scholarly journals Geopolymer Based on Mechanically Activated Air-cooled Blast Furnace Slag

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1134 ◽  
Author(s):  
Ilda Tole ◽  
Magdalena Rajczakowska ◽  
Abeer Humad ◽  
Ankit Kothari ◽  
Andrzej Cwirzen
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Portland Cement ◽  
Sodium Silicate ◽  
Blast Furnace Slag ◽  
Ball Mill ◽  
Efficient Solution ◽  
Building Materials ◽  
Furnace Slag ◽  
Alkali Activated

An efficient solution to increase the sustainability of building materials is to replace Portland cement with alkali-activated materials (AAM). Precursors for those systems are often based on water-cooled ground granulated blast furnace slags (GGBFS). Quenching of blast furnace slag can be done also by air but in that case, the final product is crystalline and with a very low reactivity. The present study aimed to evaluate the cementitious properties of a mechanically activated (MCA) air-cooled blast furnace slag (ACBFS) used as a precursor in sodium silicate alkali-activated systems. The unreactive ACBFS was processed in a planetary ball mill and its cementing performances were compared with an alkali-activated water-cooled GGBFS. Mixes based on mechanically activated ACBFS reached the 7-days compressive strength of 35 MPa and the 28-days compressive strength 45 MPa. The GGBFS-based samples showed generally higher compressive strength values.

scholarly journals Preparation of Foamed Phosphogypsum Lightweight Materials by Incorporating Cementitious Additives

2019 ◽  
Vol 25 (3) ◽  
pp. 340-347
Author(s):  
Ting WANG ◽  
Xiaojian GAO ◽  
Jian WANG
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Building Materials ◽  
Water Resistance ◽  
Hydrated Lime ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

As a byproduct of phosphoric acid industry, phosphogypsum has many environmental problems. In order to recycle phosphogypsum to manufacture lightweight building materials, cementitious additives including fly ash, ground granulate blast-furnace slag and Portland cement were added to improve strength and water-resistance and different volume of foam was added to reduce the bulk density. The results show that hydrated lime can improve mechanical strength and water resistance of PG paste and the optimal dosage of hydrated lime is 6 %. Higher addition of fly ash or ground granulated blast-furnace slag improves the fluidity and delays the setting time of PG paste. The addition of 10 ~ 20 % fly ash results in a little reducing influence and 10 % ground granulated blast-furnace slag leads to an increase of 20.7 % for 28 days compressive strength of hardened PG specimen. The higher addition of Portland cement results in the better mechanical strength and water resistance of PG specimens. The 28day compressive and flexural strength reaches 25.9 MPa and 8.9 MPa respectively for the 25 % Portland cement mixture. PG based lightweight building materials can prepared by the addition of 60 % volume of air foam, with compressive strength of 1.7 MPa, bulk density of 521.7 kg/m3 and thermal conductivity of 0.0724 W/(m·K). DOI: http://dx.doi.org/10.5755/j01.ms.25.3.19910

Strength Properties of Activated Hwangtoh Mortars

2010 ◽  
Vol 168-170 ◽  
pp. 709-715
Author(s):  
Dongsik Oh ◽  
Doheom Song ◽  
Seongseok Go
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Building Materials ◽  
Strength Properties ◽  
Mixing Conditions ◽  
Substitution Ratio ◽  
Pozzolanic Properties ◽  
The Relationship ◽  
Furnace Slag

Hwangtoh (loess) has pozzolanic properties that mean it can be used as a cement admixture when activated at high temperatures, and that it can be used in combination with building materials such as fly ash or blast furnace slag. This study aimed to analyze the relationship between the compressive strength and the brick bond strength of various mortars containing hwangtoh, and also to find the optimum mixing conditions for the use of hwangtoh. It was found that the mortars’ strength properties are significantly influenced by the water/cement ratio W/C and the activated hwangtoh substitution ratio. We recommend the following materials and mixing conditions: W/C 60%, a cement substitution ratio of activated hwangtoh of 20 ~ 25%, and the addition of 10% blast furnace slag to improve the compressive strength of such mortars.

scholarly journals Red Mud-Blast Furnace Slag-Based Alkali-Activated Materials

2021 ◽  
Vol 13 (20) ◽  
pp. 11298
Author(s):  
Alessio Occhicone ◽  
Mira Vukčević ◽  
Ivana Bosković ◽  
Claudio Ferone
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Red Mud ◽  
Blast Furnace Slag ◽  
Bauxite Residue ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Waste Products ◽  
Furnace Slag ◽  
Alkali Activated

The aluminum Bayer production process is widespread all over the world. One of the waste products of the Bayer process is a basic aluminosilicate bauxite residue called red mud. The aluminosilicate nature of red mud makes it suitable as a precursor for alkali-activated materials. In this work, red mud was mixed with different percentages of blast furnace slag and then activated by sodium silicate solution at different SiO2/Na2O ratios. Obtained samples were characterized by chemical–physical analyses and compressive strength determination. Very high values of compressive strength, up to 50 MPa, even for high percentage of red mud in the raw mixture (70 wt.% of RM in powder mixture), were obtained. In particular, the higher compressive strength was measured for cubic samples containing 50 wt.% of RM, which showed a value above 70 MPa. The obtained mixtures were characterized by no or scarce environmental impact and could be used in the construction industry as an alternative to cementitious and ceramic materials.

