scholarly journals Rheological Properties Related to Extrusion of Polyolefins

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 489
Author(s):  
Evan Mitsoulis ◽  
Savvas G. Hatzikiriakos
Keyword(s):  
Rheological Properties ◽  
Slip Velocity ◽  
Wall Slip ◽  
Molecular Characteristics ◽  
Capillary Rheometer ◽  
Rheological Models ◽  
Cross Model ◽  
Slip Effects ◽  
Best Fitting ◽  
Temperature And Pressure

Rheological properties related to the extrusion of polyolefins are the shear viscosity, the elongational viscosity, the slip velocity and their temperature- and pressure-dependencies. These properties are measured in the rheology lab mainly via a parallel-plate rheometer and a capillary rheometer. Then appropriate rheological models have to be used to account for all these properties. Such models are either viscous (e.g., the Cross model) or viscoelastic (e.g., the K-BKZ model). The latter gives the best fitting of the experimental data and offers excellent results in numerical simulations, especially in extrusion flows. Wall slip effects are also found and measured by rheometric flows. Modeling of extrusion flows should make use of appropriate slip models that take into effect the various slip parameters, including the effects of shear stress, molecular characteristics, temperature and pressure on the slip velocity. In this paper the importance of these properties in extrusion are discussed.

Evaluation of Slip Effects in the Capillary Flow of Foams

1999 ◽  
Vol 9 (1) ◽  
pp. 10-16 ◽  
Author(s):  
Karim Bekkour
Keyword(s):  
Shear Stress ◽  
Wall Shear Stress ◽  
Slip Velocity ◽  
Capillary Flow ◽  
Strong Dependence ◽  
Sodium Dodecyl ◽  
Wall Slip ◽  
Reynolds Analogy ◽  
Slip Effects ◽  
Wall Shear

Abstract Foams have been prepared from water added with a surfactant (Sodium-Dodecyl-Sulfate, SDS) and a polymer (Poly-Ethylene-Oxide, PEO) at different concentrations. This work was devoted to a study of the flow properties of the foams. The pressure drops were measured during flow in capillary tubes (2.5, 3.5 and 4 mm) in laminar regime. It was found a strong dependence of the flow curves on capillary diameter showing that pronounced wall slip effects exist. Two known approaches were applied to quantify the slip velocity: (a) the Mooney method, in which the key assumption is that the slip velocity depends only on the wall shear stress, was not applicable and (b) the Oldroyd-Jastrzebski method, in which the assumption is that the slip velocity depends not only on the wall shear stress but also on the flow geometry, yielded satisfactory results. The determination of the pressure drop coefficient showed that the Metzner and Reed correlation, i.e., the Reynolds analogy based on the generalised Reynolds number, could be applied if the data are corrected for slip effects.

Wall Slip of Suspension Flowing in Capillary at Elevated Temperature

2006 ◽  
Vol 111 ◽  
pp. 87-90 ◽  
Author(s):  
Z.Y. Wang ◽  
Yee Cheong Lam ◽  
X. Chen
Keyword(s):  
Shear Stress ◽  
Elevated Temperature ◽  
Wall Shear Stress ◽  
Slip Velocity ◽  
Particle Concentration ◽  
Flow Behavior ◽  
Wall Slip ◽  
Ethylene Vinyl Acetate ◽  
Suspension System ◽  
Capillary Rheometer

The flow of a suspension system with glass microspheres in polymer EVA (Ethylene Vinyl Acetate) melts system was studied in a capillary rheometer. The slip velocity was determined by Mooney technique. A modified slip law describing the slip velocity as a function of the wall shear stress and particle concentration was proposed and employed to describe the flow behavior of the suspension system.

Effects of the Types and Addition Amounts of Sludge on the True Rheological Properties of Petroleum Coke Slurry Flowing in Pipelines

2015 ◽  
Vol 13 (3) ◽  
pp. 311-322 ◽  
Author(s):  
Meng Liu ◽  
Yufeng Duan ◽  
Xiuyuan Ma
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Petroleum Coke ◽  
Slip Velocity ◽  
Wall Slip ◽  
Paper Mill ◽  
Shear Thinning ◽  
Tikhonov Regularization Method ◽  
Plastic Fluid ◽  
Dilatant Fluid

AbstractEffects of the types and addition amounts of sludge on the true rheological properties of petroleum coke water/sludge slurry (PCWS/PCSS) flowing in pipelines were investigated using the Tikhonov regularization method. Results show that PCWS of 59.8 wt% changes from pseudo-plastic fluid to dilatant fluid as the shear rate increases. However, PCWS of 63.4 wt% is a very complex fluid: shear thinning at low shear rate, followed by shear thickening over a critical shear rate, and a subsequent shear thinning at high shear rate. Rheological properties of PCWS have a significant change after the sludge was added. PCSS changes from dilatant fluid to pseudo-plastic fluid when the addition amounts of sewage sludge ascend to 10 wt%. Petroleum coke particles are trapped by the stable “network” structures, which are formed by flocculent sludge particles. The wall slip velocity of PCSS is higher than that of PCWS with the sludge amount increases, which is beneficial for pipe transportation. In addition, the wall slip velocity of PCSS containing sewage or petrochemical sludge increases with the wall shear rate increases, but the slip velocity of PCSS containing paper mill sludge first increases and then decreases.

scholarly journals Quantification of shear viscosity and wall slip velocity of highly concentrated suspensions with non-Newtonian matrices in pressure driven flows

