scholarly journals Compressive Strength and Microstructure of Alkali-Activated Blast Furnace Slag/Sewage Sludge Ash (GGBS/SSA) Blends Cured at Room Temperature

2016 ◽  
Vol 8 (5) ◽  
pp. 1441-1451 ◽  
Author(s):  
M. M. Tashima ◽  
L. Reig ◽  
M. A. Santini ◽  
J. C. B Moraes ◽  
J. L. Akasaki ◽  
...  
2021 ◽  
Vol 13 (20) ◽  
pp. 11298
Author(s):  
Alessio Occhicone ◽  
Mira Vukčević ◽  
Ivana Bosković ◽  
Claudio Ferone

The aluminum Bayer production process is widespread all over the world. One of the waste products of the Bayer process is a basic aluminosilicate bauxite residue called red mud. The aluminosilicate nature of red mud makes it suitable as a precursor for alkali-activated materials. In this work, red mud was mixed with different percentages of blast furnace slag and then activated by sodium silicate solution at different SiO2/Na2O ratios. Obtained samples were characterized by chemical–physical analyses and compressive strength determination. Very high values of compressive strength, up to 50 MPa, even for high percentage of red mud in the raw mixture (70 wt.% of RM in powder mixture), were obtained. In particular, the higher compressive strength was measured for cubic samples containing 50 wt.% of RM, which showed a value above 70 MPa. The obtained mixtures were characterized by no or scarce environmental impact and could be used in the construction industry as an alternative to cementitious and ceramic materials.


Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1134 ◽  
Author(s):  
Ilda Tole ◽  
Magdalena Rajczakowska ◽  
Abeer Humad ◽  
Ankit Kothari ◽  
Andrzej Cwirzen

An efficient solution to increase the sustainability of building materials is to replace Portland cement with alkali-activated materials (AAM). Precursors for those systems are often based on water-cooled ground granulated blast furnace slags (GGBFS). Quenching of blast furnace slag can be done also by air but in that case, the final product is crystalline and with a very low reactivity. The present study aimed to evaluate the cementitious properties of a mechanically activated (MCA) air-cooled blast furnace slag (ACBFS) used as a precursor in sodium silicate alkali-activated systems. The unreactive ACBFS was processed in a planetary ball mill and its cementing performances were compared with an alkali-activated water-cooled GGBFS. Mixes based on mechanically activated ACBFS reached the 7-days compressive strength of 35 MPa and the 28-days compressive strength 45 MPa. The GGBFS-based samples showed generally higher compressive strength values.


2011 ◽  
Vol 287-290 ◽  
pp. 1275-1279
Author(s):  
Yong Jia He ◽  
Lin Nu Lu ◽  
Shu Guang Hu

Compound binding material was prepared by the alkali activation of metakaolin and ground granulated blast furnace slag. Hydration product components, microstructure and mechanical properties of the hardened paste were investigated by IR, XRD, SEM, MIP, and compressive strength measurement. Results indicated that hydration products included C-S-H and geopolymer, and both of them were amorphous although there were differences in their structure and morphology. When the dosage of slag was less than 50%, the compressive strength of hardened paste increased as the dosage increased, which was mainly because C-S-H produced by the reaction of GGBFS and alkali filled void in geopolymer phase, and part of unreacted slag particles acting as microaggregate to prevent from extension of microcrack in the hardened paste, so the porosity of hardened paste decreased and compressive strength increased.


Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2286
Author(s):  
Taewan Kim ◽  
Sungnam Hong ◽  
Choonghyun Kang

This study investigates the characteristics of alkali-activated slag cement using aluminium sulphate (ALS) as an activator. The alkalis NaOH and Na2SiO3 were used as additional activators (denoted by alkali) at 5% and 10% of the weight of the ground granulated blast furnace slag (GGBFS). Three types of activators were considered. The first was when ALS was used alone. For the second, ALS and 5% alkali were used together. The third was when ALS and 10% alkali were used. ALS was used at concentrations of 2%, 4%, 6%, 8%, and 10% based on binder weight. Experimental results show that when ALS was used as a sole activator, the activity of GGBFS was low and its strength was below 1 MPa. However, compressive strength was improved when 5% or 10% alkali and ALS were used at the same time. This was effective at improving mechanical and microstructural performance when used with an additional activator capable of forming a more alkaline environment than using ALS as a sole activator.


2015 ◽  
Vol 754-755 ◽  
pp. 300-304 ◽  
Author(s):  
Aimi Noorliyana Hashim ◽  
Kamarudin Hussin ◽  
Noorzahan Begum ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamrosni Abdul Razak ◽  
...  

