scholarly journals Antiplasticization of Polymer Materials: Structural Aspects and Effects on Mechanical and Diffusion-Controlled Properties

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 769
Author(s):  
Leno Mascia ◽  
Yannis Kouparitsas ◽  
Davide Nocita ◽  
Xujin Bao
Keyword(s):  
Intermolecular Forces ◽  
Glassy Polymers ◽  
Polymer Materials ◽  
Additivity Rule ◽  
Thermal Transitions ◽  
Molecular Glasses ◽  
Diffusion Controlled ◽  
And Diffusion ◽  
Structural Aspects

Antiplasticization of glassy polymers, arising from the addition of small amounts of plasticizer, was examined to highlight the developments that have taken place over the last few decades, aiming to fill gaps of knowledge in the large number of disjointed publications. The analysis includes the role of polymer/plasticizer molecular interactions and the conditions leading to the cross-over from antiplasticization to plasticization. This was based on molecular dynamics considerations of thermal transitions and related relaxation spectra, alongside the deviation of free volumes from the additivity rule. Useful insights were gained from an analysis of data on molecular glasses, including the implications of the glass fragility concept. The effects of molecular packing resulting from antiplasticization are also discussed in the context of physical ageing. These include considerations on the effects on mechanical properties and diffusion-controlled behaviour. Some peculiar features of antiplasticization regarding changes in Tg were probed and the effects of water were examined, both as a single component and in combination with other plasticizers to illustrate the role of intermolecular forces. The analysis has also brought to light the shortcomings of existing theories for disregarding the dual cross-over from antiplasticization to plasticization with respect to modulus variation with temperature and for not addressing failure related properties, such as yielding, crazing and fracture toughness.

Effect of cluster-gradient architecture of nanostructured topocomposites on features of tribointeraction with heterophased material

2020 ◽  
pp. 130-135
Author(s):  
D.N. Korotaev ◽  
K.N. Poleshchenko ◽  
E.N. Eremin ◽  
E.E. Tarasov
Keyword(s):  
Wear Resistance ◽  
Titanium Alloy ◽  
Energy Dissipation ◽  
Phase Structure ◽  
Diffusion Processes ◽  
Structural Phase ◽  
High Wear Resistance ◽  
Wear Characteristics ◽  
And Diffusion

The wear resistance and wear characteristics of cluster-gradient architecture (CGA) nanostructured topocomposites are studied. The specifics of tribocontact interaction under microcutting conditions is considered. The reasons for retention of high wear resistance of this class of nanostructured topocomposites are studied. The mechanisms of energy dissipation from the tribocontact zone, due to the nanogeometry and the structural-phase structure of CGA topocomposites are analyzed. The role of triboactivated deformation and diffusion processes in providing increased wear resistance of carbide-based topocomposites is shown. They are tested under the conditions of blade processing of heat-resistant titanium alloy.

The Non-Causal Character of Renormalization Group Explanations

2018 ◽  
Author(s):  
Margaret Morrison
Keyword(s):  
Probability Theory ◽  
Renormalization Group ◽  
Dynamical Systems ◽  
Recent Literature ◽  
Mathematical Explanation ◽  
Causal Status ◽  
Physical Information ◽  
The Relationship ◽  
Structural Aspects

After reviewing some of the recent literature on non-causal and mathematical explanation, this chapter develops an argument as to why renormalization group (RG) methods should be seen as providing non-causal, yet physical, information about certain kinds of systems/phenomena. The argument centres on the structural character of RG explanations and the relationship between RG and probability theory. These features are crucial for the claim that the non-causal status of RG explanations involves something different from simply ignoring or “averaging over” microphysical details—the kind of explanations common to statistical mechanics. The chapter concludes with a discussion of the role of RG in treating dynamical systems and how that role exemplifies the structural aspects of RG explanations which in turn exemplifies the non-causal features.

scholarly journals Influence of the Electrolyte Salt Concentration on DNA Detection with Graphene Transistors