scholarly journals Protective Geopolymer Coatings Containing Multi-Componential Precursors: Preparation and Basic Properties Characterization

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3448
Author(s):  
Chenhui Jiang ◽  
Aiying Wang ◽  
Xufan Bao ◽  
Zefeng Chen ◽  
Tongyuan Ni ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Adhesive Strength ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Rapid Test ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

This paper presents an experimental investigation on geopolymer coatings (GPC) in terms of surface protection of civil structures. The GPC mixtures were prepared with a quadruple precursor simultaneously containing fly ash (FA), ground granulated blast-furnace slag (GBFS), metakaolin (MK), and Portland cement (OPC). Setting time, compressive along with adhesive strength and permeability, were tested and interpreted from a perspective of potential applications. The preferred GPC with favorable setting time (not shorter than 120 min) and desirable compressive strength (not lower than 35 MPa) was selected from 85 mixture formulations. The results indicate that balancing strength and setting behavior is viable with the aid of the multi-componential precursor and the mixture design based on total molar ratios of key oxides or chemical elements. Adhesive strength of the optimized GPC mixtures was ranged from 1.5 to 3.4 MPa. The induced charge passed based on a rapid test of coated concrete specimens with the preferred GPC was 30% lower than that of the uncoated ones. Setting time of GPC was positively correlated with η[Si/(Na+Al)]. An abrupt increase of setting time occurred when the molar ratio was greater than 1.1. Compressive strength of GPC was positively affected by mass contents of ground granulated blast furnace slag, metakaolin and ordinary Portland cement, and was negatively affected by mass content of fly ash, respectively. Sustained seawater immersion impaired the strength of GPC to a negligible extent. Overall, GPC potentially serves a double purpose of satisfying the usage requirements and achieving a cleaner future.

Alkali Activation of Granulated Blast Furnace Slag

2010 ◽  
Vol 158 ◽  
pp. 1-11 ◽  
Author(s):  
Zi Qiao Jin ◽  
Xian Jun Lu ◽  
Shu Gang Hu
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Ordinary Portland Cement ◽  
Hydration Product ◽  
Early Age ◽  
Hydration Products ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

In order to stimulate the potential cementitious property of granulated blast furnace slag (GBFS), the ground GBFS sample (Wei Fang Iron and Steel Corporation, China) was activated by lime and gypsum under different dosages. The results showed that lime is an effective activator for the slag, and the optimum dosage of lime is about 10% (w/w) of the slag. At the optimum dosage of lime, the 28 days compressive strength of the lime-slag paste is higher than that of 32.5 ordinary Portland cement (OPC). But, the early age strength (3 and 7 days compressive strength) of the lime-slag paste is lower than that of the OPC. Addition of gypsum can effectively improve the early age strength of the lime-slag paste. At the ratio of gypsum:lime:slag of 8.2:9.2:82.6 (w/w), both the early and long-term compressive strengths of the gypsum-lime-slag paste are higher than that of the OPC. According to XRD, TG-DTA and SEM detections of the hydration products of the lime-slag paste, the gypsum-lime-slag paste and the OPC paste, it reveals that the hydration process of the GBFS-based cementitious material is different from the ordinary Portland cement and the presence of ettringite (AFt) contributes to the early age strength of the pastes. The major hydration product of the OPC paste (<7 days) were measured as ettringite (AFt), but the AFt phase was not detected in the hydration product of the lime-slag paste and the major hydration product of the lime-slag paste was determined as amorphous CSH gel. However, AFt was detected in the hydration products of the gypsum-lime-slag paste in the early stages of hydration, and the formation of AFt is favorable for the early strength improvement of the material.

Experimental Study on Compound Binding Material of Alkali Activated Metakaolin and Ground Granulated Blast Furnace Slag

2011 ◽  
Vol 287-290 ◽  
pp. 1275-1279
Author(s):  
Yong Jia He ◽  
Lin Nu Lu ◽  
Shu Guang Hu
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Hydration Product ◽  
Alkali Activation ◽  
Granulated Blast Furnace Slag ◽  
Binding Material ◽  
Measurement Results ◽  
Furnace Slag ◽  
Alkali Activated

Compound binding material was prepared by the alkali activation of metakaolin and ground granulated blast furnace slag. Hydration product components, microstructure and mechanical properties of the hardened paste were investigated by IR, XRD, SEM, MIP, and compressive strength measurement. Results indicated that hydration products included C-S-H and geopolymer, and both of them were amorphous although there were differences in their structure and morphology. When the dosage of slag was less than 50%, the compressive strength of hardened paste increased as the dosage increased, which was mainly because C-S-H produced by the reaction of GGBFS and alkali filled void in geopolymer phase, and part of unreacted slag particles acting as microaggregate to prevent from extension of microcrack in the hardened paste, so the porosity of hardened paste decreased and compressive strength increased.

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