scholarly journals Application of the Mineralogy and Mineral Chemistry of Carbonates as a Genetic Tool in the Hydrothermal Environment

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 822
Author(s):  
Javier Carrillo-Rosúa ◽  
Salvador Morales-Ruano ◽  
Stephen Roberts ◽  
Diego Morata ◽  
Mauricio Belmar
Keyword(s):  
Mineral Chemistry ◽  
Hydrothermal Systems ◽  
Low Grade ◽  
Geochemical Exploration ◽  
Epithermal Deposits ◽  
Genetic Tool ◽  
Isotopic Studies ◽  
Mn Content ◽  
Higher Temperature ◽  
Hydrothermal Environment

The mineralogy and mineral chemistry of carbonates from various hydrothermal deposits, including volcanic-hosted Au-Cu epithermal, “Chilean Manto-type” Cu(-Ag), stratabound Mn, and Ag-Ba vein deposits from Spain and Chile, were investigated. Dolomite-ankerite (±siderite) was found in variable amounts within the epithermal deposits and associated hydrothermal alteration, whereas calcite was found either within barren veins or disseminated within the regional alteration. Calcite is the major gangue phase within the stratabound deposits, which tend to lack dolomite/ankerite and siderite. Carbonates precipitated from hydrothermal ore fluids are typically Mn-rich, up to 3.55 at. % in siderite, 2.27 at. % in dolomite/ankerite, and 1.92 at. % in calcite. In contrast, calcite related to very low-grade metamorphism or regional low-temperature alteration is Mn-poor but sometimes Mg-rich, possibly related to a higher temperature of formation. Chemical zonation was observed in the hydrothermal carbonates, although no unique pattern and chemical evolution was observed. This study suggests that the chemical composition of carbonates, especially the Mn content, could be a useful vector within ore-forming hydrothermal systems, and therefore constitutes a possible tool in geochemical exploration. Furthermore, Mn-poor calcites detected in some deposits are suggested to be linked with a later episode, maybe suggesting a predominance of meteoric waters, being not related to the main ore stage formation, thus avoiding misunderstanding of further isotopic studies.

scholarly journals Mineralogical and Geochemical Signatures of Metalliferous Sediments in Wocan-1 and Wocan-2 Hydrothermal Sites on the Carlsberg Ridge, Indian Ocean

Minerals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 26 ◽  
Author(s):  
Samuel Olatunde Popoola ◽  
Xiqiu Han ◽  
Yejian Wang ◽  
Zhongyan Qiu ◽  
Ying Ye ◽  
...  
Keyword(s):  
Indian Ocean ◽  
Volcanic Glass ◽  
Mineral Chemistry ◽  
Hydrothermal Systems ◽  
Bulk Sediment ◽  
Sediment Samples ◽  
Metalliferous Sediments ◽  
Metalliferous Sediment ◽  
Carlsberg Ridge ◽  
Hydrothermal Environments

In this paper, we conduct a comparative study on the mineralogy and geochemistry of metalliferous sediment collected near the active hydrothermal site (Wocan-1) and inactive hydrothermal site (Wocan-2) from Wocan Hydrothermal Field, on the Carlsberg Ridge (CR), northwest Indian Ocean. We aim to understand the spatial variations in the primary and post-depositional conditions and the intensity of hydrothermal circulations in the Wocan hydrothermal systems. Sediment samples were collected from six stations which includes TVG-07, TVG-08 (Wocan-1), TVG-05, TVG-10 (Wocan-2), TVG-12 and TVG-13 (ridge flanks). The mineralogical investigations show that sediment samples from Wocan-1 and Wocan-2 are composed of chalcopyrite, pyrite, sphalerite, barite, gypsum, amorphous silica, altered volcanic glass, Fe-oxides, and hydroxides. The ridge flank sediments are dominated by biogenic calcite and foraminifera assemblages. The bulk sediment samples of Wocan-1 have an elevated Fe/Mn ratio (up to ~1545), with lower U contents (<7.4 ppm) and U/Fe ratio (<~1.8 × 10−5). The sulfide separates (chalcopyrite, pyrite, and sphalerite) are enriched in Se, Co, As, Sb, and Pb. The calculated sphalerite precipitation temperature (Sph.PT) yields ~278 °C. The sulfur isotope (δ34S) analysis returned a light value of 3.0–3.6‰. The bulk sediment samples of Wocan-2 have a lower Fe/Mn ratio (<~523), with high U contents (up to 19.6 ppm) and U/Fe ratio (up to ~6.2 × 10−5). The sulfide separates are enriched in Zn, Cu, Tl, and Sn. The calculated Sph.PT is ~233 °C. The δ34S returned significant values of 4.1–4.3‰ and 6.4–8.7‰ in stations TVG-10 and TVG-05, respectively. The geochemical signatures (e.g., Fe/Mn and U/Fe ratio, mineral chemistry of sulfides separates, and S-isotopes and Sph.PT) suggest that sediment samples from Wocan-1 are located near intermediate–high temperature hydrothermal discharge environments. Additionally, relatively low δ34S values exhibit a lower proportion (less than 20%) of seawater-derived components. The geochemical signatures suggest that sediment samples from Wocan-2 has undergone moderate–extensive oxidation and secondary alterations by seawater in a low–intermediate temperature hydrothermal environments. Additionally, the significant δ34S values of station TVG-05 exhibit a higher estimated proportion (up to 41%) of seawater-derived components. Our results showed pervasive hydrothermal contributions into station TVG-08 relative to TVG-07, it further showed the increased process of seafloor weathering at TVG-05 relative to TVG-10.