Biosensors ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 24
Author(s):  
Agnes Purwidyantri ◽  
Telma Domingues ◽  
Jérôme Borme ◽  
Joana Rafaela Guerreiro ◽  
Andrey Ipatov ◽  
...  
Keyword(s):  
Phosphate Buffer ◽  
Species Interactions ◽  
Field Effect ◽  
Field Effect Transistors ◽  
Limit Of Detection ◽  
Debye Length ◽  
Intermolecular Forces ◽  
Single Layer Graphene ◽  
Dna Adsorption

Liquid-gated Graphene Field-Effect Transistors (GFET) are ultrasensitive bio-detection platforms carrying out the graphene’s exceptional intrinsic functionalities. Buffer and dilution factor are prevalent strategies towards the optimum performance of the GFETs. However, beyond the Debye length (λD), the role of the graphene-electrolytes’ ionic species interactions on the DNA behavior at the nanoscale interface is complicated. We studied the characteristics of the GFETs under different ionic strength, pH, and electrolyte type, e.g., phosphate buffer (PB), and phosphate buffer saline (PBS), in an automatic portable built-in system. The electrostatic gating and charge transfer phenomena were inferred from the field-effect measurements of the Dirac point position in single-layer graphene (SLG) transistors transfer curves. Results denote that λD is not the main factor governing the effective nanoscale screening environment. We observed that the longer λD was not the determining characteristic for sensitivity increment and limit of detection (LoD) as demonstrated by different types and ionic strengths of measuring buffers. In the DNA hybridization study, our findings show the role of the additional salts present in PBS, as compared to PB, in increasing graphene electron mobility, electrostatic shielding, intermolecular forces and DNA adsorption kinetics leading to an improved sensitivity.

On the Role of Charged Defect States and Deep Traps in the Photocarrier Drift and Diffusion in a-Si:H

2000 ◽  
Vol 609 ◽  
Author(s):  
Paul Stradins ◽  
Akihisa Matsuda
Keyword(s):  
Particle Number ◽  
Defect States ◽  
Total Electron ◽  
Minority Carrier Diffusion Length ◽  
Continuity Equations ◽  
Effective Mobility ◽  
Almost All ◽  
Charged Defects ◽  
And Diffusion

ABSTRACTThe drift and diffusion in the presence of charged defects and photocarriers trapped in the tail states is re-examined. In continuity equations, diffusive and drift currents are related to free particles while the Poisson equation includes all charges. In order to make use of ambipolar diffusion approximation, the mobilities and diffusion coefficients should be attributed to the total electron and hole populations making them strongly particle-number dependent. Due to the asymmetry of the conduction and valence band tails, almost all trapped electrons reside in negatively charged defects (D−). A simple model of photocarrier traffic via tail and defect states allows to establish the effective mobility values and coefficients in Einstein relations. In a photocarrier grating experiment, grating of D− is counterbalanced by the grating of trapped holes. Nevertheless, electrons remain majority carriers, allowing the measurement of minority carrier diffusion length, but analysis is needed to relate the latter with μτ product.

Autonom autobiografisch: Zu Thomas Manns Die Entstehung des Doktor Faustus

2020 ◽  
Vol 55 (1) ◽  
pp. 83-99
Author(s):  
Lukas Hermann
Keyword(s):  
Thomas Mann ◽  
Autobiographical Writing ◽  
Documentary Source ◽  
Textual Evidence ◽  
Structural Frame ◽  
The Status ◽  
Structural Aspects

AbstractIn its peritext, Thomas Mann’s Entstehung des Doktor Faustus is described as a “Roman eines Romans”. The essay reasons that this description of its genre as well as structural aspects of its composition mark it as an autobiographical text. Instead of following most studies on the Doktor Faustus, which regard the Entstehung simply as a documentary source for exposing autobiographical intricacies of Mann’s novel, textual evidence for the Entstehung’s autonomy is given. The analysis focuses first on the structural frame of the Entstehung in order to show Mann’s central techniques of autobiographical self-stylization. In this context auto-fictional elements can also be identified. Exemplary passages from two longer sections are taken into account based on these findings. While the Doktor Faustus is a recurrent topic in these passages, it is not, by any means, the only one. Combined with varying autobiographical writing techniques, the Entstehung is thus displaying continuous independence from the Faustus. Based on these insights, future Mann studies on both works may reevaluate the role of the Entstehung for the reception of the Faustus and the status of autobiographical literature in the works of Thomas Mann.

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