scholarly journals Bifilm Inclusions in High Alloyed Cast Iron

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3067
Author(s):  
Marcin Stawarz ◽  
Malwina Dojka

Continuous improvement in the quality of castings is especially important since a cast without defects is a more competitive product due to its longer lifecycle and cheaper operation. Producing quality castings requires comprehensive knowledge of their production, crystallization process, and chemical composition. The crystallization of alloyed ductile iron (without the addition of magnesium) with oxide bifilm inclusions is discussed. These inclusions reduce the quality of the castings, but they are a catalyst for the growth of spheroidal graphite that crystallizes in their vicinity. The research was carried out for cast iron with a highly hyper-eutectic composition. Scanning electron microscopy and EDS analysis were used in the research. A detailed analysis of the chemical composition was also carried out based on the spectrometric method, weight method, etc. Based on the obtained results, a model of spheroidal graphite crystallization near bifilm inclusions was proposed. The surface of the analyzed graphite particles was smooth, which suggests a primary crystallization process. The phenomenon of simple graphite and bifilm segregation towards the heat center of the castings was also documented.

2006 ◽  
Vol 315-316 ◽  
pp. 491-495 ◽  
Author(s):  
Zhi Xin Kang ◽  
Yuan Yuan Li ◽  
C.W. Zhong ◽  
Ming Shao ◽  
Wei Xia

The nanoscale functional thin film with the affinity to acrylic rubber was formed on the surface of a high ductile spheroidal-graphite cast iron by means of polymer plating of 6-diallylamino-1,3,5-triazine-2,4-dithiol monosodium salt. The direct joining of acrylic rubber to the cast iron was achieved with the functional nanofilm during curing. High peel strength adherend of the rubber/cast iron was obtained with suitable film thickness and good film quality under curing at 453 K for 18 min. When the film thickness was 8.53 nm, peel strength of the adherend was high to 4.9 kNm-1, and its broken-out section was rubber cohesive failure. The film thickness considerably affected peel strength and rubber coverage. Moreover, the current density of polymer plating had largely influence on mass and quality of thin film, thereby on joining property of acrylic rubber to the cast iron. The good joining property results from chemical bond within interfacial layer of acrylic rubber chain and reactive groups of nanofilm polymer-plated on the surface of cast iron.


Author(s):  
A. G. Slutsky ◽  
I. L. Kulinich ◽  
V. A. Sheinert ◽  
V. A. Stefanovich ◽  
R. E. Trubitsky ◽  
...  

Various modifiers are used for non-furnace processing of cast iron. Some of them are designed for inoculating modification, which improves mechanical properties and eliminates the appearance of whiteness in castings, while others are designed for spheroidizing processing, in particular for producing cast iron with spherical and vermicular graphite. Some have both spheroidizing and inoculating properties. The main part of inoculating and spheroidizing modifiers is made on iron-silicon, Nickel and copper bases.In addition to the chemical composition, the size of the modifier particles, as well as their shape, are of great importance for modification. The optimal size of the fraction depends significantly on the non-furnace processing technology. Thus, for the larger the bucket and the longer the casting the longer the modification effect is required. One of the methods to achieve this is to increase the particle size of the modifier to 50 mm. When intraform processing of cast iron with spherical and vermicular graphite, magnesium-containing modifiers have strict limits on the upper size (4...5 mm), and in addition, the content of small fractions (less than 0.6...1 mm) is not allowed.The use of «heavy» magnesium-containing ligatures for spheroidizing modification of cast iron in order to obtain higher physical and mechanical properties has scientific and practical interest. Numerous studies show that for maximum effect the formation of the structure of the spheroidal graphite, dispersed pearlite metallic base of SGI (spheroidal graphite iron) relevant question is not only selection of the chemical composition of magnesium alloys, but also of the fractional composition, as well as effective method of input into the liquid melt.The purpose of this work was to study the technological features of obtaining cast iron with spherical graphite by bucket modification of copper-magnesium ligature.The researchers used a Leo–1420 scanning microscope, a Polam l-213 optical microscope, and a VEGA II LMU electron microscope with an INCA ENERGY 350 microanalyzer. High-speed induction melting plant, a set of equipment for analyzing the technological and mechanical properties of high-strength cast iron were used.Earlier experimental studies have shown the real possibility of obtaining in the laboratory a «heavy» copper-magnesium alloys as the alloying of magnesium metal with copper, followed by rapid cooling with use of rolling and plastic deformation of powder alloys. Analysis of test results of samples of such alloys showed that it depends on the value of its additives into liquid iron in the structure of formed graphite phase in compacted and globular form. At the same time, the metal base of cast iron is additionally alloyed with copper, which has a favorable effect on the strength characteristics of SGI.However, an urgent problem is the possibility of the appearance of a cementite phase in the structure of high-strength cast iron as a result of its increased supercooling due to the process of spheroidization of the graphite phase. This phenomenon is compounded by the fact that the copper-magnesium ligature, in contrast to the «light» ligature, does not contain silicon active graphitizer. This feature must be taken into account when obtaining high-strength cast iron of high grades.