Study of Low-Grade Nickel Laterite Processing Using Palm Shell Charcoal as Reductant

2020 ◽  
Vol 1000 ◽  
pp. 436-446
Author(s):  
Bambang Suharno ◽  
Nolzha Primadha Ilman ◽  
Achmad Shofi ◽  
Deni Ferdian ◽  
Fajar Nurjaman
Keyword(s):  
Sodium Sulfate ◽  
Selective Reduction ◽  
Reduction Process ◽  
Low Grade ◽  
X Ray Diffraction ◽  
X Ray ◽  
Palm Shell ◽  
Higher Temperature ◽  
Nickel Grade

This study was conducted to investigate the effect of palm shell charcoal reductant in the selective reduction of nickel ore with the addition of additive at various temperatures and times. In this present work, 10 wt. % of sodium sulfate as additive and 5, 10, 15 wt. % of palm shell charcoal as reductants were used. The reduction of nickel ore was performed at 950oC, 1050oC, and 1150oC for 60, 90, and 120 minutes. A wet magnetic separation method was then carried out to separate the concentrates and tailings. Characterization of reduced ore was performed by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) with Energy Dispersive X-ray Spectroscopy (EDS), while the composition of ferronickel in concentrate was identified by X-Ray Fluorescence (XRF). The result showed that the higher temperature reduction, the higher of nickel grade, and its recovery at the concentrate. Nevertheless, the longer reduction time and the more reductant in nickel ore lowering the nickel grade and its recovery in the concentrate. The optimum condition in this selective reduction process was obtained with the addition of 5 wt. % of reductant and 10 wt. % of sodium sulfate in nickel ore, which was reduced at 1150oC for 60 minutes. It resulted in 4.60% and 73.23% for nickel grade and its recovery, respectively.

Very low-grade secondary minerals as indicators of palaeo-hydrothermal systems in the Upper Cretaceous volcanic succession of Hannah Point, Livingston Island, Antarctica

2016 ◽  
Vol 134 ◽  
pp. 246-256 ◽  
Author(s):  
Joaquin Bastias ◽  
Francisco Fuentes ◽  
Luis Aguirre ◽  
Francisco Hervé ◽  
Alain Demant ◽  
...  
Keyword(s):  
Upper Cretaceous ◽  
Hydrothermal Systems ◽  
Low Grade ◽  
Secondary Minerals ◽  
Livingston Island ◽  
Volcanic Succession

Effect of Temperature on Column Bioleaching of a Refractory Gold Ore

2013 ◽  
Vol 825 ◽  
pp. 352-355 ◽  
Author(s):  
Zeng Ling Wu ◽  
Zhong Sheng Huang ◽  
Ren Man Ruan ◽  
Shui Ping Zhong ◽  
Brenda K.C. Chan
Keyword(s):  
Sulfide Oxidation ◽  
Effect Of Temperature ◽  
Low Grade ◽  
Key Factors ◽  
Gold Extraction ◽  
Gold Ores ◽  
Fraction Distribution ◽  
Higher Temperature ◽  
Liberation Analysis ◽  
Main Factor

