scholarly journals Full Optimization of an Electroless Nickel Solution: Boosting the Performance of Low-Phosphorous Coatings

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1501
Author(s):  
Asier Salicio-Paz ◽  
Ixone Ugarte ◽  
Jordi Sort ◽  
Eva Pellicer ◽  
Eva García-Lecina
Keyword(s):  
Mechanical Properties ◽  
Electroless Nickel ◽  
Point Of View ◽  
Fine Tuning ◽  
Complexing Agent ◽  
Order Of Magnitude ◽  
Univariate Optimization ◽  
Full Optimization ◽  
Optimal Values ◽  
Influential Parameters

Univariate and multivariate optimizations of a novel electroless nickel formulation have been carried out by means of the Taguchi method. From the compositional point of view, adjustment of the complexing agent concentration in solution is crucial for fine-tuning free Ni2+ ions concentration and, in turn, the mechanical properties of the resulting coatings. The Ni (II) concentration and the pH are the main parameters which help restrict the incorporation of phosphorous into the Ni layers. On the other hand, the stirring rate, the pH and the reducing agent concentration are the most influential parameters for the corrosion resistance of the coatings. Multivariate optimization of the electrolyte leads to a set of optimized parameters in which the mechanical properties (hardness and worn volume) of the layers are similar to the optimal values achieved in the univariate optimization, but the corrosion rate is decreased by one order of magnitude.

The Surface Affinity of Rubber for a Filler

1933 ◽  
Vol 6 (2) ◽  
pp. 263-264
Author(s):  
E. Vellinger
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Zinc Oxide ◽  
Surface Activity ◽  
Point Of View ◽  
Reinforcing Fillers ◽  
Reinforcing Agent ◽  
Order Of Magnitude ◽  
Strong Surface

Abstract It is known that there is a relation between the mechanical properties of rubber and the nature of the, filler or pigment which is incorporated in it. It has been proved that certain fillers have the property of improving considerably the characteristic mechanical properties of rubber. Thus zinc oxide has proved to be a better reinforcing agent than some substances with a finer particle size. Lithopone, with a fineness which is of the same order of magnitude as that of zinc oxide, has no reinforcing action whatever. Gas black has the most powerful action known. Moreover all reinforcing fillers are very good absorbents. On the contrary inert fillers arc of little account from this point of view. The phenomena of adsorption seem then to play an important part in the reinforcing action of fillers, and consequently substances with strong surface activity are adsorbed by these fillers.

scholarly journals Energy Efficient Glazed Office Building Envelope Solutions for Different European Climates

2017 ◽  
Vol 9 (4) ◽  
pp. 470-481
Author(s):  
Marco Scanferla ◽  
Violeta Motuzienė
Keyword(s):  
Primary Energy ◽  
Building Envelope ◽  
Point Of View ◽  
Office Building ◽  
Renewable Energy Systems ◽  
High Rise ◽  
U Value ◽  
Optimal Values ◽  
Influential Parameters ◽  
Critical Aspects

The aim of this study is to show the critical aspects of a completely glazed high rise office building from an energy efficiency point of view in different European climates. The achievable consumptions and the most influential parameters such as glazing U-value, VT/SHGC and shading and their optimal values were investigated. The study has been carried out for a theoretical office building in Italy and Lithuania, representatively of a southern and northern EU climate. The building chosen is representative of all the glazed-simple shape buildings and the analysis of the entirety of the building enables a clear and im-mediate outcome of global consumptions. Number of DesignBuilder simulations were performed and the annual consumptions are summed with the primary energy criteria. Results show the critical aspects of 100% WWR buildings: in the coldest climate the main problem is the huge surface of relatively high glass U-value compared with standard walls, while in the warmer one the main efforts need to be done to avoid the summer overheating caused by incoming solar radiation. Finally, it is shown that it is difficult to lower the overall primary energy consumptions below 130 and 140 kWh/m2a for North-Italy and Lithuania locations respectively. The analysis is focused only in the envelope parameter, thus it is not included renewable energy systems, which can generate higher energy efficiencies.

scholarly journals Development of Novel Lightweight Al-Rich Quinary Medium-Entropy Alloys with High Strength and Ductility

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4223
Author(s):  
Po-Sung Chen ◽  
Yu-Chin Liao ◽  
Yen-Ting Lin ◽  
Pei-Hua Tsai ◽  
Jason S. C. Jang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Compressive Strain ◽  
High Strength ◽  
Fine Tuning ◽  
Face Centered Cubic ◽  
Transportation Industry ◽  
High Entropy ◽  
Good Potential ◽  
Face Centered

