scholarly journals Performance Evaluation of Enzyme Breaker for Fracturing Applications under Simulated Reservoir Conditions

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3133
Author(s):  
Yuling Meng ◽  
Fei Zhao ◽  
Xianwei Jin ◽  
Yun Feng ◽  
Gangzheng Sun ◽  
...  

Fracturing fluids are being increasingly used for viscosity development and proppant transport during hydraulic fracturing operations. Furthermore, the breaker is an important additive in fracturing fluid to extensively degrade the polymer mass after fracturing operations, thereby maximizing fracture conductivity and minimizing residual damaging materials. In this study, the efficacy of different enzyme breakers was examined in alkaline and medium-temperature reservoirs. The parameters considered were the effect of the breaker on shear resistance performance and sand-suspending performance of the fracturing fluid, its damage to the reservoir after gel breaking, and its gel-breaking efficiency. The experimental results verified that mannanase II is an enzyme breaker with excellent gel-breaking performance at medium temperatures and alkaline conditions. In addition, mannanase II did not adversely affect the shear resistance performance and sand-suspending performance of the fracturing fluid during hydraulic fracturing. For the same gel-breaking result, the concentration of mannanase II used was only one fifth of other enzyme breakers (e.g., mannanase I, galactosidase, and amylase). Moreover, the amount of residue and the particle size of the residues generated were also significantly lower than those of the ammonium persulfate breaker. Finally, we also examined the viscosity-reducing capability of mannanase II under a wide range of temperatures (104–158 °F) and pH values (7–8.5) to recommend its best-use concentrations under different fracturing conditions. The mannanase has potential for applications in low-permeability oilfield development and to maximize long-term productivity from unconventional oilwells.

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1783
Author(s):  
Klaudia Wilk-Zajdel ◽  
Piotr Kasza ◽  
Mateusz Masłowski

In the case of fracturing of the reservoirs using fracturing fluids, the size of damage to the proppant conductivity caused by treatment fluids is significant, which greatly influence the effective execution of hydraulic fracturing operations. The fracturing fluid should be characterized by the minimum damage to the conductivity of a fracture filled with proppant. A laboratory research procedure has been developed to study the damage effect caused by foamed and non-foamed fracturing fluids in the fractures filled with proppant material. The paper discusses the results for high quality foamed guar-based linear gels, which is an innovative aspect of the work compared to the non-foamed frac described in most of the studies and simulations. The tests were performed for the fracturing fluid based on a linear polymer (HPG—hydroxypropyl guar, in liquid and powder form). The rheology of nitrogen foamed-based fracturing fluids (FF) with a quality of 70% was investigated. The quartz sand and ceramic light proppant LCP proppant was placed between two Ohio sandstone rock slabs and subjected to a given compressive stress of 4000–6000 psi, at a temperature of 60 °C for 5 h. A significant reduction in damage to the quartz proppant was observed for the foamed fluid compared to that damaged by the 7.5 L/m3 natural polymer-based non-foamed linear fluid. The damage was 72.3% for the non-foamed fluid and 31.5% for the 70% foamed fluid, which are superior to the guar gum non-foamed fracturing fluid system. For tests based on a polymer concentration of 4.88 g/L, the damage to the fracture conductivity by the non-foamed fluid was 64.8%, and 26.3% for the foamed fluid. These results lead to the conclusion that foamed fluids could damage the fracture filled with proppant much less during hydraulic fracturing treatment. At the same time, when using foamed fluids, the viscosity coefficient increases a few times compared to the use of non-foamed fluids, which is necessary for proppant carrying capacities and properly conducted stimulation treatment. The research results can be beneficial for optimizing the type and performance of fracturing fluid for hydraulic fracturing in tight gas formations.


