scholarly journals Graphitic Carbon Nitride as a Sustainable Photocatalyst Material for Pollutants Removal. State-of-the Art, Preliminary Tests and Application Perspectives

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7368
Author(s):  
Daniele Cecconet ◽  
Michela Sturini ◽  
Lorenzo Malavasi ◽  
Andrea G. Capodaglio
Keyword(s):  
State Of The Art ◽  
Low Cost ◽  
Heterogeneous Photocatalysis ◽  
Light Spectrum ◽  
Direct Sunlight ◽  
Highly Active ◽  
Uv Led ◽  
Removal Processes ◽  
Pollutants Removal ◽  
Xenon Light

Photocatalysis is an attractive strategy for emerging pollutants remediation. Research towards the development of new, efficient and effective catalytic materials with high activity under wide irradiation spectra is a highly active sector in material science. Various semiconductor materials have been employed as photocatalysts, including TiO2, SrTiO3, CdS, BiVO4, Ta3N5, TaON, Ag3PO4, and g-C3N4. The latter is a metal-free, low cost polymer, providing high adsorption and catalytic properties, shown to be promising for photocatalysis applications under visible light. Furthermore, g-C3N4 composites are among the most promising advanced photocatalytical materials that can be produced by green synthesis processes. In this paper, the state-of-the-art of g-C3N4 applications is reviewed, and application perspectives are discussed. Photocatalysis tests with g-C3N4 under Xenon irradiation were performed to gather first-hand information to improve photoreactor design. Xenon light spectrum appears to be a suitable radiation source to replace direct sunlight in engineered pollutants removal processes catalyzed by g-C3N4, in lieu of other currently used heterogeneous photocatalysis processes (e.g., TiO2-UV). LED sources are also very promising due to higher energy efficiency and customizable, catalyzer-specific irradiation spectra.

Controllable growth of graphdiyne layered nanosheets for high-performance water oxidation

2021 ◽  
Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
High Performance ◽  
Low Cost ◽  
Highly Active ◽  
Controllable Growth

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.

scholarly journals UV Inscription and Pressure Induced Long-Period Gratings through 3D Printed Amplitude Masks

Sensors ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 1977
Author(s):  
Ricardo Oliveira ◽  
Liliana M. Sousa ◽  
Ana M. Rocha ◽  
Rogério Nogueira ◽  
Lúcia Bilro
Keyword(s):  
State Of The Art ◽  
Low Cost ◽  
Resonance Wavelength ◽  
Complex Structures ◽  
Pressing Method ◽  
Long Period ◽  
Long Period Gratings ◽  
3D Printed ◽  
Mechanical Pressing ◽  
First Time

In this work, we demonstrate for the first time the capability to inscribe long-period gratings (LPGs) with UV radiation using simple and low cost amplitude masks fabricated with a consumer grade 3D printer. The spectrum obtained for a grating with 690 µm period and 38 mm length presented good quality, showing sharp resonances (i.e., 3 dB bandwidth < 3 nm), low out-of-band loss (~0.2 dB), and dip losses up to 18 dB. Furthermore, the capability to select the resonance wavelength has been demonstrated using different amplitude mask periods. The customization of the masks makes it possible to fabricate gratings with complex structures. Additionally, the simplicity in 3D printing an amplitude mask solves the problem of the lack of amplitude masks on the market and avoids the use of high resolution motorized stages, as is the case of the point-by-point technique. Finally, the 3D printed masks were also used to induce LPGs using the mechanical pressing method. Due to the better resolution of these masks compared to ones described on the state of the art, we were able to induce gratings with higher quality, such as low out-of-band loss (0.6 dB), reduced spectral ripples, and narrow bandwidths (~3 nm).

Accurate 3D Localization Using RGB-TOF Camera and IMU for Industrial Mobile Robots

Robotica ◽  
2021 ◽  
pp. 1-18
Author(s):  
Majid Yekkehfallah ◽  
Ming Yang ◽  
Zhiao Cai ◽  
Liang Li ◽  
Chuanxiang Wang
Keyword(s):  
Mobile Robots ◽  
Inertial Measurement Unit ◽  
Indoor Environment ◽  
State Of The Art ◽  
Low Cost ◽  
Estimation Algorithm ◽  
Measurement Unit ◽  
3D Localization ◽  
Fast Motion ◽  
Tof Camera

SUMMARY Localization based on visual natural landmarks is one of the state-of-the-art localization methods for automated vehicles that is, however, limited in fast motion and low-texture environments, which can lead to failure. This paper proposes an approach to solve these limitations with an extended Kalman filter (EKF) based on a state estimation algorithm that fuses information from a low-cost MEMS Inertial Measurement Unit and a Time-of-Flight camera. We demonstrate our results in an indoor environment. We show that the proposed approach does not require any global reflective landmark for localization and is fast, accurate, and easy to use with mobile robots.