Most high-entropy alloys and medium-entropy alloys (MEAs) possess outstanding mechanical properties. In this study, a series of lightweight nonequiatomic Al50–Ti–Cr–Mn–V MEAs with a dual phase were produced through arc melting and drop casting. These cast alloys were composed of body-centered cubic and face-centered cubic phases. The density of all investigated MEAs was less than 5 g/cm3 in order to meet energy and transportation industry requirements. The effect of each element on the microstructure evolution and mechanical properties of these MEAs was investigated. All the MEAs demonstrated outstanding compressive strength, with no fractures observed after a compressive strain of 20%. Following the fine-tuning of the alloy composition, the Al50Ti20Cr10Mn15V5 MEA exhibited the most compressive strength (~1800 MPa) and ductility (~34%). A significant improvement in the mechanical compressive properties was achieved (strength of ~2000 MPa, strain of ~40%) after annealing (at 1000 °C for 0.5 h) and oil-quenching. With its extremely high specific compressive strength (452 MPa·g/cm3) and ductility, the lightweight Al50Ti20Cr10Mn15V5 MEA demonstrates good potential for energy or transportation applications in the future.

Rheology of hydrocarbon gels

1950 ◽  
Vol 200 (1061) ◽  
pp. 183-188 ◽  
Keyword(s):  
Mechanical Properties ◽  
Experimental Measurement ◽  
Theoretical Basis ◽  
Continuous Media ◽  
Point Of View ◽  
Coarse Grained ◽  
Testing Instrument ◽  
Fine Grained ◽  
Mineral Oils ◽  
Space And Time

Hydrocarbon gels contain a number of materials, such as rubber, greases, saponified mineral oils, etc., of great interest for various engineering purposes. Specific requirements in mechanical properties have been met by producing gels in appropriately chosen patterns of constituent components of visible, colloidal, molecular and atomic sizes, ranging from coarse-grained aggregates, represented by sponges, foams, emulsions, etc.; to fine-grained and apparently homogeneous ones, represented by optically clear compounds. The engineer who has to deal with the whole range of such materials will adopt a macroscopic point of view, based on an apparent continuity of all the material structures and of the distributions in space and time of the displacements and forces occurring under mechanical actions. It has been possible to determine these distributions in the framework of a comprehensive scheme in which the fundamental principles of the mechanics of continuous media provide the theoretical basis, and a testing instrument of new design, termed Rheogoniometer, the means of experimental measurement (Weissenberg 1931, 1934, 1946, 1947, 1948).

The Influence of the Addition of Ti on the Mechanical Properties of W-S-Ti Coatings

2006 ◽  
Vol 514-516 ◽  
pp. 687-691 ◽  
Author(s):  
Manuel Evaristo ◽  
Ana Nossa ◽  
Albano Cavaleiro
Keyword(s):  
Mechanical Properties ◽  
Friction Coefficient ◽  
Tribological Performance ◽  
The Self ◽  
Wear Coefficient ◽  
Gradual Loss ◽  
Order Of Magnitude ◽  
Amorphous Structures ◽  
Ti Content ◽  
Ti Films

In this work, W-S-Ti films were deposited by r.f. magnetron sputtering, using simultaneously WS2 and Ti targets. The atomic percentage of Ti in the coating was varied from 0 at.% up to 28 at.%. No significant variations in the S/W ratio with the increase of Ti content were observed. The increasing Ti contents in the films led to a gradual loss of crystallinity. Coatings with contents greater than ≈ 16 at.% only presents a broad peak characteristic of amorphous structures. Alloying the films with Ti led to significant improvements in the hardness (from 0.3 to 8.9 GPa). Also, the adhesive critical load continuously grew with the increase of the Ti content in the films. The wear coefficient of the films dropped more than one order of magnitude with the increase of Ti content whereas the friction coefficient was kept fairly constant with just a small increase in relation to single W-S film. In conclusion, to have a good tribological performance, the addition of Ti to the films should be balanced in order that the increase of the mechanical properties does not lead to severe loss of the self-lubricant properties.

Microwave Activation of Homogeneous and Heterogeneous Catalytic Reactions

1997 ◽  
Vol 62 (2) ◽  
pp. 347-354 ◽  
Author(s):  
Milan Hájek
Keyword(s):  
Active Sites ◽  
Specific Effect ◽  
Point Of View ◽  
Heterogeneous Reactions ◽  
Microwave Activation ◽  
Rate Enhancement ◽  
Heterogeneous Catalytic ◽  
Order Of Magnitude ◽  
And Performance ◽  
Alkylation Reactions

Microwave heating was applied in homogeneous and in heterogeneous reactions and the results were compared from the point of view of activation of chemical reactions. Reactions including the addition of halo compounds to alkenes catalyzed by copper and ruthenium complexes in different solvents and NaY zeolite catalyzed alkylation of secondary amine in the absence of solvent were studied as model reactions to compare possibilities of microwave activation of reactants and catalysts. Rate enhancement of over one order of magnitude in homogeneous reactions was caused mainly by thermal dielectric heating effect which resulted from the effective coupling of microwaves to polar solvents. Activation of reactants and catalysts was very low if any. In heterogeneously catalyzed alkylation reactions highly efficient activation of zeolite catalyst was recorded. The results indicated that the best reaction conditions were in experiments when both activation of catalyst and performance of reaction were carried out under microwave conditions. Rate enhancement was most probably caused by "hot spots" or by "selective heating" of active sites. In both homogeneous and heterogeneous reactions non-thermal activation (specific effect) was excluded.