2012 ◽  
Vol 602-604 ◽  
pp. 1238-1242 ◽  
Author(s):  
Guan Jun Liu ◽  
Xiao Rui Li ◽  
Li Jun Zheng

An anionic surfactant clean fracturing fluid was synthesized and its main performance was studied. The viscosity of fracturing fluid increased with increasing dosage of anionic surfactant. And the viscosity of fracturing fluid increased first, and then decreased with increasing concentration of KCl. The viscosity reached maximum 360 mPa•s when the KCl content is 2.7%. The results showed that the fracturing fluid had best temperature resistance and shear resistance performance under the condition of 100°C and at the shearing rate of 170 s-1. The sedimentation velocity of sand in the fracturing fluid are about 11.124, 18.840 mm/min at the temperature of 80°C and 120°C respectively. It indicated that the fracturing fluid has a better sand-carrying performance. The viscosity of fracturing fluid decreased below 5 mPa•s during 70 minutes when the dosage of kerosene was 3%, and the surface tension of the breaker fluid is 26.10 mN/m while the interfacial tension is 0.73mN/m. The low surface tension can meet the requirements of operation. The damage rate to the core is 7.65% and the fracturing fluid has lower damage to core than guar gel.


1985 ◽  
Vol 25 (02) ◽  
pp. 157-170 ◽  
Author(s):  
R.A. Cutler ◽  
D.O. Enniss ◽  
A.H. Jones ◽  
S.R. Swanson

Abstract Lightweight, intermediate-strength proppants have been developed that are intermediate in cost between sand and bauxite. A wide variety of proppant materials is characterized and compared in a laboratory fracture conductivity study. Consistent sample preparation, test, and data reduction procedures were practiced, which allow a relative comparison of the conductivity of various proppants at intermediate and high stresses. Specific gravity, proppants at intermediate and high stresses. Specific gravity, corrosion resistance, and crush resistance of each proppant also were determined. proppant also were determined. Fracture conductivity was measured to a laminar flow of deaerated, deionized water over a closure stress range of 6.9 to 96.5 MPa [1,000 to 14,000 psi] in 6.9-MPa [1,000-psi] increments. Testing was performed at a constant 50 degrees C [122 degrees F] temperature. Results of the testing are compared with values from the literature and analyzed to determine proppant acceptability in the intermediate and high closure stress regions. Fracture strengths for porous and solid proppants agree well with calculated values. Several oxide ceramics were found to have acceptable conductivity at closure stresses to 96.5 MPa [14,000 psi]. Resin-coated proppants have lower conductivities than uncoated, intermediate-strength oxide proppants when similar size distributions are tested. Recommendations are made for obtaining valid conductivity data for use in proppant selection and economic analyses. proppant selection and economic analyses. Introduction Massive hydraulic fracturing (MHF) is used to increase the productivity of gas wells in low-permeability reservoirs by creating deeply penetrating fractures in the producing formation surrounding the well. Traditionally, producing formation surrounding the well. Traditionally, high-purity silica sand has been pumped into the created fracture to prop it open and maintain gas permeability after completing the stimulation. The relatively low cost, abundance, sphericity, and low specific gravity of high-quality sands (e.g., Jordan, St. Peters, and Brady formation silica sands) have made sand a good proppant for most hydraulic fracturing treatments. The closure stress on the proppants increases with depth, and even for selected high-quality sands the fracture conductivity has been found to deteriorate rapidly when closure stresses exceed approximately 48 MPa [7,000 psi]. Several higher-strength proppants have been developed to withstand the increased closure stress of deeper wells. Sintered bauxite, fused zirconia, and resin-coated sands have been the most successful higher-strength proppants introduced. These proppants have improved proppants introduced. These proppants have improved crush resistance and have been used successfully in MHF treatments. The higher cost of these materials as compared to sand has been the largest single factor inhibiting their widespread use. The higher specific gravity of bauxite and zirconia proppants not only increases the volume cost differential compared to sand but also enhances proppant settling. Lower-specific-gravity proppants not only are more cost effective but also have the potential to improve proppant transport. Novotny showed the effect of proppant diameter on settling velocity in non-Newtonian fluids and concluded that proppant settling may determine the success or failure of a hydraulic fracturing treatment. By using the same proppant settling equation as Novotny, the settling velocity of 20/40 mesh proppants is calculated for four different specific gravities and shown as a function of fluid shear rate in Fig. 1. The specific gravity of bauxite is 3.65 and sand is 2.65; therefore, bauxite is 37.7 % more dense than sand. The settling velocity for bauxite, as shown in Fig. 1, however, is approximately 65 % higher than sand. Work on proppants with specific gravities lower than bauxite was initiated to improve the transport characteristics of the proppant during placement. It has been demonstrated that vertical propagation of the fracture can be limited by reducing the fracturing fluid pressure. The viscosity range of existing fracturing pressure. The viscosity range of existing fracturing fluids makes minimizing fluid viscosity a much more effective method of controlling pressure than lowering the pumping rate. A potential advantage of decreasing the pumping rate. A potential advantage of decreasing the specific gravity of the proppant is that identical proppant transport to that currently achievable can take place in lower-viscosity fluids. (Alternatively, higher volumes of proppant can be pumped in a given amount of a proppant can be pumped in a given amount of a high-viscosity fracturing fluid.) Not only are low-viscosity fluids capable of allowing better fracture control, they are also less expensive. More importantly, it recently was shown that the conductivity of a created hydraulic fracture in the Wamsutter area is about one-tenth of that predicted by laboratory conductivity tests. P. 157


