scholarly journals The Influence of CoO/P2O5 Substitutions on the Structural, Mechanical, and Radiation Shielding of Boro-Phosphate Glasses

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6632
Author(s):  
Ahmed M. A. Mostafa ◽  
Mohamed A. M. Uosif ◽  
Ziyad A. Alrowaili ◽  
Reda Elsaman ◽  
Ahmed A. Showahy ◽  
...  
Keyword(s):  
Radiation Protection ◽  
Photon Energy ◽  
Elastic Moduli ◽  
Glass Network ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Phosphate Glasses ◽  
Structural Units ◽  
Protective Properties ◽  
Mass Attenuation

A new glass system (50−x)P2O5–20B2O3–5Al2O3–25Na2O–xCoO was manufactured using a standard melt quenching procedure, where 1≤ x ≤ 12 mol%. The characteristics of boro-phosphate-glasses containing CoO have been studied. The effect of CoO on the radiation-protective properties of glasses was established. The density of the prepared glasses as a function of CoO increased. XRD was used to check the vitreous structure of samples. Fourier-transform infrared (FTIR) spectroscopy was used to study the structure of each sample. FTIR demonstrated that connections grew as CoO/P2O5 levels increased, and the FTIR spectra shifted to higher wavenumbers. The increment of CoO converts non-bridging oxygens associated with phosphate structural units into bridging oxygens. This process increases the concentration of BO4 structural units and creates new, strong and stable bonds B–O–P, i.e., there is polymerization of the boro-phosphate glass network. With an increase in the ratio of CoO/P2O5 in the produced samples, ultrasonic velocities and elastic moduli were observed to increase. The coefficients of linear and mass attenuation, the transmittance of photons in relation to the photon energy, the efficiency of radiation protection in relation to the photon energy, and the thickness of the absorber were modeled using these two methods (experimental and theoretical). From the obtained values, it can be concluded that the 12Co sample containing 12 mol% will play the most influential role in radiation protection. An increase in the content of cobalt-I oxide led to a significant increase in the linear and mass attenuation coefficient values, which directly contributes to the development of the radiation-protective properties of glass.

Structural and Physical Properties Study of Some Phosphate Glasses Used for Radiation Shielding

2016 ◽  
pp. 3983-3993
Author(s):  
Taghreed Zaghloul Amer
Keyword(s):  
Molar Volume ◽  
Attenuation Coefficient ◽  
Gamma Ray ◽  
Glassy State ◽  
Glass Network ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Phosphate Glasses ◽  
Ion Density ◽  
Oxygen Ion

Mossbauer Effect (ME) and Infrared (IR) spectroscopes are used to study the structure of some iron-sodium phosphate glasses containing strontium, with composition [(70-x) mol% P2O5. x mol% SrO, 15 mol% Fe2O3.15 mol% Na2O, where x= 3, 6,9,12 and 15]. These glasses can have many interesting applications especially as gamma ray attenuators.The amorphous nature and the glassy state character of these glasses can be confirmed from comparing the experimental and empirical values of both their density and molar volume. It was found that, as SrO was gradually increased the density increased while the molar volume decreased which may be due to the gradual decrease of the number of oxygen ion density in the glass networks.The micro-hardness and magnetic susceptibility are also increased, which can be attributed to the gradual migration of iron from glass network modifier (GNM) to glass network former (GNF) positions, as confirmed by IR and ME results. IR and ME analysis indicated that both ferric and ferrous have tetrahedral and octahedral symmetry respectively and acting as GNF and GNM at different SrO contents. The gradual replacement of P2O5 by SrO force the iron to transfer from GNM to GNF.The gamma-ray mass attenuation coefficient increased with the gradual increase of Sr2+ as heavy metal, while the HVL decreased.  On the other hand the attenuation coefficient decreased with the increase of gamma-ray photon energy. So, these glasses can be used as transparent shielding materials for low gamma-ray energies and to capsulate the radio-active wastes, while the sample containing 15 mol% SrO, exhibits the highest attenuation coefficient.  

