scholarly journals Synthesis of Novel Arginine-Based Flame Retardant and Its Application in Lyocell Fabric

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3588
Author(s):  
Jiayi Chen ◽  
Yansong Liu ◽  
Jiayue Zhang ◽  
Yuanlin Ren ◽  
Xiaohui Liu
Keyword(s):  
Fourier Transform ◽  
Heat Release ◽  
Flame Retardant ◽  
Photoelectron Spectroscopy ◽  
Fourier Transform Infrared ◽  
Ftir Analysis ◽  
Excellent Thermal Stability ◽  
X Ray ◽  
Cone Calorimeter Test ◽  
Before And After

Lyocell fabrics are widely applied in textiles, however, its high flammability increases the risk of fire. Therefore, to resolve the issue, a novel biomass-based flame retardant with phosphorus and nitrogen elements was designed and synthesized by the reaction of arginine with phosphoric acid and urea. It was then grafted onto the lyocell fabric by a dip-dry-cure technique to prepare durable flame-retardant lyocell fabric (FR-lyocell). X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FTIR) analysis demonstrated that the flame retardant was successfully introduced into the lyocell sample. Thermogravimetric (TG) and Raman analyses confirmed that the modified lyocell fabric featured excellent thermal stability and significantly increased char residue. Vertical combustion results indicated that FR-lyocell before and after washing formed a complete and dense char layer. Thermogravimetric Fourier-transform infrared (TG-FTIR) analysis suggested that incombustible substances (such as H2O and CO2) were produced and played a significant fire retarding role in the gas phase. The cone calorimeter test corroborated that the peak of heat release rate (PHRR) and total heat release (THR) declined by 89.4% and 56.4%, respectively. These results indicated that the flame retardancy of the lyocell fabric was observably ameliorated.

A novel curing agent based on diphenylphosphine oxide for flame-retardant epoxy resin

2017 ◽  
Vol 30 (10) ◽  
pp. 1229-1239 ◽  
Author(s):  
Shan Huang ◽  
Xiao Hou ◽  
Jiaojiao Li ◽  
Xiujuan Tian ◽  
Qing Yu ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Energy Dispersive Spectrometer ◽  
Diglycidyl Ether ◽  
Curing Agent ◽  
Diphenylphosphine Oxide ◽  
Excellent Thermal Stability ◽  
Cone Calorimeter Test ◽  
Ul 94

A phosphorous/nitrogen-containing diphenylphosphine oxide (DPO) derivative (DPO-SS) was designed and synthesized via a two-step reaction of 4,4′-diaminodiphenylsulfone, 2-hydroxy-benzaldehyde, and DPO. The structure of DPO-SS was confirmed by Fourier transform infrared spectroscopy (FTIR), 1H and 31P nuclear magnetic resonance (NMR) spectroscopy, and mass spectrometry (MS). DPO-SS was used as a flame retardant and curing agent for copolymerizing with diglycidyl ether of bisphenol-A. Thermal and flame-retardant properties of the obtained flame-retardant epoxy resin (F-EP) were investigated by thermogravimetric analysis, dynamic thermomechanical analysis, limited oxygen index (LOI) measurement, vertical burning test (UL-94), and cone calorimeter test. Results indicated that all F-EP samples exhibited excellent thermal stability and flame-retardant property. Especially for F-EP with P content of 0.7 wt% (denoted as EP/P-0.7), it achieved high LOI values (32.4%) and UL-94 V-0 rating. Compared with pure EP, all F-EP samples showed lower heat release rate, total heat release, total smoke produce, and little Tg fluctuation. In order to study the flame-retardant mechanism, the char residues were investigated by FTIR, scanning electron microscopy, and energy-dispersive spectrometer analysis. The results manifested that DPO-SS acted as flame retardant in both gas phase and condensed phase. Water absorption properties of pure EP and F-EP were also compared through immersion experiments. Results showed that EP/P-0.7 sample had apparently lower water absorptivity than pure EP.