Bifunctional single-atomic Mn sites for energy-efficient hydrogen production

Nanoscale ◽  
2021 ◽  
Author(s):  
Xianyun Peng ◽  
Junrong Hou ◽  
Yuying Mi ◽  
Jiaqiang Sun ◽  
Gaocan Qi ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Energy Saving ◽  
Hydrogen Evolution Reaction ◽  
Energy Efficient ◽  
Low Cost ◽  
Clean Energy ◽  
H2 Production ◽  
Energy Technology ◽  
Highly Active ◽  
Clean Energy Technology

Electrocatalytic hydrogen evolution reaction (HER) for H2 production is essential for future renewable and clean energy technology. Screening energy-saving, low-cost, and highly active catalysts efficiently, however, is still a grand...

scholarly journals Single-Layer Line-Fed Broadband Microstrip Patch Antenna on Thin Substrates

Electronics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 37
Author(s):  
Roberto Vincenti Gatti ◽  
Riccardo Rossi ◽  
Marco Dionigi
Keyword(s):  
Patch Antenna ◽  
State Of The Art ◽  
Low Cost ◽  
Single Layer ◽  
Microstrip Antennas ◽  
Microstrip Patch Antenna ◽  
Layer Line ◽  
Limited Bandwidth ◽  
Microstrip Patch ◽  
Effective Design

In this work, the issue of limited bandwidth typical of microstrip antennas realized on a single thin substrate is addressed. A simple yet effective design approach is proposed based on the combination of traditional single-resonance patch geometries. Two novel shaped microstrip patch antenna elements with an inset feed are presented. Despite being printed on a single-layer substrate with reduced thickness, both radiators are characterized by a broadband behavior. The antennas are prototyped with a low-cost and fast manufacturing process, and measured results validate the simulations. State-of-the-art performance is obtained when compared to the existing literature, with measured fractional bandwidths of 3.71% and 6.12% around 10 GHz on a 0.508-mm-thick Teflon-based substrate. The small feeding line width could be an appealing feature whenever such radiating elements are to be used in array configurations.

Co3O4-CuCoO2 hybrid nanoplates as a low-cost and highly active catalyst for producing hydrogen from ammonia borane

2021 ◽  
Author(s):  
Yufa Feng ◽  
Jinyun Liao ◽  
Xiaodong Chen ◽  
Qingyu Liao ◽  
Huize Wang ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Active Catalyst ◽  
Low Cost ◽  
Ammonia Borane ◽  
Catalytic Materials ◽  
Highly Active ◽  
Promising Strategy

Developing low-cost and highly active hydrolysis catalytic materials for the dehydrogenation of hydrogen-rich chemicals is a promising strategy to store and easily release hydrogen for fuel cell applications. In this...

scholarly journals A Machine Vision Approach for Bioreactor Foam Sensing

2021 ◽  
pp. 247263032110088
Author(s):  
Jonas Austerjost ◽  
Robert Söldner ◽  
Christoffer Edlund ◽  
Johan Trygg ◽  
David Pollard ◽  
...  
Keyword(s):  
Machine Learning ◽  
Machine Vision ◽  
State Of The Art ◽  
Low Cost ◽  
High Accuracy ◽  
Consumer Electronics ◽  
Learning System ◽  
Automotive Applications ◽  
Fine Grained

Machine vision is a powerful technology that has become increasingly popular and accurate during the last decade due to rapid advances in the field of machine learning. The majority of machine vision applications are currently found in consumer electronics, automotive applications, and quality control, yet the potential for bioprocessing applications is tremendous. For instance, detecting and controlling foam emergence is important for all upstream bioprocesses, but the lack of robust foam sensing often leads to batch failures from foam-outs or overaddition of antifoam agents. Here, we report a new low-cost, flexible, and reliable foam sensor concept for bioreactor applications. The concept applies convolutional neural networks (CNNs), a state-of-the-art machine learning system for image processing. The implemented method shows high accuracy for both binary foam detection (foam/no foam) and fine-grained classification of foam levels.