PLoS ONE ◽  
2021 ◽  
Vol 16 (12) ◽  
pp. e0260786
Author(s):  
Bhargavi Bhat ◽  
Shuhao Liu ◽  
Yu-Ting Lin ◽  
Martin L. Sentmanat ◽  
Joseph Kwon ◽  
...  

Hydraulic fracturing of unconventional reservoirs has seen a boom in the last century, as a means to fulfill the growing energy demand in the world. The fracturing fluid used in the process plays a substantial role in determining the results. Hence, several research and development efforts have been geared towards developing more sustainable, efficient, and improved fracturing fluids. Herein, we present a dynamic binary complex (DBC) solution, with potential to be useful in the hydraulic fracturing domain. It has a supramolecular structure formed by the self-assembly of low molecular weight viscosifiers (LMWVs) oleic acid and diethylenetriamine into an elongated entangled network under alkaline conditions. With less than 2 wt% constituents dispersed in aqueous solution, a viscous gel that exhibits high viscosities even under shear was formed. Key features include responsiveness to pH and salinity, and a zero-shear viscosity that could be tuned by a factor of ~280 by changing the pH. Furthermore, its viscous properties were more pronounced in the presence of salt. Sand settling tests revealed its potential to hold up sand particles for extended periods of time. In conclusion, this DBC solution system has potential to be utilized as a smart salt-responsive, pH-switchable hydraulic fracturing fluid.


2015 ◽  
Author(s):  
Jia Zhou ◽  
Paul Carman ◽  
Hong Sun ◽  
Richard Wheeler ◽  
Harold Brannon ◽  
...  

Abstract Post-treatment production analyses for hydraulic fracturing treatments with conventional crosslinked gel or slickwater often indicate that the treatments do not achieve the designed stimulation effectiveness, which could be attributed to non-optimal proppant placement and/or significantly damaged fracture conductivity. Although conventional crosslinked fluids are observed to provide good proppant suspension in laboratory environments, they might not provide the desired proppant transport under downhole conditions. Crosslinked fluids are known to be difficult to clean up, and thus are notorious for imparting gel damage to proppant pack and formation. Slickwater can be used to mitigate gel damage by reducing the effective polymer loadings, but consequential extreme proppant settling and banking problems reduce the chance of achieving fracture performance. Several proppant placement techniques have been developed to generate highly conductive paths for hydrocarbons to flow from an unconventional reservoir to the wellbore, such as hybrid fracturing, reverse hybrid fracturing, and channel fracturing, each of which predominantly rely upon high viscosity fluids to carry the proppant to the designated location. This paper presents a non-traditional fracturing fluid system and application technique with near perfect proppant suspension and transport, high fracture conductivity, and self-diverting characteristics. The revolutionary fracturing fluid system employs engineered packing of particle domains for proppant suspension mechanics that are significantly different from crosslinked polymer systems which use polymer chain overlap and inter-chain crosslinking to generate viscosity governed proppant transport. The unique gel particle structure perfectly suspends proppant for several hours at reservoir conditions to facilitate better transverse and vertical placement of proppant in the fracture and significantly increases the fractured surface area, which is one of most important factors in unconventional reservoir production. The self-diverting tendencies offer the potential to maximize created fracture area while simultaneously reducing the treating fluid volumes without the addition of costly diverting additives. The degradability of the fluid can be controlled at reservoir conditions by fluid pH and/or breaker loading to yield near 100% regained proppant pack conductivity. This paper discusses the evolution of the technology, and laboratory results for this unique fluid system. The system can unlock reservoir potential in areas requiring high fractured surface area and high regained conductivity, such as unconventional liquid-rich formations.