2021 ◽  
Author(s):  
Patrick Wilms ◽  
Jan Wieringa ◽  
Theo Blijdenstein ◽  
Kees van Malssen ◽  
Reinhard Kohlus
Keyword(s):  
Shear Stress ◽  
Liquid Phase ◽  
Shear Rate ◽  
Shear Viscosity ◽  
Slip Velocity ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Wall Slip ◽  
Flow Index ◽  
Concentrated Suspensions

AbstractThe rheological characterization of concentrated suspensions is complicated by the heterogeneous nature of their flow. In this contribution, the shear viscosity and wall slip velocity are quantified for highly concentrated suspensions (solid volume fractions of 0.55–0.60, D4,3 ~ 5 µm). The shear viscosity was determined using a high-pressure capillary rheometer equipped with a 3D-printed die that has a grooved surface of the internal flow channel. The wall slip velocity was then calculated from the difference between the apparent shear rates through a rough and smooth die, at identical wall shear stress. The influence of liquid phase rheology on the wall slip velocity was investigated by using different thickeners, resulting in different degrees of shear rate dependency, i.e. the flow indices varied between 0.20 and 1.00. The wall slip velocity scaled with the flow index of the liquid phase at a solid volume fraction of 0.60 and showed increasingly large deviations with decreasing solid volume fraction. It is hypothesized that these deviations are related to shear-induced migration of solids and macromolecules due to the large shear stress and shear rate gradients.

scholarly journals Rheological Basics for Modeling of Extrusion Process of Wood Polymer Composites

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 622
Author(s):  
Krzysztof Wilczyński ◽  
Kamila Buziak ◽  
Adrian Lewandowski ◽  
Andrzej Nastaj ◽  
Krzysztof J. Wilczyński
Keyword(s):  
Polymer Composites ◽  
Process Modeling ◽  
Slip Flow ◽  
Extrusion Process ◽  
Process Conditions ◽  
Rheological Models ◽  
Wood Polymer ◽  
Slip Effects ◽  
Process Simulations ◽  
Wood Polymer Composites

Wood polymer composites are materials with pseudoplastic and viscoelastic properties. They have yield stress and exhibit slip during flow. Studies on extrusion and rheology, as well as on process modeling of these highly filled materials are limited. Extensive rheological and extrusion modeling studies on the wood polymer composite based on the polypropylene matrix were performed. Viscous and slip flow properties were determined (with Rabinowitsch, Bagley, and Mooney corrections) at broad (extrusion) range of shear rate and temperature, using a high-pressure capillary rheometer. Rheological models of Klein and power-law were used for flow modeling, and Navier model was applied for slip modeling. A novel global computer model of WPC extrusion with slip effects has been developed, and process simulations were performed to compute the extrusion parameters (throughput, power consumption, pressure, temperature, etc.), and to study the effect of the material rheological characteristics on the process flow. Simulations were validated experimentally, and were discussed with respect to both rheological and process modeling aspects. It was concluded that the location of the operating point of extrusion process, which defines the thermo-mechanical process conditions, is fundamentally dependent on the rheological materials characteristics, including slip effects.

scholarly journals Numerical Study of MHD Flow and Heat Transfer Through Porous Medium Between Two Parallel Plates With Hall and Ion Slip Effects

2020 ◽  
Vol 7 ◽  
Keyword(s):  
Heat Transfer ◽  
Porous Medium ◽  
Numerical Study ◽  
Mhd Flow ◽  
Parallel Plates ◽  
Electrically Conducting ◽  
Flow And Heat Transfer ◽  
Slip Effects ◽  
Ion Slip ◽  
Temperature And Pressure

This paper studies the effects of Hall and ion slip on two dimensional incompressible flow and heat transfer of an electrically conducting viscous fluid in a porous medium between two parallel plates, generated due to periodic suction and injection at the plates. The flow field, temperature and pressure are assumed to be periodic functions in ti e ω and the plates are kept at different but constant temperatures. A numerical solution for the governing nonlinear ordinary differential equations is obtained using quasilinearization method. The graphs for velocity, temperature distribution and skin friction are presented for different values of the fluid and geometric parameters.

Application of CFD-DSMC coupling method in micro-scale gas flow and combustion

2020 ◽  
Vol 34 (27) ◽  
pp. 2050301
Author(s):  
Shaoyi Suo ◽  
Linsong Jiang ◽  
Maozhao Xie
Keyword(s):  
Boundary Layer ◽  
Chemical Reaction ◽  
Wall Temperature ◽  
Slip Velocity ◽  
Gas Flow ◽  
Wall Slip ◽  
Reaction Products ◽  
Microscopic Method ◽  
Flow Heat ◽  
The Impact

The reversible elementary reaction mechanism of six components and seven steps of H2/O2 are applied by using a CFD-DSMC coupling iteration method to study the impact of boundary on flow, heat transfer and chemical reaction in a microtube. The microtube consists of a converging section and a straight section, which represents the gap on the contact surface of the pellets in porous media. It shows that after coupling, with the designed conditions in this paper, the influence of wall temperature is more obvious than that of wall slip velocity on the coupling results from the analysis of chemical reaction, yet the velocity field in the boundary layer is more affected by the wall slip velocity. In addition, the velocity in the central region of the flow decreases while the concentration of reaction products increases after coupling, due to the increasing of the velocity in the boundary layer and the influence of wall temperature, respectively. By the coupling of CFD-DSMC methods, more details and influence of the boundary can be considered, and the computational efficiency is higher than that of the single microscopic method.

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