A low-cost asymmetric carbazole-based hole-transporting material for efficient perovskite solar cells

2021 ◽  
Author(s):  
Xueqiao Li ◽  
Na Sun ◽  
Zhanfeng Li ◽  
Jinbo Chen ◽  
Qinjun Sun ◽  
...  
Keyword(s):  
Solar Cells ◽  
State Of The Art ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
The State ◽  
Hole Transporting ◽  
Hole Transporting Material

Perovskite solar cells (PSCs) have reached their highest efficiency with the state-of-the-art hole-transporting material (HTM) spiro-OMeTAD.

scholarly journals Superior Antireflection Coating for a Silicon Cell with a Micronanohybrid Structure

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Hsi-Chien Liu ◽  
Gou-Jen Wang
Keyword(s):  
Solar Cell ◽  
Silicon Solar Cell ◽  
Low Cost ◽  
Antireflection Coating ◽  
Light Spectrum ◽  
Two Stage ◽  
Liquid Diffusion ◽  
Pyramid Structure ◽  
Short Time ◽  
Structure Array

The object of this paper is to develop a high antireflection silicon solar cell. A novel two-stage metal-assisted etching (MAE) method is proposed for the fabrication of an antireflective layer of a micronanohybrid structure array. The processing time for the etching on an N-type high-resistance (NH) silicon wafer can be controlled to around 5 min. The resulting micronanohybrid structure array can achieve an average reflectivity of 1.21% for a light spectrum of 200–1000 nm. A P-N junction on the fabricated micronanohybrid structure array is formed using a low-cost liquid diffusion source. A high antireflection silicon solar cell with an average efficiency of 13.1% can be achieved. Compared with a conventional pyramid structure solar cell, the shorted circuit current of the proposed solar cell is increased by 73%. The major advantage of the two-stage MAE process is that a high antireflective silicon substrate can be fabricated cost-effectively in a relatively short time. The proposed method is feasible for the mass production of low-cost solar cells.

scholarly journals Catalytic Hydrogenation, Hydrodeoxygenation, and Hydrocracking Processes of a Lignin Monomer Model Compound Eugenol over Magnetic Ru/C–Fe2O3 and Mechanistic Reaction Microkinetics

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 425 ◽  
Author(s):  
Ana Bjelić ◽  
Miha Grilc ◽  
Sašo Gyergyek ◽  
Andraž Kocjan ◽  
Darko Makovec ◽  
...  
Keyword(s):  
Model Compound ◽  
Annealing Temperature ◽  
Low Cost ◽  
Value Added ◽  
Product Distribution ◽  
Surface Chemical ◽  
Annealing Temperatures ◽  
Microkinetic Model ◽  
Highly Active ◽  
Commercial Carbon

Conversion of waste lignocellulosic (LC) biomass, a widely-available low-cost feedstock, into value-added biobased chemicals (and biofuels) has been gaining much attention recently. Therefore, the present lignin valorisation study was aimed at developing magnetically-separable highly-active catalysts for hydrodeoxygenation (HDO), also proposing surface chemical kinetics. Five carbonaceous substrate-deposited Ru were synthesised and tested for the HDO of monomer moiety eugenol. Their annealing temperatures differed, specifically between 300 and 750 °C, while one was not subjected to calcination. Experiments revealed the substantial influence of annealing temperature on the product distribution. Namely, fresh nonannealed nanocomposites were not active for hydrogenolysis. By further pretreatment increase, hydrogenation and, exclusively, the deoxygenation of saturated cyclic species, were enhanced, these being more promoted considering rates and yields than commercial carbon-supported ruthenium. Over 80 mol% of 4-propyl-cylohexanol and propyl-cyclohexane could be formed over the samples, treated at 500 and 600 °C, for 100 and 125 min, respectively, under 275 °C and 5 MPa of reactor hydrogen pressure. Interestingly, a notable 4-propyl-phenol amount was produced upon 750 °C pretreating. The intrinsic microkinetic model, developed previously, was applied to determine relevant turnover parameters. Calculated modelling results indicated a 47- and 10-fold greater demethoxylation and dehydroxylation mechanism ability upon the reheatingpreheating at 600 °C in comparison to industrial (heterogeneous) Ru/C.

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