scholarly journals Catalytic Degradability of p-Nitrophenol Using Ecofriendly Silver Nanoparticles

Metals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1661
Author(s):  
Ganesh Shimoga ◽  
Ramasubba Reddy Palem ◽  
Soo-Hong Lee ◽  
Sang-Youn Kim

In an effort to produce non-toxic and economically viable “green” protocols for waste water treatment, researchers are actively involved to develop versatile and effective silver nanoparticles (SNPs) as nano-catalyst from bio-based techniques. Since, p-nitrophenol (PNP) is one of the anthropogenic contaminants, considerable attention has been focused in catalytic degradability of PNP in wastewater treatment by curtailing serious effect on aquatic fauna. Ingestion of contaminants by aquatic organisms will not only affect the aquatic species but is also a potential threat to human health, especially if the toxic contaminants are involved in food chain. In this short report, we provided a comprehensive insight on few remarkable nanocatalysts especially based on SNPs and its biopolymer composites synthesized via ecofriendly “green” route. The beneficiality and catalytic performance of these silver nanocatalysts are concisely documented on standard model degradation reduction of PNP to p-aminophenol (PAP) in the presence of aqueous sodium borohydride. The catalytic degradation of PNP to PAP using SNPs follows pseudo first order kinetics involving six-electrons with lower activation energy. Furthermore, we provided a list of highly effective, recoverable, and economically viable SNPs, which demonstrated its potential as nanocatalysts by focusing its technical impact in the area of water remediation.

2017 ◽  
Vol 41 (22) ◽  
pp. 13377-13381 ◽  
Author(s):  
Arijit Saha ◽  
Soumen Payra ◽  
Subhash Banerjee

Silica (SiO2) supported bimetallic copper/silver nanoparticles (Cu/Ag@SiO2NPs) were synthesized for clean oxidation of benzoins/benzyl alcohols. All the reactions were fast, clean and high yielding (95–99%) and the Cu/Ag@SiO2nano-catalyst was reused eight times without loss of its catalytic performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (99) ◽  
pp. 96573-96583 ◽  
Author(s):  
Raja Mohamed Sait Thameem Azarudeen ◽  
Marimuthu Govindarajan ◽  
Abubucker Amsath ◽  
Shine Kadaikunnan ◽  
Naiyf S. Alharbi ◽  
...  

As a low-cost and eco-friendly control tool, Ag nanoparticles were fabricated usingHedyotis puberulaaqueous extract as a reducing and capping agent and showed potent activity against malaria and arbovirus vectors with low biotoxicity against non-target aquatic organisms.


2017 ◽  
Vol 16 (01) ◽  
pp. 1650019 ◽  
Author(s):  
P. D. Jolhe ◽  
B. A. Bhanvase ◽  
V. S. Patil ◽  
S. H. Sonawane

The present work deals with the investigation of the greener route for the production of silver nanoparticles using Raphanus sativus (R. sativus) bioextract in a continuous flow tubular microreactor. The parameters affecting the particle size and distribution were investigated. From the results obtained it can be inferred that the ascorbic acid (reducing agent) present in the R. sativus bioextract is responsible for the reduction of silver ions. At optimum condition, the particle size distribution of nanoparticles is found between 18[Formula: see text]nm and 39[Formula: see text]nm. The absorbance value was found to be decreased with an increase in the diameter of the microreactor. It indicates that a number of nuclei are formed in the micrometer sized (diameter) reactor because of the better solute transfer rate leading to the formation of large number of silver nanoparticles. The study of antibacterial activity of green synthesized silver nanoparticles shows effective inhibitory activity against waterborne pathogens, Shegella and Listeria bacteria.


2019 ◽  
Vol 64 (5) ◽  
pp. 409-413 ◽  
Author(s):  
Sajjad SEDAGHAT ◽  
◽  
Elham ARSHADI ◽  
Parvin AFSHAR ◽  
Alireza NAFAR ◽  
...  

Author(s):  
Inbathamizh L ◽  
Kalpana V ◽  
Revathi Yadav K

With the increase in the potential applications of nanoparticles in pharma and various fields, nanoparticle research is attracting more attention. Though several chemical and physical methods are being used for the synthesis of metal nanoparticles, they are associated with several disadvantages. Couroupita guianensis is a traditional plant with medicinal values. The focus of the study was to follow a green chemistry route to synthesize silver nanoparticles (AgNPs) using the leaf extract of Couroupita guianensis as a reductant and stabilizing agent. The boiled aqueous leaf extract with silver nitrate solution on exposure to sunlight showed the maximum absorbance at 430nm indicating the synthesis of AgNPs. Ultra Violet (UV)-Visible spectroscopy, Scanning Electron Microscopy (SEM), and Fourier Transform Infrared spectroscopy (FTIR) techniques were used for the characterization of AgNPs. The synthesized AgNPs were found to be spherical and 4.44 – 40.20nm in size. They also seemed to be capped with the significant functional groups present in the leaf extract. Thus, the study suggested Couroupita guianensis mediated green synthesis of AgNPs as an efficient and eco-friendly approach with substantial advantages over the conventional methods. The process could be further scaled-up for mass production and wider applications of AgNPs.


Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1612
Author(s):  
Zhaoyu Wen ◽  
Qiong Fu ◽  
Jie Wu ◽  
Guangyin Fan

Simple and efficient synthesis of a nano-catalyst with an excellent catalytic property for hydrogen generation from hydrolysis of dimethyl amine-borane (DMAB) is a missing piece. Herein, effective and recycled palladium (Pd) nanoparticles (NPs) supported on soft nitriding porous carbon (NPC) are fabricated and applied for DMAB hydrolysis. It is discovered that the soft nitriding via a low-temperature urea-pretreatment induces abundant nitrogen-containing species on the NPC support, thus promoting the affinity of the Pd precursor and hindering the agglomeration of formed Pd NPs onto the NPC surface during the preparation process. Surface-clean Pd NPs with a diameter of sub-2.0 nm deposited on the NPC support (Pd/NPC) exhibit an outstanding catalytic performance with a turnover frequency (TOF) of 2758 h−1 toward DMAB hydrolysis, better than many previous reported Pd-based catalysts. It should be emphasized that the Pd/NPC also possesses a good stability without an obvious decrease in catalytic activity for DMAB hydrolysis in five successive recycling runs. This study provides a facile but efficient way for preparing high-performance Pd catalysts for catalytic hydrogen productions.


2014 ◽  
Vol 43 (40) ◽  
pp. 15138-15142 ◽  
Author(s):  
Emma Oakton ◽  
Gianvito Vilé ◽  
Daniel S. Levine ◽  
Eva Zocher ◽  
David Baudouin ◽  
...  

When X = SiMe3, small (2.1 ± 0.5 nm) densely packed silica-supported Ag particles can be prepared, which show an improved catalytic activity (per gram) whilst maintaining high alkene selectivity.


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