scholarly journals Silane-Functionalized Sheep Wool Fibers from Dairy Industry Waste for the Development of Plasticized PLA Composites with Maleinized Linseed Oil for Injection-Molded Parts

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2523
Author(s):  
Franciszek Pawlak ◽  
Miguel Aldas ◽  
Francisco Parres ◽  
Juan López-Martínez ◽  
Marina Patricia Arrieta
Keyword(s):  
Linseed Oil ◽  
Microstructural Analysis ◽  
Dairy Industry ◽  
Poly Lactic Acid ◽  
Industry Waste ◽  
Wool Fibers ◽  
Molded Parts ◽  
Silane Modification ◽  
Injection Molded ◽  
Sheep Wool

Poly(lactic acid) (PLA) was plasticized with maleinized linseed oil (MLO) and further reinforced with sheep wool fibers recovered from the dairy industry. The wool fibers were firstly functionalized with 1 and 2.5 phr of tris(2-methoxyethoxy)(vinyl) (TVS) silane coupling agent and were further used in 1, 5, and 10 phr to reinforce the PLA/MLO matrix. Then, the composite materials were processed by extrusion, followed by injection-molding processes. The mechanical, thermal, microstructural, and surface properties were assessed. While the addition of untreated wool fibers to the plasticized PLA/MLO matrix caused a general decrease in the mechanical properties, the TVS treatment was able to slightly compensate for such mechanical losses. Additionally, a shift in cold crystallization and a decrease in the degree of crystallization were observed due to the fiber silane modification. The microstructural analysis confirmed enhanced interaction between silane-modified fibers and the polymeric matrix. The inclusion of the fiber into the PLA/MLO matrix made the obtained material more hydrophobic, while the yellowish color of the material increased with the fiber content.

scholarly journals Effect of Different Compatibilizers on Injection-Molded Green Fiber-Reinforced Polymers Based on Poly(lactic acid)-Maleinized Linseed Oil System and Sheep Wool

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1514 ◽  
Author(s):  
Franciszek Pawlak ◽  
Miguel Aldas ◽  
Juan López-Martínez ◽  
María Dolores Samper
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Thermal Properties ◽  
Linseed Oil ◽  
Fiber Reinforced Polymers ◽  
Coupling Agents ◽  
Poly Lactic Acid ◽  
Original Material ◽  
Fiber Reinforced ◽  
Sheep Wool

A method to modify polymers is that of introducing fibers in a matrix to produce a fiber-reinforced polymer (FRP). Consequently, the aim of this work was to study the compatibility effect of four coupling agents on wool FRP properties, using poly(lactic acid) plasticized with maleinized linseed oil as polymer matrix. The content of wool assessed was 1 phr. The compatibilizers were (3-(2-aminoethylamino)propyl)-trimethoxysilane, trimethoxy (2-(7-oxabicyclo (4.1.0)hept-3-yl) ethyl) silane, tris(2-methoxyethoxy)(vinyl) silane and titanium (IV) (triethanolaminate)isopropoxide. Initially, wool was modified with coupling agents in an acetone/water (50/50) solution. Mechanical properties were evaluated by tensile and flexural properties, hardness by Shore D measurement and impact resistance by Charpy’s energy. Differential scanning calorimetry, dynamic thermo-mechanical analysis, and thermogravimetric analysis were conducted to evaluate the interaction among components and the effect of the coupling agents on the thermal properties of the original material. Color, wettability and scanning electron microscopy were used to describe physical and microstructural properties. Modification of fibers allows achieving improved mechanical properties and changes the thermal properties of the FRPs slightly. Coupling agent treatment helps to formulate PLA–MLO and sheep wool materials and to improve their performance, thereby creating a broader spectrum of applications for PLA maintaining the bio-based character of the material.