Design of Commercial Window as Radiation Shielding Using Domestic Raw Materials

2014 ◽  
Vol 979 ◽  
pp. 426-430
Author(s):  
Narong Sangwaranatee ◽  
Jakrapong Kaewkhao ◽  
Natthakridta Chanthima
Keyword(s):  
Attenuation Coefficient ◽  
Photon Energy ◽  
Atomic Number ◽  
Raw Materials ◽  
Effective Atomic Number ◽  
Material Design ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Partial Interaction ◽  
Mass Attenuation

The total mass attenuation coefficient, partial photon interaction and effective atomic number of commercial window added with BaSO4in have been investigated at photon energy from 1 keV to 100 GeV on the basis of calculation. The theoretical values of total and partial interaction were obtained by the WinXCom software. The variations of mass attenuation coefficient and effective atomic number with photon energy are shown graphically. The results show that the variation of mass attenuation coefficient and effective atomic number has changed with photon energy and composition of window. It has been found that these parameters increase with increasing BaSO4concentrations, due to the increasing photoelectric absorption in glass samples. These results showed that the BaSO4can improve radiation shielding properties in commercial glass and useful for radiation shielding material design.

scholarly journals Investigations of gamma ray and fast neutron shielding properties of tellurite glasses with different oxide compositions

2016 ◽  
Vol 94 (11) ◽  
pp. 1133-1137 ◽  
Author(s):  
M.I. Sayyed
Keyword(s):  
Photon Energy ◽  
Gamma Ray ◽  
Effective Atomic Number ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Fast Neutrons ◽  
Tellurite Glasses ◽  
Neutron Shielding ◽  
Shielding Properties ◽  
Mass Attenuation

In the present paper, the basic radiation parameters of tellurite glasses with different forming oxides (B2O3, BaO, K2O, V2O5, WO3, and ZnO) have been studied over a wide photon energy range from 1 keV to 100 GeV, using WinXCom program. These parameters are the mass attenuation coefficient (μ/ρ), effective atomic number (Zeff), and electron density (Ne,eff). In addition, the macroscopic effective removal cross sections (ΣR) for fast neutrons have been calculated. The dependence of different parameters on incident photon energy and chemical content has been discussed. Among the selected glass systems TeO2–WO3 and TeO2–B2O3 showed superior shielding properties for gamma-ray and neutrons, respectively. It is shown that the selected glass systems have higher values of the mass attenuation coefficients (μ/ρ) than concretes and 0.7SiO2:0.3BaO glass. These results indicate that tellurite glasses can be used as radiation shielding materials.

scholarly journals Estimation of the X/γ- ray shielding properties of different glass system using Monte Carlo Simulation

2021 ◽  
Vol 12 (2) ◽  
pp. 1117-1122
Author(s):  
Ayano Shanko, MD, Et. al.
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Attenuation Coefficient ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Glass System ◽  
Effective Electron ◽  
X Ray ◽  
Shielding Properties ◽  
Mass Attenuation

The aim of the research is to estimate the X-ray shielding properties of different glass systems using Monte Carlo Simulation. X-ray glass is also known as radiation shielding glass. Glass provides protection against the absorption of energy radiation. The shielding layer is formed by a high concentration of lead and barium. The mass attenuation coefficient, the effective atomic number and the effective electron density are used to determine the position of gamma-ray photons in matter. Shield characterization in terms of mass attenuation coefficient (μm), transmission fraction (T), effective atomic numbers (Zeff), half-value layer (HVL) and exposure build-up. factor (EBF) of a glass system is estimated by the Monte Carlo Simulation. The random sampling and statistical analysis are computed using the monte carlo simulation. Various external factors are considered as the input parameters. The different composition of the glass will be examined using the Monte Carlo simulation and the shielding capability would be determined for the various samples.