Energy saving in building technology is among the most critical problems in the world. Thus it is a need to develop sustainable alternatives to conventional concrete utilizing more environmental friendly materials. One of the possibilities to work out is the massive usage of industrial wastes like ground granulated blast furnace slag (GGBS) to turn them to useful environmental friendly and technologically advantageous cementitious materials. In this study, ground granulated blast furnace slag (GGBS) is used to produce of alkali activated slag (AAS) mortar with the effect of alkaline activator concentration. Alkali activated slag (AAS) mortar is accelerated using alkaline solution of sodium silicate mixed with sodium hydroxide. The fixed ratio of sodium silicate to sodium hydroxide is 1.7 and the concentration of sodium hydroxide is varied from 6M to 12M. Concentration of 10M NaOH promotes the best properties of mortar by achieving the greatest compressive strength. Substitution of mineral admixture also influences strength performance of AAS mortars. The mortar with 20% calcium carbonate demonstrates the maximum compressive strength. The used of alkaline activation system is the best method to prepare industrial byproduct concrete. Moreover, alkali activated product itself gains superior properties which lead to the system become the most interesting method to produce sustainable concrete.


2014 ◽  
Vol 600 ◽  
pp. 227-239
Author(s):  
Hanan A. El Nouhy

This research investigates the influence of high temperature on the properties of bricks containing non-ground granulated blast-furnace slag (GBFS) as fine aggregate replacement. Replacement percentages were 0%, 25% and 50% by dry weight of fine aggregates. The manufactured bricks were exposed to 200°С, 400°С, 600°С, and 800°С for a constant duration of two hours after 28 days of curing. Tests were conducted according to both Egyptian Standard Specifications (ESS) and American Society for Testing and Materials (ASTM) in order to determine compressive strength, absorption percentage, oven-dry weight, and ultrasound pulse velocity. Also, loss in weight was performed. Compressive strength limit regarding load-bearing units was met by mix 1 at all tested temperatures. Mixes 2 and 3, resulted in compressive strength that satisfied the requirement for load-bearing units at temperatures ranging from room temperature to 600°С.Compressive strength obtained regarding mixes 2 and 3 met the requirements of non-load bearing units at 800°С. The control mix resulted in normal weight bricks when tested at the various temperatures till 600°С. At 800°С, mixes 2 and 3 yielded light weight and medium weight bricks, respectively. There was a significant reduction in mass when comparing the mass at 800°С with the corresponding mass at room temperature concerning the three mixes. Results showed that it is feasible to partially replace fine aggregate with GBFS even when bricks are subjected to elevated temperature.


Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 337 ◽  
Author(s):  
Juan Cosa ◽  
Lourdes Soriano ◽  
María Borrachero ◽  
Lucía Reig ◽  
Jordi Payá ◽  
...  

The properties of a binder developed by the alkali-activation of a single waste material can improve when it is blended with different industrial by-products. This research aimed to investigate the influence of blast furnace slag (BFS) and fly ash (FA) (0–50 wt %) on the microstructure and compressive strength of alkali-activated ceramic sanitaryware (CSW). 4 wt % Ca(OH)2 was added to the CSW/FA blended samples and, given the high calcium content of BFS, the influence of BFS was analyzed with and without adding Ca(OH)2. Mortars were used to assess the compressive strength of the blended cements, and their microstructure was investigated in pastes by X-ray diffraction, thermogravimetry, and field emission scanning electron microscopy. All the samples were cured at 20 °C for 28 and 90 days and at 65 °C for 7 days. The results show that the partial replacement of CSW with BFS or FA allowed CSW to be activated at 20 °C. The CSW/BFS systems exhibited better mechanical properties than the CSW/FA blended mortars, so that maximum strength values of 54.3 MPa and 29.4 MPa were obtained in the samples prepared with 50 wt % BFS and FA, respectively, cured at 20 °C for 90 days.


2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Bong-Suk Cho ◽  
Kyung-Mo Koo ◽  
Se-Jin Choi

This study investigates the effect of desulfurization slag (DS) and gypsum (G) on the compressive strength and microstructure properties of blast furnace slag-(BFS-) based alkali-activated systems. DS is produced in a Kambara reactor process of molten iron produced in a steel production process. DS contains CaO, SiO2, Fe2O3, and SO3 and is composed of Ca(OH)2 and 2CaO·SiO2 as main compounds. In this investigation, the weight of BFS was replaced by DS at 5, 10, 15, 20, 25, and 30%. In addition, G was also applied at 9, 12, and 15% by weight of BFS to improve the compressive strength of the alkali-activated system with BFS and DS. According to this investigation, the compressive strength of the alkali-activated mixes with BFS and DS ranged from 14.9 MPa (B95D5) to 19.8 MPa (B90D10) after 91 days. However, the 28 days compressive strength of the alkali-activated mixes with BFS, DS, and G reached 39.1 MPa, 45.2 MPa, and 48.4 MPa, respectively, which were approximately 78.8 to 97.5% of that of O100 mix (49.6 MPa). The main hydrates of the BFS-DS (B80D20) binder sample were Ca(OH)2, CaCO3, and low-crystalline calcium silicate hydrates, while the main hydration product of BFS-DS-G (B75D10G15) binder was found as ettringite. The use of BFS-DS-G binders would result in the value-added utilization of steel slag and provide an environmentally friendly construction material, and contribute to a reduction of CO2 in the cement industry.


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