2021 ◽  
Vol 252 ◽  
pp. 03049
Author(s):  
Yin Shun-li ◽  
Zhuang Tian-lin ◽  
Yang Li-yong ◽  
Jia Yun-peng ◽  
Liu Xue-wei ◽  
...  

The conductivity of supporting fractures is an important parameter to evaluate the hydraulic fracturing effect of shale reservoirs, and its size is affected by many factors. In this paper, the proppant is optimized and evaluated on the basis of real rock slab simulation and actual construction proppant test. The laboratory experimental study on the influence of proppant type, sand concentration, proppant embedding and fracturing fluid residue on propping fracture conductivity is carried out, the results show that the average conductivity of 40 / 70 mesh proppant is about 7.15d · cm at 5kg / m2 sand concentration under the condition of reservoir closure pressure of about 50MPa, which can basically meet the requirements of main fracture conductivity of Kong 2 shale reservoir in Dagang Oilfield; the damage of guar gum fracturing fluid and proppant embedment are two important factors that cause the great decline of conductivity of rock slab, and the damage of guar gum fracturing fluid has a great influence on the conductivity, reaching about 50%; the stronger the mud is (the higher the clay content is), the greater the embedment degree of proppant is, and the greater the loss of conductivity is; for the same lithology, the proppant particle size has little damage to the conductivity, and the sand concentration has a greater impact on the conductivity. The larger the sand concentration is, the smaller the loss of the conductivity is.


2021 ◽  
Author(s):  
Shuhao Liu ◽  
Yu-Ting Lin ◽  
Martin L. Sentmanat ◽  
Joseph Kwon ◽  
Mustafa Akbulut ◽  
...  

Abstract Hydraulic fracturing has seen a boom in the last century, as a means to fulfill the growing energy demand in the world. The fracturing fluid used in the process plays a substantial role in determining the results. Hence, several research and development efforts have been geared towards developing more sustainable, efficient, and improved fracturing fluids. Herein, we present a dynamic binary complex (DBC) solution, with potential to be useful in the hydraulic fracturing domain. It has a supramolecular structure formed by the self-assembly of low molecular weight viscosifiers (LMWVs) oleic acid and diethylenetriamine into an elongated entangled network under alkaline conditions. With less than 2 wt% constituents dispersed in aqueous solution, a viscous gel that exhibits high viscosities even under shear was formed. Key features include sensitivity to pH and salinity, and a zero-shear viscosity that could be tuned by a factor of ~280 by changing the pH. Furthermore, its viscous properties were pronounced in the presence of salt. Sand settling tests revealed its potential to hold up sand particles for extended periods of time. In conclusion, this DBC solution system has potential to be utilized as a smart salt-responsive, pH-switchable hydraulic fracturing fluid that can be prepared using seawater.


Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1470
Author(s):  
Z. H. Chieng ◽  
Mysara Eissa Mohyaldinn ◽  
Anas. M. Hassan ◽  
Hans Bruining

