scholarly journals Influence of the Precursor, Molarity and Temperature on the Rheology and Structural Buildup of Alkali-Activated Materials

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3590
Author(s):  
Salman Siddique ◽  
Vivek Gupta ◽  
Sandeep Chaudhary ◽  
Solmoi Park ◽  
Jeong-Gook Jang
Keyword(s):  
Fly Ash ◽  
Storage Modulus ◽  
Loss Factor ◽  
Polymerization Process ◽  
Flow Curves ◽  
Rheological Measurements ◽  
Interparticle Force ◽  
Temperature Levels ◽  
Alkali Activated ◽  
Activating Solution

This study presents an investigation of the effects of the precursor, alkalinity and temperature on the rheology and structural buildup of alkali activated materials. Here, 100% fly ash, 100% slag and blended mixes of fly ash and slag were activated by 4 M, 6 M, 8 M or 10 M (only for sodium hydroxide) solutions at 25 °C, 35 °C, 45 °C and 55 °C. The rheological properties were investigated to obtain the flow curves, viscosity, storage modulus, and loss factor of these materials. The results showed that for the presence of slag, a higher molarity of the alkali activating solution and a high temperature all caused greater interparticle force, leading to an increase in the shear stress and viscosity of the alkali activated materials. It was also observed that slag had the greatest effect on the increase in the storage modulus of the blended mixes. Furthermore, the higher alkalinity and temperature levels were instrumental in initiating the dissolution of fly ash and improving its rate of structural buildup. Moreover, the interdependence of various factors showed that the type of precursor, as well as the concentration of alkali activating solution, were the primary influencing factors on the polymerization process, as well as the rheological measurements of alkali-activated materials.

scholarly journals Alkali-Activated Stainless Steel Slag as a Cementitious Material in the Manufacture of Self-Compacting Concrete

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3945
Author(s):  
Julia Rosales ◽  
Francisco Agrela ◽  
José Luis Díaz-López ◽  
Manuel Cabrera
Keyword(s):  
Mechanical Properties ◽  
Stainless Steel ◽  
Fly Ash ◽  
Steel Slag ◽  
Cementitious Material ◽  
Self Compacting Concrete ◽  
Stainless Steel Slag ◽  
Alkali Activated ◽  
Activating Solution

This work develops the manufacture of self-compacting concrete (SCC) with 50% cement reduction. As an alternative binder to cement, the viability of using an alkali-activated combination of stainless steel slag (SSS) and fly ash (FA) has been demonstrated. SSS was processed applying three different treatments. Binders were manufactured mixing 35% SSS with 65% FA, as precursors, and a hydroxide activating solution. This binder was replaced by the 50% cement for the manufacture of SCC. The results obtained show good mechanical properties and durability. The study shows a reduction in the use of cement in the manufacture of SCC reusing two wastes.

Mechanical Properties of Alkali Activated Fly Ash Geopolymer Stabilized Expansive Clay

2019 ◽  
Vol 23 (9) ◽  
pp. 3875-3888 ◽  
Author(s):  
Anant Lal Murmu ◽  
Anamika Jain ◽  
Anjan Patel
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Expansive Clay ◽  
Alkali Activated

scholarly journals Mechanical Consequences of Dynamically Loaded NiTi Wires under Typical Actuator Conditions in Rehabilitation and Neuroscience

2021 ◽  
Vol 12 (1) ◽  
pp. 4
Author(s):  
Umut D. Çakmak ◽  
Zoltán Major ◽  
Michael Fischlschweiger
Keyword(s):  
Shape Memory Alloy ◽  
Shape Memory ◽  
Storage Modulus ◽  
Loss Factor ◽  
Empirical Relation ◽  
Material Behavior ◽  
Chemical Compositions ◽  
Loading Frequency ◽  
Frequency Dependency ◽  
Controlled Conditions

In the field of rehabilitation and neuroscience, shape memory alloys play a crucial role as lightweight actuators. Devices are exploiting the shape memory effect by transforming heat into mechanical work. In rehabilitation applications, dynamic loading of the respective device occurs, which in turn influences the mechanical consequences of the phase transforming alloy. Hence in this work, dynamic thermomechanical material behavior of temperature-triggered phase transforming NiTi shape memory alloy (SMA) wires with different chemical compositions and geometries was experimentally investigated. Storage modulus and mechanical loss factor of NiTi alloys at different temperatures and loading frequencies were analyzed under force-controlled conditions. Counterintuitive storage modulus- and loss factor-dependent trends regarding the loading frequency dependency of the mechanical properties on the materials’ composition and geometry were, hence, obtained. It was revealed that loss factors showed a pronounced loading frequency dependency, whereas the storage modulus was not affected. It was shown that force-controlled conditions led to a lower storage modulus than expected. Furthermore, it turned out that a simple empirical relation could capture the characteristic temperature dependency of the storage modulus, which is an important input relation for modeling the rehabilitation device behavior under different dynamic and temperature loading conditions, taking directly into account the material behavior of the shape memory alloy.

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