Low-grade, finely disseminated refractory sulfide gold ores associated with high arsenic are ubiquitous resources all over the world. Since heap bio-oxidation is an economic and promising biotechnology to recover gold, low grade, high organic carbon and arsenic bearing gold ores from Zhesang Mines in China were chosen for this purpose to study the key factors that would affect biooxidation. Pyrite and arsenopyrite (particle size 0.002-0.22 mm) were the main minerals from Mineral Liberation Analysis (MLA). Column biooxidation and cyanidation of mineral size < 10 mm were evaluated for its potential for gold extraction. Results showed that temperature was the main factor influencing sulfide oxidation. 58-67 % of sulfide was oxidized at 35-45°C after > 240 days of biooxidation with mixed mesophiles, while higher sulfide-S dissolution (77%) was obtained at 60°C. Sulfide-S fraction distribution revealed higher mineral decomposition, finer fractions and eventually higher sulfide oxidation at 60°C. Jarosite and scorodite were found from the residues at 60°C by SEM and EDX, which implies higher temperature accelerated arsenic precipitation. No elemental sulfur was detected during the biooxidation at 35-60°C. After bio-oxidation, column cyanidation was successfully demonstrated recovery of gold from the residues, with gold extraction rate reaching 66%.

scholarly journals PLUMBIAN "ALUNITES" IN HYDROTHERMAL ALTERATION ZONES OF EPITHERMAL AND PORPHYRY TYPE MINERALIZATIONS IN W. THRACE

2004 ◽  
Vol 36 (1) ◽  
pp. 492 ◽  
Author(s):  
Π. Βουδούρης ◽  
Κ. Αρίκας ◽  
Α. Κατερινόπουλος
Keyword(s):  
Hydrothermal Alteration ◽  
Solid Solutions ◽  
Mineral Chemistry ◽  
Alteration Zones ◽  
Hydrothermal Alteration Zones ◽  
Hydrothermal Environment

In this study a new occurrence of Pb-rich members of the alunite supergroup minerals is described. The "alunites" were traced in advanced argilic alteration zones of epithermal and porphyry type mineralizations in W. Thrace/(Greece). These "alunites" are Ca-Sr-Ba-Pb-rich phosphatessulfates and represent solid solutions between members of the alunite, woodhouseite and crandallite group minerals. The highest concentrations of PbO in the Mavrokoryfi and Melitaina alunites are 24.7% and 17.4% respectively. The plumbian phosphates-sulfates occur in the cores of the crystals and are surrounded by common K-Na-rich alunites in Mavrokoryfi and Ba-rich woodhouseite in Melitena, an indication that they were formed in a magmatic-hydrothermal environment after dissolution of apatite and feldspars by phosphate-sulphate rich solutions. The mineral-chemistry of these "alunites" can provide information regarding the genesis of the advanced argilic alteration zones in Greece, and help us in the distinction of the epithermal from deep porphyry style environments.

scholarly journals Changes in Halogen (F, Cl, Br, and I) and S Ratios in Rock-Forming Minerals as Monitors for Magmatic Differentiation, Volatile-Loss, and Hydrothermal Overprint: The Case for Peralkaline Systems

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 995 ◽  
Author(s):  
Hans G.M. Eggenkamp ◽  
Michael A.W. Marks ◽  
Petya Atanasova ◽  
Thomas Wenzel ◽  
Gregor Markl
Keyword(s):  
Mineral Chemistry ◽  
Hydrothermal Systems ◽  
Fluid Loss ◽  
Volatile Components ◽  
Compositional Variation ◽  
Magmatic Differentiation ◽  
Charge Balance ◽  
Rock Interaction ◽  
Eudialyte Group ◽  
Volatile Loss

We determined the halogen (F, Cl, Br, and I) and sulfur (S) concentrations in Cl-rich rock-forming minerals from five peralkaline complexes. We investigated sodalite (N = 42), eudialyte-group minerals (N = 84), and tugtupite (N = 8) from representative rock samples derived from Ilímaussaq (South Greenland), Norra Kärr (Sweden), Tamazeght (Morocco), Lovozero, and Khibina (Russian Federation). Taken together, sodalite and eudialyte-group minerals dominate the Cl and Br budget of the investigated rocks. For F, however, several other phases (e.g., amphibole, fluorite, villiaumite, and minerals of the rinkite group and the apatite supergroup) are additional sinks, and parts of the S may be scavenged in generally rare sulfides. The investigated minerals contain Cl at the wt.% level, F and S concentrations are in the hundreds to thousands of µg/g-range, Br is less common (0.2–200 µg/g) and I is rare (mostly well below 1 µg/g). Normalized to Cl, sodalite prefers Br relative to eudialyte-group minerals, while F is always enriched in the latter. Our data show that both F and S may represent important components in eudialyte-group minerals, sometimes at similar levels as Cl, which normally dominates. Sulfur reveals redox-dependent behavior: Under reduced crystallization conditions, S is more compatible in eudialyte-group minerals (EGM) than in sodalite, which flips to the opposite under water-rich and presumably more oxidized conditions. We investigate the applicability of F/Cl, Br/Cl, and S/Cl ratios in these minerals in peralkaline systems to better understand the interplay of magmatic differentiation, fluid loss and hydrothermal overprint. Similar to apatite in metaluminous systems, fractionation of sodalite, and eudialyte-group minerals in peralkaline magmas leads to decreasing Br/Cl ratios. The data presented in this study bear implications for the mineral chemistry and compositional variation of sodalite and especially EGM in general. Volatile components in EGM that are not normally considered, such as F and S, can reach concentrations of thousands of µg/g. Especially in the case of F, with its low atomic weight, the results obtained in this study indicate that it is very significant for formulae calculations, neutral charge-balance, and similar aspects at such concentration levels. This study demonstrates that halogen contents and ratios are sensitive monitors for a variety of processes in magmatic-hydrothermal systems, including magmatic fractionation, volatile loss, and fluid–rock interaction.

