scholarly journals A Stretchable Pillararene-Containing Supramolecular Polymeric Material with Self-Healing Property

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2191
Author(s):  
Meng Zhao ◽  
Changjun Li ◽  
Xiaotao Shan ◽  
Huijing Han ◽  
Qiuhua Zhao ◽  
...  

Constructing polymeric materials with stretchable and self-healing properties arise increasing interest in the field of tissue engineering, wearable electronics and soft actuators. Herein, a new type of supramolecular cross-linker was constructed through host-guest interaction between pillar[5]arene functionalized acrylate and pyridinium functionalized acrylate, which could form supramolecular polymeric material via photo-polymerization of n-butyl acrylate (BA). Such material exhibited excellent tensile properties, with maximum tensile strength of 3.4 MPa and strain of 3000%, respectively. Moreover, this material can effectively dissipate energy with the energy absorption efficiency of 93%, which could be applied in the field of energy absorbing materials. In addition, the material showed self-healing property after cut and responded to competitive guest.

2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Junxian Zhou ◽  
Chuang Dong ◽  
Bingzhi Chen ◽  
Xu Niu

An improved pyramidal prefolded pattern was designed and applied to thin-walled tubes. This delicately designed pattern modularizes the tube to control the folding process and act as an inducer to trigger deformation modes with outstanding crushing performance. Dynamic crushing tests were conducted numerically; the simulation results reveal that the patterned square tube developed a deformation mode with shorter wavelength, better load consistencies, and higher energy-absorption efficiency (up to 29%) than that of the traditional counterpart. Moreover, geometric analysis was performed and structural improvements were conducted by applying the optimal geometric parameters onto an octagonal profile. The designed patterned octagonal tube collapsed into a highly efficient deformation mode known as diamond mode. Furthermore, the comparative results show that patterned octagonal tubes demonstrated an energy absorption up to 90.1% higher than that of a conventional square column while improving the geometric compliance. These findings enrich research on patterned tubes and provide new explorations for the development of high-performance energy-absorbing structures.


2008 ◽  
Vol 22 (09n11) ◽  
pp. 1730-1735 ◽  
Author(s):  
KUNIHARU USHIJIMA ◽  
DAI-HENG CHEN ◽  
HIRONOBU NISITANI

In this paper, a new type of honeycomb structure is proposed to enhance the energy absorption capacity for a honeycomb structure, and investigated its energy absorption efficiency (absorbed energy per unit volume) by finite element method (FEM). This model has small arc-shaped parts on the double cell wall, and can be manufactured by a similar way of standard honeycomb structures. Also, the proposed structure has large rigidity of plastic bending without increasing the mass. In this paper, effects of geometrical properties on the energy absorption characteristics are discussed.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 869
Author(s):  
Minghua Wei ◽  
Shaopeng Wu ◽  
Haiqin Xu ◽  
Hechuan Li ◽  
Chao Yang

Steel slag is the by-product of the steelmaking industry, the negative influences of which prompt more investigation into the recycling methods of steel slag. The purpose of this study is to characterize steel slag filler and study its feasibility of replacing limestone filler in asphalt concrete by evaluating the resistance of asphalt mastic under various aging methods. Firstly, steel slag filler, limestone filler, virgin asphalt, steel slag filler asphalt mastic and limestone filler asphalt mastic were prepared. Subsequently, particle size distribution, surface characterization and pore characterization of the fillers were evaluated. Finally, rheological property, self-healing property and chemical functional groups of the asphalt mastics with various aging methods were tested via dynamic shear rheometer and Fourier transform infrared spectrometer. The results show that there are similar particle size distributions, however, different surface characterization and pore characterization in the fillers. The analysis to asphalt mastics demonstrates how the addition of steel slag filler contributes to the resistance of asphalt mastic under the environment of acid and alkaline but is harmful under UV radiation especially. In addition, the pore structure in steel slag filler should be a potential explanation for the changing resistance of the asphalt mastics. In conclusion, steel slag filler is suggested to replace limestone filler under the environment of acid and alkaline, and environmental factor should be taken into consideration when steel slag filler is applied to replace natural fillers in asphalt mastic.


2021 ◽  
Vol 28 (3) ◽  
Author(s):  
Chenghao Dai ◽  
Xijuan Cao ◽  
Kai Gou ◽  
Qiyan Yin ◽  
Binjie Du ◽  
...  

Author(s):  
Chao Zhou ◽  
Juntao Zhou ◽  
Xiaoqing Ma ◽  
Dicky Pranantyo ◽  
Jingjing Li ◽  
...  

Soft Matter ◽  
2021 ◽  
Author(s):  
Yuxing Shan ◽  
shuai liang ◽  
Xiangkai Mao ◽  
Jie Lu ◽  
Lili Liu ◽  
...  

Abstract. Stretchable elastomers with superhydrophobic surfaces have potential applications in wearable electronics. However, various types of damage inevitably occur on these elastomers in actual application, resulting in deterioration of the...


2008 ◽  
Vol 136 ◽  
pp. 39-44 ◽  
Author(s):  
Willy C.K. Tan ◽  
J.C. Kiew ◽  
K.Y. Siow ◽  
Z.R. Sim ◽  
H.S. Poh ◽  
...  

When one cut himself, it's amazing to watch how quickly the body acts to mend the wound. Immediately, the body works to pull the skin around the cut back together. The concept of repair by bleeding of enclosed functional agents serves as the biomimetric inspiration of synthetic self repair systems. Such synthetic self repair systems are based on advancement in polymeric materials; the process of human thrombosis is the inspiration for the application of self healing fibres within the composite materials. Preliminary results based on flexural 3 point bend test on prepared samples have shown the healed hollow fibre laminate has a healed strength increase of 47.6% compared to the damaged baseline laminate. These results gave us confidence that there is a great potential to adopt such self healing mechanism on actual composite parts like in aircraft’s composite structures.


Author(s):  
Mengyan Shi ◽  
Jiayao Ma ◽  
Yan Chen ◽  
Zhong You

Thin-walled tubes as energy absorption devices are widely in use for their low cost and high manufacturability. Employing origami technique on a tube enables induction of a predetermined failure mode so as to improve its energy absorption efficiency. Here we study the energy absorption of a hexagonal tubular device named the origami crash box numerically and theoretically. Numerical simulations of the quasi-static axial crushing show that the pattern triggers a diamond-shaped mode, leading to a substantial increase in energy absorption and reduction in initial peak force. The effects of geometric parameters on the performance of the origami crash box are also investigated through a parametric study. Furthermore, a theoretical study on the deformation mode and energy absorption of the origami crash box is carried out, and a good match with numerical results is obtained. The origami crash box shows great promise in the design of energy absorption devices.


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