On the analysis and prediction of elastic properties in alkali Na2O–B2O3–V2O5 glasses under the substitution of V2O5 by Na2O

2019 ◽  
Vol 60 (6) ◽  
pp. 213-221
Author(s):  
Amin Abd El-Moneim ◽  
Hassan Y. Alfifi
Keyword(s):  
Elastic Properties ◽  
Dissociation Energy ◽  
Packing Density ◽  
Poisson’S Ratio ◽  
Elastic Moduli ◽  
Unit Volume ◽  
Dominant Role ◽  
Glass Network ◽  
Poisson's Ratio ◽  
Structural Units

In this article, we have continued our recent work(30,42) on the prediction of elastic properties in alkali borovanadate glasses. Changes in the elastic moduli and Poisson’s ratio due to the substitution of V2O5 by Na2O in the ternary alkali Na2O–B2O3–V2O5 glasses have been analysed and predicted on the basis of the theories and approaches that existing in the field. Both the packing density and dissociation energy per unit volume of the glass were evaluated in terms of the basic structural units that constitute the glass network. In addition to this, the theoretical values of elastic moduli and Poisson’s ratio were calculated from the Makishima–Mackenzie’s model and compared with the corresponding experimental values. The results revealed that the concentrations of the basic structural units BO3, BO4, VO5 and VO4 play a dominant role in correcting the anomalous behaviour between experimental elastic moduli and calculated dissociation energy per unit volume. An excellent agreement between the theoretical and experimental elastic moduli was achieved for majority of the samples. The correlation between bulk modulus and the ratio between packing density and mean atomic volume has also been achieved on the basis of Abd El-Moneim and Alfifi’s approaches.

scholarly journals Radiation Shielding Properties Comparison of Pb-Based Silicate, Borate, and Phosphate Glass Matrices

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Suwimon Ruengsri
Keyword(s):  
Phosphate Glass ◽  
Theoretical Calculations ◽  
Visible Region ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Attenuation Coefficients ◽  
Total Attenuation ◽  
Shielding Properties ◽  
Glass Matrices ◽  
Mass Attenuation

Theoretical calculations of mass attenuation coefficients, partial interactions, atomic cross-section, and effective atomic numbers of PbO-based silicate, borate, and phosphate glass systems have been investigated at 662 keV. PbO-based silicate glass has been found with the highest total mass attenuation coefficient and then phosphate and borate glasses, respectively. Compton scattering has been the dominate interaction contributed to the different total attenuation coefficients in each of the glass matrices. The silicate and phosphate glass systems are more appropriate choices as lead-based radiation shielding glass than the borate glass system. Moreover, comparison of results has shown that the glasses possess better shielding properties than standard shielding concretes, suggesting a smaller size requirement in addition to transparency in the visible region.

scholarly journals Photon Shielding Characterization of SiO2-PbO-CdO-TiO2 Glasses for Radiotheraphy Shielding Application

2021 ◽  
pp. 32-38
Author(s):  
Idris M. Mustapha ◽  
Atimga B. James ◽  
Sulayman M. Bello
Keyword(s):  
Attenuation Coefficient ◽  
Energy Region ◽  
Effective Atomic Number ◽  
Mean Free Path ◽  
Mass Attenuation Coefficient ◽  
Photoelectric Effect ◽  
High Energy ◽  
Radiation Shielding ◽  
Sudden Increase ◽  
Mass Attenuation

