Sorption of Nanomaterials to Sandstone Rock

We investigated the interaction of silica nanostructured particles and sandstone rock using various experimental approaches, such as fluid compatibility, batch sorption and single-phase core-floods. Diol and polyethylenglycol (PEG) surface-modified nanostructured silica materials were tested using two brines differing in ionic strength and with the addition of sodium carbonate (Na2CO3). Berea and Keuper outcrop materials (core plug and crushed samples) were used. Core-flood effluents were analysed to define changes in concentration and a rock’s retention compared to a tracer. Field Flow Fractionation (FFF) and Dynamic Light Scattering (DLS) were performed to investigate changes in the effluent’s size distribution. Adsorption was evaluated using UV–visible spectroscopy and scanning electron microscopy (SEM). The highest adsorption was observed in brine with high ionic strength, whereas the use of alkali reduced the adsorption. The crushed material from Berea rock showed slightly higher adsorption compared to Keuper rock, whereas temperature had a minor effect on adsorption behaviour. In core-flood experiments, no effects on permeability have been observed. The used particles showed a delayed breakthrough compared to the tracer, and bigger particles passed the rock core faster. Nanoparticle recovery was significantly lower for PEG-modified nanomaterials in Berea compared to diol-modified nanomaterials, suggesting high adsorption. SEM images indicate that adsorption spots are defined via surface roughness rather than mineral type. Despite an excess of nanomaterials in the porous medium, monolayer adsorption was the prevailing type observed.

Conceptual Approaches to Solving the Issue of Reinforcing the Rock - Cut Structures of Geghard Monastery Complex

The article presents a visual and instrumental research of the technical condition of the main rock-cut structures and their masonry additions, the documentation of their damages (cracks, crevices, destructions and erosions) and deformations, thorough complete laboratory studies of rock samples and their physical and mechanical characteristics, conceptual approaches to preventive and reinforcing measures necessary for the further safe survival of structures, as well as the comprehensive development and implementation of measures to prevent further damages (elimination of causes) and ensure the long-term existence of structures. Based on the analyses carried out, it is recommended to use a ready-made dry mixture mortar of the “Mapegrout'' brand produced by the Italian company “Mapei” to fill cracks if necessary. It is available in the market of the country and is successfully used in the reconstruction of tunnels and other underground structures. The issues of compatibility of reinforcing materials with sandstone rock are also considered on the basis of some averaged data of the main decisive physical and mechanical characteristics of the strength and deformation of sandstone.

A Nano Method for a Big Challenge: Nanosilica-Based Sealing System for Water Shutoff

Minimizing unwanted water production from oil wells is highly required in the petroleum industry. This would lead to improved economic life of mature wells that involve new and innovative technologies. Nanosilica-based sealing fluid has been developed to address problems associated with unwanted water production. The objective of this work is to evaluate a newly developed novel water shutoff system based on nanosilica over a wide range of parameters. This modified nanosilica has a smooth, spherical shape, and are present in a narrow particle size distribution. Therefore, it can be used for water management in different water production mechanisms including high permeability streak, wormhole, and fractured reservoirs. A systematic evaluation of novel nanosilica/activator for water shutoff purposes requires the examination of the chemical properties before, during, and after gelation at given reservoir conditions. These properties are solution initial viscosity, gelation time, injectivity, and strength of the formed gel against applied external forces in different flooding systems. This paper details a promising method to control undesired water production using eco-friendly, cost-effective nanosilica. Experimental results revealed that nanosilica initially exhibited a low viscosity and hence providing a significant advantage in terms of mixing and pumping requirements. Nanosilica gelation time, which is a critical factor in placement of injected-chemical treatment, can be tailored by adjusting the activator concentration to match field requirements at the desired temperature. In addition, core flood tests were conducted in carbonate core plugs, Berea sandstone rock, and artificially fractured (metal tube) to investigate the performance of the chemical treatment. Flow tests clearly indicated that the water production significantly dropped in all tested types of rocks. The environmental scanning electron microscope (SEM) results showed the presence of SiO-rich compounds suggesting that the tested nanosilica product filled the porous media; therefore, it blocked the whole core plug. A novel cost-effective sealant that uses nanotechnology to block the near wellbore region has been developed. The performance and methods controlling its propagation rate into a porous medium will be presented. Based on the outcomes, it must be emphasized that these trivial particles have a promising application in the oil reservoir for water shutoff purposes.