scholarly journals Effect of Post-Process Curing and Washing Time on Mechanical Properties of mSLA Printouts

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4856
Author(s):  
Bartłomiej Nowacki ◽  
Paweł Kowol ◽  
Mateusz Kozioł ◽  
Piotr Olesik ◽  
Jakub Wieczorek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Bending Strength ◽  
Curing Time ◽  
Cross Sectional ◽  
Post Process ◽  
Order Of Magnitude ◽  
Static Tensile ◽  
High Roughness ◽  
Ambiguous Effect

The article discusses the influence of the post-process on the mechanical properties of elements produced with the use of the mask stereolithography (mSLA) method. Printed samples were subjected to the following post-process steps: Washing and post-curing, at various times. Then, static tensile and static bending tests were carried out, as well as Shore D hardness measurements for the inner and surface part of the sample, as well as profilographometric analysis of the surface. The post-curing time has been found to strongly affect the tensile and bending strength of printouts, and to improve their surface quality. Washing has an ambiguous effect on the strength of the printouts, but, in the end, it was found that extended washing slightly reduces the strength. Washing significantly affects the quality of the printout surface. A washing time that is too short results in a surface that strongly resembles the printing process, with high roughness. Increasing the washing time to 10 min lowers the roughness by one order of magnitude. Post-curing has also been shown to be beneficial for the cured sample with the application of shielding water. This approach results in an improvement in the flexural strength of the printouts. In general, the obtained research results indicate that, for printouts with cross-sectional dimensions of several mm, the optimal washing time is no more than 10 min and the post-curing time is at least 30 min.

scholarly journals Economical and efficient technique for a static localized maximum sun lux determination

2019 ◽  
Vol 10 (2) ◽  
pp. 777
Author(s):  
Ahmed H. Ali ◽  
Adel S. Nada ◽  
Ahmed S. Shalaby
Keyword(s):  
Solar Cell ◽  
Solar Energy ◽  
Solar Irradiance ◽  
Field Measurements ◽  
Fine Tuning ◽  
Efficient Technique ◽  
Irradiance Measurement ◽  
Novel Technique ◽  
Site Field ◽  
Optimal Values

<span>Solar energy is one of the most promising renewable sources that is currently being used worldwide to contribute for meeting rising demands. In this paper solar irradiance measurement will experimentally carried out in two different regions in Egypt; Cairo and Luxor cities. This paper proposes a simple solar lux measurement using a light dependent resistor (LDR) with an arduino kit. This technique is based on two approaches which are coarse and fine maximum sun lux determination. This is based on the predetermined 26<sup>0</sup> vertical slop of the LDR. Coarse tuning determines one of the reach sun lux quarter (90<sup>0</sup>) of horizontal quad. The fine tuning allocates the optimized 10<sup>0</sup> in which; the maximum sun lux can be obtained. The optimal values of sun lux were found between the (90<sup>o</sup>–180<sup>o</sup>) quarter. This study confirms that the narrow ten degrees (95<sup>o</sup>-105<sup>o</sup>) are the optimized static sun lux extraction for the two site field measurements. This novel technique can be used for locating the angle of best installations for the solar cell at which maximum solar energy can be extracted. </span>

scholarly journals Hardening of Nickel Alloys by Ion Implantation of Titanium and Carbon

1996 ◽  
Vol 444 ◽  
Author(s):  
S. M. Myers ◽  
D. M. Follstaedt ◽  
J. A. Knapp ◽  
T. R. Christenson
Keyword(s):  
Mechanical Properties ◽  
Finite Element ◽  
Surface Layer ◽  
Ion Implantation ◽  
Finite Element Modeling ◽  
Yield Stress ◽  
Nickel Alloys ◽  
Element Modeling ◽  
Order Of Magnitude ◽  
Amorphous Surface

AbstractDual ion implantation of titanium and carbon was shown to produce an amorphous surface layer in annealed bulk nickel, in electroformed Ni, and in electroformed Ni7 5Fe 2 5. Diamond-tip nanoindentation coupled with finite-element modeling quantified the elastic and plastic mechanical properties of the implanted region. The amorphized matrix, with a thickness of about 100 nm, has a yield stress of approximately 6 GP and an intrinsic hardness near 16 GPa, exceeding by an order of magnitude the corresponding values for annealed bulk Ni. Implications for micro-electromechanical systems are discussed.

scholarly journals Enhancement in the Tribological and Mechanical Properties of Electroless Nickel-Nanodiamond Coatings Plated on Iron

2017 ◽  
Vol 39 (4) ◽  
pp. 444-451
Author(s):  
Z. Karaguiozova ◽  
J. Kaleicheva ◽  
V. Mishev ◽  
G. Nikolcheva
Keyword(s):  
Mechanical Properties ◽  
Electroless Nickel
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