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir’s formations and, thus, leads to reduce the permeability in these hydrocarbon reservoirs. The development of clean (and cost-effective) fracturing fluid is a main driver of the hydraulic fracturing process. Presently, viscoelastic surfactant (VES)-fluid is one of the most widely used fracturing fluids in the hydraulic fracturing development of unconventional reservoirs, due to its non-residue(s) characteristics. However, conventional single-chain VES-fluid has a low temperature and shear resistance. In this study, two modified VES-fluid are developed as new thickening fracturing fluids, which consist of more single-chain coupled by hydrotropes (i.e., ionic organic salts) through non-covalent interaction. This new development is achieved by the formulation of mixing long chain cationic surfactant cetyltrimethylammonium bromide (CTAB) with organic acids, which are citric acid (CA) and maleic acid (MA) at a molar ratio of (3:1) and (2:1), respectively. As an innovative approach CTAB and CA are combined to obtain a solution (i.e., CTAB-based VES-fluid) with optimal properties for fracturing and this behaviour of the CTAB-based VES-fluid is experimentally corroborated. A rheometer was used to evaluate the visco-elasticity and shear rate & temperature resistance, while sand-carrying suspension capability was investigated by measuring the settling velocity of the transported proppant in the fluid. Moreover, the gel breaking capability was investigated by determining the viscosity of broken VES-fluid after mixing with ethanol, and the degree of core damage (i.e., permeability performance) caused by VES-fluid was evaluated while using core-flooding test. The experimental results show that, at pH-value ( 6.17 ), 30 (mM) VES-fluid (i.e., CTAB-CA) possesses the highest visco-elasticity as the apparent viscosity at zero shear-rate reached nearly to 10 6 (mPa·s). Moreover, the apparent viscosity of the 30 (mM) CTAB-CA VES-fluid remains 60 (mPa·s) at (90 ∘ C) and 170 (s − 1 ) after shearing for 2-h, indicating that CTAB-CA fluid has excellent temperature and shear resistance. Furthermore, excellent sand suspension and gel breaking ability of 30 (mM) CTAB-CA VES-fluid at 90 ( ∘ C) was shown; as the sand suspension velocity is 1.67 (mm/s) and complete gel breaking was achieved within 2 h after mixing with the ethanol at the ratio of 10:1. The core flooding experiments indicate that the core damage rate caused by the CTAB-CA VES-fluid is ( 7.99 % ), which indicate that it does not cause much damage. Based on the experimental results, it is expected that CTAB-CA VES-fluid under high-temperature will make the proposed new VES-fluid an attractive thickening fracturing fluid.


2021 ◽  
Author(s):  
Basil Alfakher ◽  
Ali Al-Taq ◽  
Sajjad Aldarweesh ◽  
Luai Alhamad

Abstract Guar and its derivatives are the most commonly used gelling agents for fracturing fluids. At high temperature, higher polymer loadings are required to maintain sufficient viscosity for proper proppant carry and creating the fracture geometry. To minimize fracturing fluids damage and optimize fracture conductivity, it is necessary to design a fluid that is easy to clean up by ensuring proper breaking and sufficiently low surface tension for flow back. Therefore, breakers and surfactants must be carefully selected and optimally dosed to ensure the success of fracturing treatments. In this study, two fracturing fluids were evaluated for moderate to high temperature applications with a focus on post-treatment cleanup efficiency. The first is a guar-based fluid with a borate crosslinker evaluated at 280°F and the second is a CMHPG-based fluid with a zirconate crosslinker evaluated at 320°F. The shear viscosities of both fluids were tested with a live sodium bromate breaker, a polymer encapsulated ammonium persulfate breaker and a dual breaker system combining the two breakers. Different anionic and nonionic surfactant chemistries (aminosulfonic acid and alcohol based) were investigated by measuring surface tension of the surfactant solutions at different concentrations. The compatibility of the surfactants with other fracturing fluid additives and their adsorption in Berea sandstone was also investigated. Finally, the damage caused by leak-off for each fracturing fluid was simulated by using coreflooding experiments and Berea sandstone core plugs. Lab results showed the guar and CMHPG fluids maintained sufficient viscosity for the first two hours at baseline, respectively. The encapsulated breaker proved to be effective in delaying the breaking of the fracturing fluids. The dual breaker system was the most effective and the loading was optimized for each tested temperature to provide the desired viscosity profile. Two of the examined surfactants were effective in lowering surface tension (below 30 dyne/cm) and were stable for all tested temperatures. The guar broken fluid showed better regained permeability (up to 94%) when compared to the CMHPG (up to 53%) fluid for Berea sandstone. This paper outlines a methodical approach to selecting and optimizing fracturing fluid chemical additives for better post-treatment cleanup and subsequent well productivity.


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