In this study, photon attenuation parameters of (30-x) SiO2–15PbO–10CdO-xTiO2, with x = 0, 2, 4, 6, 8 and 10% mol, were determined and their application as shielding material were discussed. The WinXCOM software was used to determine the mass attenuation coefficient of the studied glasses for the energy range (0.015-15MeV). The mass attenuation coefficient of the glass samples first decline up to 0.09 MeV and slightly increase abruptly and then declined uniformly for all the glasses to approximately zero after about 10 MeV.   The effective atomic number (Zeff) was also calculated for the glass samples and were observe to raise from 0.015 to 0.02 MeV and then decreased between 0.02-5 MeV. On account of the dominance of the photoelectric effect in the low energy region, there was a sudden increase in Zeff at about 0.08 MeV close to the absorption edge of the Pb (0.088 MeV). The rapid increment was observed at 0.1–1.5 MeV by transcending typical Compton scattering interaction at intermediate energies for Zeff'’s and began to decrease in the same form again. The lower Zeff   values were found in low and high energy region for all SPCT glasses. The calculated mean free path, half value layer and tenth value layer values were observe to decline as the TiO2 doping of the glasses increased which accounts for the  three photon interaction mechanisms effectiveness in the variation of MFP and HVL values with energy. It can be concluded that SPCT glasses may be considered an alternative material for radiation shielding practices.

Photon Interactions Study of Bi2O3-Na2O-CaO-SiO2-B2O3 Glasses

2016 ◽  
Vol 675-676 ◽  
pp. 443-446 ◽  
Author(s):  
Pruittipol Limkitjaroenporn ◽  
Wasu Cheewasukhanont ◽  
Kitipun Boonin ◽  
Jakrapong Kaewkhao
Keyword(s):  
Pair Production ◽  
Attenuation Coefficient ◽  
Photon Energy ◽  
Total Mass ◽  
Mass Attenuation Coefficient ◽  
Low Energy ◽  
Borosilicate Glasses ◽  
Photoelectric Absorption ◽  
Photon Interactions ◽  
Mass Attenuation

The Bi2O3 doped with soda lime borosilicate glasses in composition xBi2O3 : 15Na2O : 10CaO : 20B2O3 : (55-x)SiO2 at different concentrations (x = 0, 5, 10, 15, 20, 25 mol%) were studied the photon interactions. The total mass attenuation coefficient, coherent, incoherent, photoelectric absorption and pair production of prepared were studies using WinXcom Program at 1keV to 2MeV. The result of total mass attenuation coefficient and photoelectric absorption were decreases but discontinue because of photoelectric absorption edge at low energy. The photoelectric effect shows the main interaction at the low energy and decrease with increasing of photon energy. The higher photon energy the incoherent scattering found to be the main interaction. But at the photon energy 1.022 MeV, the pair production will be occurs and found to be the main interaction at the photon energy higher than 1.022 MeV.

Gamma radiation shielding properties of glasses within the TeO2-TiO2-ZnO system

2019 ◽  
Vol 107 (6) ◽  
pp. 517-522 ◽  
Author(s):  
M. Almatari
Keyword(s):  
Gamma Radiation ◽  
Attenuation Coefficient ◽  
Atomic Number ◽  
Effective Atomic Number ◽  
Mean Free Path ◽  
Mass Attenuation Coefficient ◽  
Radiation Shielding ◽  
Glass System ◽  
Shielding Properties ◽  
Mass Attenuation

Abstract Radiations are widely used in hospitals and health services in radiotherapy and molecular imaging using x-ray and gamma radiation which considered as the most penetrating radiations and very difficult to shield. In this study, the radiation shielding properties of different zinc oxide (ZnO) concentrations of the (95-x)TeO2-5TiO2-xZnO (x=5, 10, 15, 20, 25, 30 and 40 mol%) glass system was investigated to be introduced as a new transparency effective shielding material. In order to study shielding properties, mass attenuation coefficients in the energy range of 0.015–15 MeV photon energies for the current glass system were calculated using ParShield software. Moreover, half value layer, mean free path and effective atomic number were evaluated using the obtained attenuation coefficient. The results indicated that if ZnO was added to the current glass system the mass attenuation coefficient will be decreased as well as effective atomic number values. The highest mass attenuation coefficient at all energies was found to be in TT5Z5 glass sample as well as the effective atomic number value.

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