FORMATION OF GaN FILM BY AMMONIATING Ga2O3 DEPOSITED ON Si SUBSTRATE WITH ELECTROPHORESIS

2002 ◽  
Vol 16 (28n29) ◽  
pp. 4267-4270 ◽  
Author(s):  
LI YANG ◽  
CHENGSHAN XUE ◽  
HUIZHAO ZHUANG ◽  
HUAIXIANG LI ◽  
QINQIN WEI
Keyword(s):  
Fourier Transform ◽  
Gallium Nitride ◽  
Photoelectron Spectroscopy ◽  
Fourier Transform Infrared ◽  
Hexagonal Wurtzite Structure ◽  
Wurtzite Structure ◽  
X Ray Diffraction ◽  
Si Substrate ◽  
X Ray ◽  
Gan Film

The gallium nitride (GaN) films have been successfully fabricated on silicon (111) substrates through ammoniating Ga 2 O 3 films deposited by electrophoresis. The structure and composition of the formed films were characterized by Fourier transform infrared (FTIR) transmission spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results indicate that the films formed in this study are polycrystalline GaN with hexagonal wurtzite structure.

Grafting Sulfoammonium Zwitterionic Brushes onto Polycarbonateurethane Surface to Improve Hemocompatibility

2011 ◽  
Vol 306-307 ◽  
pp. 1631-1634 ◽  
Author(s):  
Ya Kai Feng ◽  
Da Zhi Yang ◽  
Hai Yang Zhao ◽  
Jin Tang Guo ◽  
Qing Liang Chen ◽  
...  
Keyword(s):  
Contact Angle ◽  
Fourier Transform ◽  
Physical Properties ◽  
Water Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Potential Application ◽  
Platelet Adhesion ◽  
Fourier Transform Infrared ◽  
Water Contact ◽  
X Ray

Poly(3-dimethyl(methacryloyloxyethyl)ammonium propane sulfonate) (poly(DMAPS)) zwitterionic brushes were grafted onto the polycarbonateurethane (PCU) surface to improve its hydrophilicity and hemocompatibility by Ultraviolet (UV) polymerization. Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS) and water contact angle were used to characterize the chemical and physical properties of the modified PCU surface. DMAPS-grafted PCU films showed significantly high hydrophilicity owing to the high hydrophilic poly(DMAPS) zwitterionic brushes. The cytotoxicity tests revealed the sulfoammonium zwitterionic brushes modified PCU film had good cytocompatibility. In addition, the hemocompatibility of the modified PCU films was evaluated by hemolytic tests and platelet adhesion tests. The PCU films modified with zwitterionic brushes had a lower hemolytic index, showed effective resistance to platelet adhesion. Due to the fact that sulfoammonium zwitterionic brushes can improve the hemocompatibility of the PCU surface, this gives rise to its potential application as blood-contacting materials or devices.

X-ray photoelectron spectroscopy and Fourier transform-infrared studies of transition metal phosphate glasses

1995 ◽  
Vol 30 (1) ◽  
pp. 225-234 ◽  
Author(s):  
E. E. Khawaja ◽  
S. M. A. Durrani ◽  
F. F. Al-Adel ◽  
M. A. Salim ◽  
M. Sakhawat Hussain
Keyword(s):  
Fourier Transform ◽  
Transition Metal ◽  
Photoelectron Spectroscopy ◽  
Fourier Transform Infrared ◽  
Phosphate Glasses ◽  
Metal Phosphate ◽  
X Ray ◽  
Infrared Studies

scholarly journals Comprehension of paraquat adsorption on faujasite zeolite X and Y in sodium form

2017 ◽  
Vol 36 (1-2) ◽  
pp. 684-693 ◽  
Author(s):  
Wina Rongchapo ◽  
Chalermpan Keawkumay ◽  
Nattawut Osakoo ◽  
Krittanun Deekamwong ◽  
Narong Chanlek ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Photoelectron Spectroscopy ◽  
Fourier Transform Infrared ◽  
Magic Angle Spinning ◽  
Mas Nmr ◽  
Magic Angle ◽  
Zeolite X ◽  
X Ray

The nature of paraquat adsorption is compared between zeolite NaX and NaY which have the same faujasite structure but different Si/Al ratio, namely 1.2 and 2.2, respectively. The adsorption was proposed to occur via ion exchange and expected to increase with Al content. However, NaX had a lower paraquat adsorption capacity than NaY. The bare and paraquat-containing zeolites (PQX and PQY) were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, N2 adsorption–desorption analysis, magic-angle spinning nuclear magnetic resonance (MAS) NMR, and X-ray photoelectron spectroscopy. The presence of adsorbed paraquat was confirmed by Fourier transform infrared spectroscopy. Paraquat adsorbed in supercages of the zeolites resulting in a decrease of surface area and displacement of sodium cations. Results from 23Na MAS NMR and X-ray photoelectron spectroscopy indicated that interaction of sodium ions in the cavity of NaX was stronger than that in NaY, making it less exchangeable with paraquat.

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