scholarly journals CO2 Utilization in the Ironmaking and Steelmaking Process

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 273 ◽  
Author(s):  
Kai Dong ◽  
Xueliang Wang

Study on the resource utilization of CO2 is important for the reduction of CO2 emissions to cope with global warming and bring a beneficial metallurgical effect. In this paper, research on CO2 utilization in the sintering, blast furnace, converter, secondary refining, continuous casting, and smelting processes of stainless steel in recent years in China is carried out. Based on the foreign and domestic research and application status, the feasibility and metallurgical effects of CO2 utilization in the ferrous metallurgy process are analyzed. New techniques are shown, such as (1) flue gas circulating sintering, (2) blowing CO2 through a blast furnace tuyere and using CO2 as a pulverized coal carrier gas, (3) top and bottom blowing of CO2 in the converter, (4) ladle furnace and electric arc furnace bottom blowing of CO2, (5) CO2 as a continuous casting shielding gas, (6) CO2 for stainless steel smelting, and (7) CO2 circulation combustion. The prospects of CO2 application in the ferrous metallurgy process are widespread, and the quantity of CO2 utilization is expected to be more than 100 kg per ton of steel, although the large-scale industrial utilization of CO2 emissions is just beginning. It will facilitate the progress of metallurgical technology effectively and promote the energy conservation of the metallurgical industry strongly.

Author(s):  
Kai Dong ◽  
Xueliang Wang

A overview on application of CO2 in the ironmaking and steelmaking process is presented. Study on resource utilization of CO2 is significant for the reduction of CO2 emissions and the coping with global warming. The paper introduces the research progress of CO2 utilization in the sintering, Blast Furnace, Converter, secondary refining, Continuous Casting and smelting process of stainless steel in recent years in China. According to the foreign and domestic research and application status, the paper analyzes the feasibility and metallurgical effects of the CO2 utilization in the ferrous metallurgy process. The paper mainly introduces such new techniques as 1) flue gas circulating sintering, 2) blowing CO2 through Blast Furnace tuyere and CO2 as a pulverized coal carrier gas, 3) top and bottom blowing CO2 in the converter, 4) Ladle Furnace and Electric Arc Furnace bottom blowing CO2, 5) CO2 as Continuous Casting shielding gas, 6) CO2 for stainless steel smelting, and 7) CO2 circulation combustion. CO2 has a very wide application prospect in ferrous metallurgy process and the quantity of CO2 utilization is expected to be 100kg per ton of steel. It will effectively facilitate the progress of metallurgical technology and strongly promote the energy conservation of metallurgical industry.


Atmosphere ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 811
Author(s):  
Yaqin Hu ◽  
Yusheng Shi

The concentration of atmospheric carbon dioxide (CO2) has increased rapidly worldwide, aggravating the global greenhouse effect, and coal-fired power plants are one of the biggest contributors of greenhouse gas emissions in China. However, efficient methods that can quantify CO2 emissions from individual coal-fired power plants with high accuracy are needed. In this study, we estimated the CO2 emissions of large-scale coal-fired power plants using Orbiting Carbon Observatory-2 (OCO-2) satellite data based on remote sensing inversions and bottom-up methods. First, we mapped the distribution of coal-fired power plants, displaying the total installed capacity, and identified two appropriate targets, the Waigaoqiao and Qinbei power plants in Shanghai and Henan, respectively. Then, an improved Gaussian plume model method was applied for CO2 emission estimations, with input parameters including the geographic coordinates of point sources, wind vectors from the atmospheric reanalysis of the global climate, and OCO-2 observations. The application of the Gaussian model was improved by using wind data with higher temporal and spatial resolutions, employing the physically based unit conversion method, and interpolating OCO-2 observations into different resolutions. Consequently, CO2 emissions were estimated to be 23.06 ± 2.82 (95% CI) Mt/yr using the Gaussian model and 16.28 Mt/yr using the bottom-up method for the Waigaoqiao Power Plant, and 14.58 ± 3.37 (95% CI) and 14.08 Mt/yr for the Qinbei Power Plant, respectively. These estimates were compared with three standard databases for validation: the Carbon Monitoring for Action database, the China coal-fired Power Plant Emissions Database, and the Carbon Brief database. The comparison found that previous emission inventories spanning different time frames might have overestimated the CO2 emissions of one of two Chinese power plants on the two days that the measurements were made. Our study contributes to quantifying CO2 emissions from point sources and helps in advancing satellite-based monitoring techniques of emission sources in the future; this helps in reducing errors due to human intervention in bottom-up statistical methods.


2021 ◽  
Vol 13 (4) ◽  
pp. 2225
Author(s):  
Ralf Peters ◽  
Janos Lucian Breuer ◽  
Maximilian Decker ◽  
Thomas Grube ◽  
Martin Robinius ◽  
...  

Achieving the CO2 reduction targets for 2050 requires extensive measures being undertaken in all sectors. In contrast to energy generation, the transport sector has not yet been able to achieve a substantive reduction in CO2 emissions. Measures for the ever more pressing reduction in CO2 emissions from transportation include the increased use of electric vehicles powered by batteries or fuel cells. The use of fuel cells requires the production of hydrogen and the establishment of a corresponding hydrogen production system and associated infrastructure. Synthetic fuels made using carbon dioxide and sustainably-produced hydrogen can be used in the existing infrastructure and will reach the extant vehicle fleet in the medium term. All three options require a major expansion of the generation capacities for renewable electricity. Moreover, various options for road freight transport with light duty vehicles (LDVs) and heavy duty vehicles (HDVs) are analyzed and compared. In addition to efficiency throughout the entire value chain, well-to-wheel efficiency and also other aspects play an important role in this comparison. These include: (a) the possibility of large-scale energy storage in the sense of so-called ‘sector coupling’, which is offered only by hydrogen and synthetic energy sources; (b) the use of the existing fueling station infrastructure and the applicability of the new technology on the existing fleet; (c) fulfilling the power and range requirements of the long-distance road transport.