A Study on the Birefringence Measurement in Injection Molded Parts Using Two Different Laser Sources and R-G-B Separation of White Light

2006 ◽  
Vol 326-328 ◽  
pp. 187-190
Author(s):  
Jong Sun Kim ◽  
Chul Jin Hwang ◽  
Kyung Hwan Yoon
Keyword(s):  
White Light ◽  
Low Cost ◽  
Main Idea ◽  
Injection Molding Process ◽  
Molding Process ◽  
Laser Method ◽  
High Productivity ◽  
Molded Parts ◽  
Injection Molded ◽  
Plastic Parts

Recently, injection molded plastic optical products are widely used in many fields, because injection molding process has advantages of low cost and high productivity. However, there remains residual birefringence and residual stresses originated from flow history and differential cooling. The present study focused on developing a technique to measure the birefringence in transparent injection-molded optical plastic parts using two methods as follows: (i) the two colored laser method, (ii) the R-G-B separation method of white light. The main idea of both methods came from the fact that more information can be obtained from the distribution of retardation caused by different wavelengths. The comparison between two methods is demonstrated for the same sample of which retardation is up to 850 nm.

scholarly journals Development of a novel color inhomogeneity test method for injection molded parts

2014 ◽  
Vol 37 ◽  
pp. 112-116 ◽  
Author(s):  
L. Zsíros ◽  
A. Suplicz ◽  
G. Romhány ◽  
T. Tábi ◽  
J.G. Kovács
Keyword(s):  
Test Method ◽  
Molded Parts ◽  
Injection Molded

Prediction and measurement of residual stresses in injection molded parts

2001 ◽  
Vol 2 (4) ◽  
pp. 203-211 ◽  
Author(s):  
Young Il Kwon ◽  
Tae Jin Kang ◽  
Kwansoo Chung ◽  
Jae Ryoun Youn
Keyword(s):  
Residual Stresses ◽  
Molded Parts ◽  
Injection Molded

Geometry-Based Index for Predicting Sink Mark in Plastic Parts

1991 ◽  
Author(s):  
Kurt Beiter ◽  
Kosuke Ishii ◽  
Lee Hornberger
Keyword(s):  
Process Conditions ◽  
Plastic Part ◽  
Design Rules ◽  
Packing Pressure ◽  
Molded Parts ◽  
Injection Molded ◽  
Form Features ◽  
Plastic Parts ◽  
Sink Mark

Abstract This paper describes the development of geometry-based indices that predict sink mark depth in injection molded parts. Plastic part designers need such indices to incorporate manufacturability concerns at the conceptual stage of design. These indices apply to several form features so engineers do not have to check different design rules for each geometry element. First, we propose a geometry-based sink index that can be used to predict sink mark depth as a function of process conditions such as packing pressure. Next, we explain how this relationship is identified through experiments. We also describe HyperDesign/Plastics, a Macintosh-based design aid that incorporates the sink index.

Estimation of diffusion and solubility coefficients for water and CO2 in reaction injection molded parts

1996 ◽  
Vol 17 (5) ◽  
pp. 649-655 ◽  
Author(s):  
Deborah F. Mielewski ◽  
Nitin R. Anturkar ◽  
David R. Bauer
Keyword(s):  
Molded Parts ◽  
Injection Molded ◽  
Solubility Coefficients

scholarly journals Effects of Injection Molding Screw Tips on Polymer Mixing

2018 ◽  
Vol 62 (3) ◽  
pp. 241-246 ◽  
Author(s):  
Dániel Török ◽  
József Gábor Kovács
Keyword(s):  
Injection Molding ◽  
Processing Parameters ◽  
Raw Material ◽  
Molding Machine ◽  
Surface Color ◽  
Melt Temperature ◽  
Injection Molding Machine ◽  
Aesthetic Appearance ◽  
Molded Parts ◽  
Injection Molded

In all fields of industry it is important to produce parts with good quality. Injection molded parts usually have to meet strict requirements technically and aesthetically. The aim of the measurements presented in our paper is to investigate the aesthetic appearance, such as surface color homogeneity, of injection molded parts. It depends on several factors, the raw material, the colorants, the injection molding machine and the processing parameters. In this project we investigated the effects of the injection molding machine on surface color homogeneity. We focused on injection molding screw tips and investigated five screw tips with different geometries. We produced flat specimens colored with a masterbatch and investigated color homogeneity. To evaluate the color homogeneity of the specimens, we used digital image analysis software developed by us. After that we measured the plastication rate and the melt temperature of the polymer melt because mixing depends on these factors. Our results showed that the screw tips (dynamic mixers) can improve surface color homogeneity but they cause an increase in melt temperature and a decrease in the plastication rate.

Sign in / Sign up

Export Citation Format

Share Document