals Applicability of Cork as Novel Modifiers to Develop Electrochemical Sensor for Caffeine Determination

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 37
Author(s):  
Mayra K. S. Monteiro ◽  
Djalma R. Da Silva ◽  
Marco A. Quiroz ◽  
Vítor J. P. Vilar ◽  
Carlos A. Martínez-Huitle ◽  
...  
Keyword(s):  
Electrochemical Sensor ◽  
Linear Response ◽  
High Performance ◽  
Low Cost ◽  
Pharmaceutical Formulations ◽  
Caffeine Concentration ◽  
Real Samples ◽  
Wide Range ◽  
Potential Use

This study aims to investigate the applicability of a hybrid electrochemical sensor composed of cork and graphite (Gr) for detecting caffeine in aqueous solutions. Raw cork (RAC) and regranulated cork (RGC, obtained by thermal treatment of RAC with steam at 380 °C) were tested as modifiers. The results clearly showed that the cork-graphite sensors, GrRAC and GrRGC, exhibited a linear response over a wide range of caffeine concentration (5–1000 µM), with R2 of 0.99 and 0.98, respectively. The limits of detection (LOD), estimated at 2.9 and 6.1 µM for GrRAC and GrRGC, suggest greater sensitivity and reproducibility than the unmodified conventional graphite sensor. The low-cost cork-graphite sensors were successfully applied in the determination of caffeine in soft drinks and pharmaceutical formulations, presenting well-defined current signals when analyzing real samples. When comparing electrochemical determinations and high performance liquid chromatography measurements, no significant differences were observed (mean accuracy 3.0%), highlighting the potential use of these sensors to determine caffeine in different samples.

scholarly journals Sustainable Myrcene-Based Elastomers via a Convenient Anionic Polymerization

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 838
Author(s):  
David Hermann Lamparelli ◽  
Magdalena Maria Kleybolte ◽  
Malte Winnacker ◽  
Carmine Capacchione
Keyword(s):  
Anionic Polymerization ◽  
Sodium Hydride ◽  
Reactivity Ratios ◽  
Molecular Weights ◽  
Styrene Copolymers ◽  
Wide Range ◽  
Elastomeric Materials ◽  
Complete Study ◽  
Anionic Copolymerization ◽  
Trialkylaluminum Derivatives

Soluble heterocomplexes consisting of sodium hydride in combination with trialkylaluminum derivatives have been used as anionic initiating systems at 100 °C in toluene for convenient homo-, co- and ter-polymerization of myrcene with styrene and isoprene. In this way it has been possible to obtain elastomeric materials in a wide range of compositions with interesting thermal profiles and different polymeric architectures by simply modulating the alimentation feed and the (monomers)/(initiator systems) ratio. Especially, a complete study of the myrcene-styrene copolymers (PMS) was carried out, highlighting their tapered microstructures with high molecular weights (up to 159.8 KDa) and a single glass transition temperature. For PMS copolymer reactivity ratios, rmyr = 0.12 ± 0.003 and rsty = 3.18 ± 0.65 and rmyr = 0.10 ± 0.004 and rsty = 3.32 ± 0.68 were determined according to the Kelen–Tudos (KT) and extended Kelen–Tudos (exKT) methods, respectively. Finally, this study showed an easy accessible approach for the production of various elastomers by anionic copolymerization of renewable terpenes, such as myrcene, with commodities.

scholarly journals Preparation of Hierarchical Highly Ordered Porous Films of Brominated Poly(phenylene oxide) and Hydrophilic SiO2/C Membrane via the Breath Figure Method

Materials ◽  
2018 ◽  
Vol 11 (4) ◽  
pp. 481 ◽  
Author(s):  
Hua Yuan ◽  
Bing Yu ◽  
Hailin Cong ◽  
Ming Chi ◽  
Yuanzhe Cheng ◽  
...  
Keyword(s):  
Porous Films ◽  
Phenylene Oxide ◽  
Breath Figure ◽  
Breath Figure Method ◽  
Ordered Porous

scholarly journals A new pest management research facility Scions largescale precision track sprayer

2014 ◽  
Vol 67 ◽  
pp. 267-273
Author(s):  
S.F. Gous ◽  
T.M. Withers ◽  
A.J. Hewitt
Keyword(s):  
Large Scale ◽  
Spray Deposition ◽  
Management Research ◽  
Application Research ◽  
Pesticide Application ◽  
Research Facility ◽  
Liquid Pressure ◽  
Plant Canopies ◽  
Wide Range ◽  
Potential Use

A new large scale precision track sprayer has been developed and evaluated for spray deposition and pesticide application research under controlled conditions The spray room is fitted with a 4 m wide electrically driven boom suspended 4 m above ground running on a 12 m long Ibeam It is fitted with 9 independently controlled shut off valves and nozzles Sprays can be applied to live plant canopies up to 3 m tall within a 2 m times; 3 m sample area The number location and type of nozzle on the boom can be altered as can spray liquid pressure and boom speed in order to simulate a wide range of spray application scenarios Calibration of the largescale precision track sprayer has been undertaken for a range of droplet spectra from extremely coarse to very fine This paper documents the calibration results and discusses the potential use of this facility for pesticide application research

One-Step Dynamic Fabrication of Asymmetric Multi-Layered Porous Films for Sustained Drug Delivery

2021 ◽  
Author(s):  
Pengcheng Cui ◽  
Silong Wu ◽  
Jun Xie ◽  
Jiaying Ma ◽  
Lingyun Ding ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Porous Film ◽  
Porous Films ◽  
Inverse Emulsion ◽  
Sustained Drug Delivery ◽  
Breath Figure ◽  
One Step ◽  
Breath Figure Method

Asymmetric multi-layered porous film was prepared by casting inverse emulsion following the breath figure method. The porous morphologies both on the surface and in the bulk of the fabricated film...

scholarly journals SIMULATION AND OPTIMIZATION OF POROUS BONE-LIKE MICROSTRUCTURES WITH SPECIFIC MECHANICAL PROPERTIES

2019 ◽  
Vol 25 ◽  
pp. 89-92
Author(s):  
Adrian Wit ◽  
Sebastian Wronski ◽  
Jacek Tarasiuk
Keyword(s):  
Mechanical Properties ◽  
Statistical Analysis ◽  
Periodic Structures ◽  
Voronoi Tessellation ◽  
Close Packing ◽  
Skeletal System ◽  
Standard Methods ◽  
Simulation And Optimization ◽  
Wide Range ◽  
Meso Scale

Bone trabecular structure can be characterized as a connected network of mineral bars and plates with unique mechanical properties. Standard methods of producing bone-like structures based on periodic structures or foams have same limitations. The organization of the trabecular bone (meso scale) is adapted to the values of stresses and strains affecting the skeletal system. To simulate bone-like structure, the methodology of generating stochastic structure based on hyperuniform spatial points distribution is proposed. Statistical analysis of generated structure shows the possibility to generate clouds of points in wide range of random close packing density, up to 59.52%. Points connected by Voronoi tessellation produce to unique porous topology with no closed-cells and with wide range of connectivity. Manufacturing of a generated structure is only limited by used technique. The proposed algorithm was developed regardless of the manufacturing technique, however, same examples of the structure were printed using 3D addictive technology. The mechanical properties of developed structure are strongly dependent on the material from which they are made, but the modification of the structure allows to change the strength in specific and controlled way.

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