Managing Sanding Risk in Sandstone Reservoir Through a New Constitutive Model

Sandstone reservoir failure during hydrocarbon production can cause negative impact on the oil/gas field development economics. Loss of integrity and hydrocarbon leakage due to downhole or surface erosion can decrease the risk of operational safety. Therefore, a proper understanding of the best formulation to manage and find the balance between productivity and sand risk is very important. Making decisions for the best and most economical completion design needs a full and proper sanding risk analysis driven by geomechanics modeling. The accuracy of modeling the reservoir rock mechanical behavior and the failure analysis depends on the selection of the constitutive model (failure criteria) specially to understand the failure and post failure mechanisms. Thus, an appropriate constitutive model/criterion is required as most of the current model/criteria are not developed for a weak rock material honoring the non-linearity and post failure (softening) process. Therefore, a new and novel elasto-plastic constitutive model for sandstone rock has been investigated and developed. The effort started with a sequence of triaxial tests at different confining pressures on core samples. Different types of rock have been tested during the developing and validation of the constitutive model. Comparison with other existing failure criteria was also performed. As the results, the newly developed constitutive model is better honoring the full spectrum of elasto-plastic rock mechanical behavior (softening and post-failure) which is important for oil and gas applications, specifically for sand production and drilling i.e. failure stabilization due to stress relief. The formulation and process are demonstrated with a case study for an old gas field, where a few gas wells have been shut-in due to severe sand production. The sand production predictive models have been validated with downhole pressure. The wells have been side-tracked and recompleted using the new sand failure prediction, using the new formulation resulted in restoring sand-free production at former rates. The novelty of this study would be in finding the right formula to best design the predictive model and to avoid any sand production when using the newly developed constitutive model.

Simulation of Immiscible WAG Experiments Performed in Carbonate Rocks: The Impact of Heterogeneity on Hysteresis Phenomenon

Simulation of Water-Alternating-Gas (WAG) Experiments require precise estimation of hysteresis phenomenon in three-phase relative permeability. Most of the research available in the literature are focused on experiments performed on sandstone rocks and the study of carbonate rocks has attracted less attention. In this paper, a recently published hysteresis model by Heriot-Watt University (HWU) was used for simulation of WAG experiments conducted on mixed-wet homogenous carbonate rock. In this study, we simulated immiscible WAG experiments, which were performed under reservoir conditions on mixed-wet carbonate reservoir rock extracted from Abu Dhabi field by using real reservoir fluids. Experiments are performed with different injection scenarios and at high IFT conditions. Then, the results of the coreflood experiments were history matched using 3RPSim to generate two-phase and three-phase relative permeability data. Finally, the hysteresis model suggested by Heriot-Watt University was used for the estimation of hysteresis in relative permeability data. The performance of the model was compared with the experimental data from sandstones to evaluate the impact of heterogeneity on hysteresis phenomenon. It was shown that the available correlations for estimation of three-phase oil relative permeability fail to simulate the oil production during WAG experiments, while the modified Stone model suggested by HWU provided a better prediction. Overall, HWU hysteresis model improved the match for trapped gas saturation and pressure drop. The results show that the hysteresis effect is less dominant in the carbonate rock compared to the sandstone rock. The tracer test results show that the carbonate rock is more homogenous compared to sandstone rock. Therefore, the conclusion is that the hysteresis effect is negligible in homogenous systems.