2021 ◽  
Vol 13 (11) ◽  
pp. 5957
Author(s):  
Tomas Mauder ◽  
Michal Brezina

Production of overall CO2 emissions has exhibited a significant reduction in almost every industry in the last decades. The steelmaking industry is still one of the most significant producers of CO2 emissions worldwide. The processes and facilities used at steel plants, such as the blast furnace and the electric arc furnace, generate a large amount of waste heat, which can be recovered and meaningfully used. Another way to reduce CO2 emissions is to reduce the number of low-quality steel products which, due to poor final quality, need to be scrapped. Steel product quality is strongly dependent on the continuous casting process where the molten steel is converted into solid semifinished products such as slabs, blooms, or billets. It was observed that the crack formation can be affected by the water cooling temperature used for spray cooling which varies during the year. Therefore, a proper determination of the cooling water temperature can prevent the occurrence of steel defects. The main idea is based on the utilization of the waste heat inside the steel plant for preheating the cooling water used for spray cooling in the Continuous Casting (CC) process in terms of water temperature stabilization. This approach can improve the quality of steel and contribute to the reduction of greenhouse gas emissions. The results show that, in the case of billet casting, a reduction in the cooling water consumption can be also reached. The presented tools for achieving these goals are based on laboratory experiments and on advanced numerical simulations of the casting process.


2010 ◽  
Vol 650 ◽  
pp. 9-16 ◽  
Author(s):  
Zhi Jia Huang ◽  
Xiao Ding ◽  
Hao Sun ◽  
Si Yue Liu

The amount of CO2 emissions from steelworks accounts for a great share of the total CO2 emissions from industry in China. Thus, reducing CO2 emissions from steelworks is urgent for China’s environmental protection and sustainable development. This study aims at identifying factors that influence CO2 emissions from steelworks and proposing measures to reduce CO2 emissions. The life cycle inventory (LCI) of iron and steel products implies the relationship between the CO2 emissions of the steelworks and the input variables of the LCI. The Tornado Chart Tool is utilized to calculate the variation of CO2 emissions caused by the change of each input variables of LCI. Then, mean sensitivity of each input variable is calculated and the ranking criterion developed is used to identify the main factors influencing the integrated steelworks. Subsequently, measures for reducing CO2 emissions are proposed. The results indicate that the very important influencing factors of CO2 emissions in steelworks are the CO2 emission factor of Blast Furnace Gas (BFG), liquid steel unit consumption of continuous casting, continuous casting slab unit consumption of hot rolling and hot metal ratio of steelmaking. Consequently, many efficient measures for reducing CO2 emissions have been proposed, such as removing CO2 contained in BFG, decreasing the hot metal ratio of Basic Oxygen Furnace (BOF), recycling BFG, optimizing the products’ structure, etc.


Author(s):  
Volodymyr Bondarenko ◽  
◽  
Oleksandr Filonenko ◽  
Mykhailo Petlovanyi ◽  
Vladyslav Ruskykh ◽  
...  

Purpose. Experimental studies of the interaction of blast-furnace and steel-making slags with open pit waters during their direct contact and assessment of the volume of filling of the formed man-made cavities during mining of mineral deposits. Methods. Based on the analysis, the current low level of metallurgical slag and the lack of real and effective directions of their large-scale utilization were determined. The laboratory studies of the interaction of metallurgical slags with open pit water at a certain time of interaction, generally accepted methods for studying the chemical composition and concentration of substances in water, computer-aided design software packages and drawings to determine the volumes of the open pit mined-out area were used. Results. The dynamics of changes in the products of interactions of steel-smelting slags with open-pit waters at a certain ratio and period of interaction was investigated. It was found that the concentration of pollutants upon contact of water with steel-making slag changes according to polynomial dependences on the time of their interaction, decreasing by the 30th day, which eliminates the danger for the aquifer. The safest type of metallurgical slag was recommended for the formation of the bottom layer of the backfill massif. The volumes of the mined-out area of the open pit were determined in detail to assess the volumes of placement of the backfill material based on metallurgical slags. Scientific novelty. The safety of the contact of backfill materials based on steelmaking slags with open pit water was scientifically proven, which is confirmed by the established polynomial patterns of changes in concentrations and pollutants from the ratio and time of interaction. Practical significance. The formation of the backfill massif on the basis of blast-furnace dump and steel-smelting slags will allow achieving an environmental effect, such as their safe disposal as a reclamation of technologically disturbed lands by mining and restoration of the economic value of the land plot, as well as preventing the formation of new dumps.


Author(s):  
Huijuan Wang ◽  
Sha Bai ◽  
Pu Zhao ◽  
Tian Li ◽  
Chenjun Ning ◽  
...  

Synthesis of syngas (CO, H2) by photocatalytic reduction of CO2 and H2O represents an eco-friendly pathway for large-scale CO2 utilization for the production of chemical raw materials with high added...


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