Chlorite and Epidote Mineral Chemistry in Porphyry Ore Systems: A Case Study of the Northparkes District, New South Wales, Australia

2020 ◽  
Vol 115 (4) ◽  
pp. 701-727 ◽  
Author(s):  
Adam Pacey ◽  
Jamie J. Wilkinson ◽  
David R. Cooke
Keyword(s):  
New South ◽  
New South Wales ◽  
Mineral Chemistry ◽  
Ore Deposits ◽  
Low Grade ◽  
South Wales ◽  
Spatial Trends ◽  
Propylitic Alteration ◽  
Mineral Partitioning

Abstract Propylitic alteration, characterized by the occurrence of chlorite and epidote, is typically the most extensive and peripheral alteration facies developed around porphyry ore deposits. However, exploration within this alteration domain is particularly challenging, commonly owing to weak or nonexistent whole-rock geochemical gradients and the fact that similar assemblages can be developed in other geologic settings, particularly during low-grade metamorphism. We document and interpret systematic spatial trends in the chemistry of chlorite and epidote from propylitic alteration around the E48 and E26 porphyry Cu-Au deposits of the Northparkes district, New South Wales, Australia. These trends vary as a function of both distance from hydrothermal centers and alteration paragenesis. The spatial trends identified in porphyry-related chlorite and epidote at Northparkes include (1) a deposit-proximal increase in Ti, As, Sb, and V in epidote and Ti in chlorite, (2) a deposit-distal increase in Co and Li in chlorite and Ba in epidote, and (3) a pronounced halo around deposits in which Mn and Zn in chlorite, as well as Mn, Zn, Pb, and Mg in epidote, are elevated. Chlorite Al/Si ratios and epidote Al/Fe ratios may show behavior similar to that of Mn-Zn or may simply decrease outward, and V and Ni concentrations in chlorite are lowest in the peak Mn-Zn zone. In comparison to porphyry-related samples, chlorite from the regional metamorphic assemblage in the district contains far higher concentrations of Li, Ca, Ba, Pb, and Cu but much less Ti. Similarly, metamorphic epidote contains higher concentrations of Sr, Pb, As, and Sb but less Bi and Ti. These chlorite and epidote compositional trends are the net result of fluid-mineral partitioning under variable physicochemical conditions within a porphyry magmatic-hydrothermal system. They are most easily explained by the contribution of spent magmatic-derived ore fluid(s) into the propylitic domain. It is envisaged that such fluids experience progressive cooling and reduction in fs2 during outward infiltration into surrounding country rocks, with their pH controlled by the extent of rock-buffering experienced along the fluid pathway.

Paragenesis and mineral chemistry of alabandite (MnS) from the Ag-rich Santo Toribio epithermal deposit, Northern Peru

2003 ◽  
Vol 67 (1) ◽  
pp. 95-102 ◽  
Author(s):  
G. R. Olivo ◽  
K. Gibbs
Keyword(s):  
High Salinity ◽  
Early Stage ◽  
Mineral Chemistry ◽  
Abrupt Decrease ◽  
Epithermal Deposits ◽  
Second Stage ◽  
The World ◽  
Northern Peru ◽  
World Class ◽  
Polymetallic Ore