A Systematic Study to Assess Displacement Performance of a Naturally-Derived Surfactant in Flow Porous Systems

For the first time, the present work assesses the feasibility of using Korean red ginseng root extract, a non-ionic surfactant, for the purposes of enhanced oil recovery (EOR). The surfactant is characterized by Fourier-transform infrared spectroscopy (FT-IR) analysis. Pendant drop and sessile drop techniques are employed to study the oil–water interfacial tension (IFT) and wettability nature of the sandstone rock, respectively. In addition, oil recovery enhancement is investigated using micromodel and core floods. In the salt-free system, IFT measurements indicate that the surfactant carries a critical micelle concentration of 5 g/L. In a saline medium (up to 50 g/L), the addition of a surfactant with different concentrations leads to an IFT reduction of 47.28–84.21%. In a constant surfactant concentration, a contact angle reduction is observed in the range of 5.61–9.30°, depending on salinity rate, revealing a wettability alteration toward more water-wet. Surfactant flooding in the glass micromodel provides a more uniform sweeping, which leads to an oil recovery enhancement of 3.02–11.19%, depending on the extent of salinity. An optimal salt concentration equal to 30 g/L can be recognized according to the results of previous tests. Surfactant flooding (10 g/L) in optimal salt concentration achieves an additional oil recovery of 7.52% after conventional water flooding.

Effect of temperature on the pH of water flood effluents and irreducible water saturation: A study with reference to the Barail sandstone outcrop of the upper Assam Basin

Low salinity water flooding (LSWF) is a promising strategy for improving oil recovery in sandstone reservoirs, and recent studies have shown that the recovery with low salinity water injection is a function of not only the salinity and ionic composition but also of the pH of injected brine, temperature, and the combined effect of both on the wetting properties of the clay mineral surfaces. Following brine flooding, the initial wettability of sandstone rock surfaces existed when crude oil, formation water (FW), and rock surface interaction were in chemical equilibrium at reservoir condition changes based on brine pH, salinity, temperature, and clay mineralogy. This study proposes pH, core flood temperature, and irreducible water saturation as key parameters in inducing wettability changes in the sandstone porous media. In the present work, the sandstone cores were subjected to flooding at temperatures of 70 °C, 85 °C, and 105 °C and measured the pH of the discharge effluents and initial or irreducible water saturation with respect to varying temperatures. This paper investigates the rise of the pH gradient and irreducible water saturation, Swir with respect to LS flooding, at increasing temperatures using a Barail sandstone core. The key results include the following: The pH of the flood effluents increases with increasing core flood temperature, which indicates a shifting of the existing wetting state of the rock. The combined effects of increasing pH and initial or irreducible water saturation pertaining to low salinity flooding at progressively increasing temperatures result in increasing water wettability of the sandstone rock. Increasing flooding temperatures cause an increase in Swir, which follows a linear relationship. The findings of the paper highlight the link of increasing pH and irreducible water saturation with the water wetting properties of the sandstone reservoir rock and hence the fluid flow or the oil–water relative permeability behaviour. This paper proposes that increased irreducible water saturation and pH of water flood effluents are connected to increasing water wetness in a sandstone rock as a function of elevated temperatures. As adequate work and consensus on the potential effects of temperature on wettability alteration under low salinity water flooding is still lacking, the current work in relation to the Barail sandstone of the upper Assam basin could be a novel reference for understanding of the importance of temperature dependent wettability alteration behaviour in sandstone cores. The findings of this study can assist in the formation of a novel approach towards considering the increasing irreducible water saturation and pH of the brine effluent as an effect of alternatively injection of low salinity water at elevated temperatures on sandstone porous rock.

“Like Wringing Water from a Stone!” Information Extraction from Two Rock Graffiti in North Kharga, Egypt

In the course of the last ten years, the North Kharga Oasis–Darb Ain Amur Survey team, led by Salima Ikram (American University in Cairo), has been exploring a network of interconnected desert paths in Egypt’s Western Desert, known as Darb Ain Amur. These marked paths run between Kharga Oasis and Dakhla Oasis, linking them to Darb el-Arbain, a notorious caravan route facilitating contacts between Egypt and sub-Saharan Africa since prehistoric times. Ancient travelers using the Darb Ain Amur spent several days in the midst of the Western Desert and were thus forced to use areas around sandstone rock outcrops as makeshift stopovers or camping sites. During these much-needed breaks, ancient travelers identified accessible, inscribable surfaces on the towering sandstone massifs and left on them their personalized markings. In this essay, I examine two short rock graffiti carved by such travelers in a site north of Kharga Oasis, focusing on the types of information one may extract from such ancient epigraphic materials.