2019 ◽  
Vol 13 (2) ◽  
pp. 92-99
Author(s):  
Imre Kiss

The manufacturing process of the rolling rolls, as well as the quality of materials used in casting them, can have an important influence upon the quality and the safety of the exploitation. Our approaches to the issue of quality assurance of the rolling rolls, from the viewpoint of the quality of materials that are featured, can cause duration and safety in the rolling exploitation. This research is required because of the numerous flaws that cause rejection, since the phase of melting of these irons is intended to cast rolls. According to the industrial analysis in the cast iron rolls foundries, the results show that one of the main rejection categories is due to the inadequate hardness of the rolls. One of the parameters that will determine the cast iron’s structure is the chemical composition, and this factor could assure the exploitation properties of each roll in all the stands of rolling mill. In this sense, the paper presents an overview of industrial and laboratory research regarding the assurance of the chemical composition of the irons (with nodular graphite) destined for the half–hard rolls casting, and tries to draw some remarks upon the proper correlations of these irons. This study analyses iron rolls cast in combined moulds (iron chill, for the barrel and moulding sand, for the necks of rolls) and includes charges of rolls from half–hard classes, with definite structure and nodular graphite, obtained in simplex cast processes. It presents, in graphical form, the influence of the chemical composition of these irons on the hardness, measured on the barrel. The proper solution is determined through some mathematical restrictions to the input data that the mathematical modelling is initiated with. It will be determined through regression equations, which describe the mathematical dependency between the hardness and the elements of chemical composition – the basic elements (Carbon [C], Manganese [Mn] and Silicon [Si]), the particulate elements (Sulphur [S], Phosphorus [P] and Magnesium [Mg]) and the main alloying elements (Nickel [Ni], Molybdenum [Mo] and Chrome [Cr]). The main results and the graphical addenda are presented.


2012 ◽  
Vol 12 (2) ◽  
pp. 235-244 ◽  
Author(s):  
S. Pietrowski

Wearing Quality of Austenitic, Duplex Cast Steel, Gray and Spheroidal Graphite Iron The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic ("duplex") cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and "duplex" are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and "duplex" in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL-250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and "duplex" are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.


CORROSION ◽  
1954 ◽  
Vol 10 (9) ◽  
pp. 295-298 ◽  
Author(s):  
J. A. CAMERON

Abstract Oxidation tests of up to 4000 hours duration at 1300 degrees F were made on ordinary flake graphite gray irons, ductile iron, and on highly alloyed cast iron having both flake and spheroidal graphite. It is concluded that ductile irons possess resistance to oxidation markedly better than that of flake graphite irons. In highly alloyed irons the difference is less pronounced at this temperature. Specimens exposed in atmospheric tempering furnace equipped with fan for circulation of air.


Sign in / Sign up

Export Citation Format

Share Document