AbstractThe Miocene, epithermal, Ag-rich polymetallic Santo Toribio deposit is hosted by the volcanics of the Quiruvilva-Pierina subbelt, Northern Peru, which also comprises the world-class, high sulphidation Pierina deposit. The Ag-rich, alabandite-bearing veins of the Santo Toribio deposit formed during two major stages. The early stage is characterized by deposition of arsenopyrite, pyrite, quartz, Mn- sphalerite, stannite, alabandite and minor miargyrite. Sphalerite associated with this stage is exceptionally enriched in Mn (up to 14.5 wt.%) and alabandite is optically and mineralogically zoned. Its brown zones have greater Fe+Sb and smaller Mn contents than the green zones and Fe+Sb replaces Mn in its structure. During this early stage, fs2 must have been high to allow the stabilization of alabandite relative to rhodochrosite. In the second stage, the physicochemical conditions changed and the CO2/S ratio increased, causing dissolution of alabandite and the deposition of abundant rhodochrosite and a second generation of arsenopyrite, pyrite and quartz, sphalerite with chalcopyrite inclusions, mirargyrite, ramdohrite, and finally stibnite. This polymetallic ore probably formed due to an abrupt decrease in H+ and/or Cl- concentration caused by boiling or dilution of the high-salinity hydrothermal fluids and constitutes an example of “intermediate sulfidation-state” epithermal deposits.

scholarly journals ENVIRONMENTALLY SAFE USAGE OF HYDROPOWER POTENTIAL BY HYDROTHERMAL POWER SUPPLY SYSTEMS

2019 ◽  
pp. 67-75
Author(s):  
S. Goshovskyi ◽  
O. Zurian
Keyword(s):  
Heat Pump ◽  
Energy Systems ◽  
Hydrothermal Systems ◽  
Heat Energy ◽  
Operating Conditions ◽  
Small Rivers ◽  
Low Grade ◽  
Hydropower Potential ◽  
Environmentally Safe ◽  
Low Grade Heat

The article contains the results of scientific research and design work related to environmentally safe usage of hydropower potential of the small rivers of the Dnieper basin. The innovative design solutions for extraction of low-grade heat energy of water and systems for its transformation into energy convenient for consumption were offered. It was established that use of renewable low-grade energy of soil is widely used in environmentally safe and economically sound power systems. At the same time hydropower potential is not widely used in hydrothermal heat pump systems. It was proved that existing hydrothermal systems are not always adjusted to actual operating conditions and object location. The evidence was provided that the scientific approach to development of appropriate configuration of hydrothermal collector, to methodology of their optimal mounting and to efficiency determination depending on operating conditions is quite topical issue. The scientific novelty of the new process approach is use of special design of water collector that has modular configuration and consists of several functionally related water sondes. The efficiency of hydrothermal system was scientifically proved. The paper describes the results of experimental research of efficiency of hydrothermal heat pump system where the low-grade heat energy of water is used as a renewable primary heating energy source for functioning of the heat pump. The authors have developed experimental hydrothermal and geothermal heat pump systems to conduct the research. Both collector and ground section of the system have mounted sensors of temperature, pressure and coolant flow velocity. The software for archiving and visualization of obtained data was developed. The research procedure was developed. As part of study, observation data were received and performance efficiency of geothermal and hydrothermal systems was calculated. The comparative analysis of energy systems depending on used renewable energy source was carried out. The conclusion was made that use of hydrothermal heat pump systems is environmentally safe. The data obtained as part of study have great scientific and applied significance for engineering of heat pump energy systems using hydropower potential of the small rivers.

Adiabatic Absorption by Absorbent Atomization for Improving Absorption Heat Transformer Performance

2020 ◽  
Vol 142 (5) ◽  
Author(s):  
Yigal Evron ◽  
Khaled Gommed ◽  
Gershon Grossman
Keyword(s):  
Distribution System ◽  
Distribution Systems ◽  
Waste Heat ◽  
Heat Pumps ◽  
Low Grade ◽  
Liquid Distribution ◽  
Experimental Step ◽  
Higher Temperature ◽  
Future Work ◽  
Heat Transformer

Abstract Absorption heat transformers (AHTs) are a type of absorption heat pumps that are primarily driven by low-grade (typically waste) heat and produce higher temperature (high-grade) heat. Under the Indus3Es project, a 10 kW LiBr-H2O “Lab Scale” absorption heat transformer was built as a first experimental step toward larger scales. The focus was on the high-pressure vessel (HPV) (absorber and evaporator) design. To enhance performance, the aim was to obtain complete adiabatic absorption prior to the main absorption process accompanied by heat transfer. This maximizes the temperature within the absorber. This is particularly beneficial for absorption heat transformers, compared to chillers, because obtaining an elevated temperature is the objective. To obtain adiabatic absorption, atomizing spray nozzles were used as the liquid absorbent distribution system. This method proved successful; complete adiabatic absorption was obtained before the droplets contacted the absorber heat exchange surfaces. However, the spray nozzles must be supplied with pressurized liquid and are potentially more delicate than alternative liquid distribution systems. Therefore, future work may focus on determining the required atomization level to avoid excessive pressures and nozzle requirements.

Sign in / Sign up

Export Citation Format

Share Document