scholarly journals Effect of Steam Quality on Extra-Heavy Crude Oil Upgrading and Oil Recovery Assisted with PdO and NiO-Functionalized Al2O3 Nanoparticles

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1009
Author(s):  
Luisana Cardona ◽  
Oscar E. Medina ◽  
Santiago Céspedes ◽  
Sergio H. Lopera ◽  
Farid B. Cortés ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Mass Fraction ◽  
Steam Injection ◽  
Heavy Crude Oil ◽  
Al2o3 Nanoparticles ◽  
Steam Quality ◽  
Oil Viscosity ◽  
Overburden Pressure ◽  
Heavy Crude

This work focuses on evaluating the effect of the steam quality on the upgrading and recovering extra-heavy crude oil in the presence and absence of two nanofluids. The nanofluids AlNi1 and AlNi1Pd1 consist of 500 mg·L−1 of alumina doped with 1.0% in mass fraction of Ni (AlNi1) and alumina doped with 1.0% in mass fraction of Ni and Pd (AlNi1Pd1), respectively, and 1000 mg·L−1 of tween 80 surfactant. Displacement tests are done in different stages, including (i) basic characterization, (ii) waterflooding, (iii) steam injection at 0.5 quality, (iv) steam injection at 1.0 quality, (v) batch injection of nanofluids, and (vi) steam injection after nanofluid injection at 0.5 and 1.0 qualities. The steam injection is realized at 210 °C, the reservoir temperature is fixed at 80 °C, and pore and overburden pressure at 1.03 MPa (150 psi) and 5.51 MPa (800 psi), respectively. After the steam injection at 0.5 and 1.0 quality, oil recovery is increased 3.0% and 7.0%, respectively, regarding the waterflooding stage, and no significant upgrade in crude oil is observed. Then, during the steam injection with nanoparticles, the AlNi1 and AlNi1Pd1 increase the oil recovery by 20.0% and 13.0% at 0.5 steam quality. Meanwhile, when steam is injected at 1.0 quality for both nanoparticles evaluated, no incremental oil is produced. The crude oil is highly upgraded for the AlNi1Pd1 system, reducing oil viscosity 99%, increasing the American Petroleum Institute (API)° from 6.9° to 13.3°, and reducing asphaltene content 50% at 0.5 quality. It is expected that this work will eventually help understand the appropriate conditions in which nanoparticles should be injected in a steam injection process to improve its efficiency in terms of oil recovery and crude oil quality.

scholarly journals Screening of waterflooding, hot waterflooding and steam injection for extra heavy crude oil production from Tatarstan oilfield

2021 ◽  
Vol 931 (1) ◽  
pp. 012002
Author(s):  
A Pituganova ◽  
I Minkhanov ◽  
A Bolotov ◽  
M Varfolomeev
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Water Injection ◽  
Oil Production ◽  
Steam Injection ◽  
Hot Water ◽  
Heavy Crude Oil ◽  
Oil Viscosity ◽  
Heavy Crude ◽  
Bulk Model

Abstract Thermal enhanced oil recovery techniques, especially steam injection, are the most successful techniques for extra heavy crude oil reservoirs. Steam injection and its variations are based on the decrease in oil viscosity with increasing temperature. The main objective of this study is the development of advanced methods for the production of extra heavy crude oil in the oilfield of the Republic of Tatarstan. The filtration experiment was carried out on a bulk model of non-extracted core under reservoir conditions. The experiment involves the injection of slugs of fresh water, hot water and steam. At the stage of water injection, no oil production was observed while during steam injection recovery factor (RF) achieved 13.4 % indicating that fraction of immobile oil and non-vaporizing residual components is high and needed to be recovered by steam assisted EORs.

scholarly journals Upgrading of Extra-Heavy Crude Oils by Dispersed Injection of NiO–PdO/CeO2±δ Nanocatalyst-Based Nanofluids in the Steam

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1755 ◽  
Author(s):  
Oscar E. Medina ◽  
Cristina Caro-Vélez ◽  
Jaime Gallego ◽  
Farid B. Cortés ◽  
Sergio H. Lopera ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Dynamic Test ◽  
Steam Injection ◽  
Gravity Level ◽  
Steam Quality ◽  
Overburden Pressure ◽  
Static Tests ◽  
Steam Flooding ◽  
Heavy Crude

The main objective of this study is to evaluate the injection of a dispersed nanocatalyst-based nanofluid in a steam stream for in situ upgrading and oil recovery during a steam injection process. The nanocatalyst was selected through adsorption and thermogravimetric experiments. Two nanoparticles were proposed, ceria nanoparticles (CeO2±δ), with and without functionalization with nickel, and palladium oxides (CeNi0.89Pd1.1). Each one was employed for static tests of adsorption and subsequent decomposition using a model solution composed of n-C7 asphaltenes (A) and resins II (R) separately and for different R:A ratios of 2:8, 1:1, and 8:2. Then, a displacement test consisting of three main stages was successfully developed. At the beginning, steam was injected into the porous media at a temperature of 210 °C, the pore and overburden pressure were fixed at 150 and 800 psi, respectively, and the steam quality was 70%. This was followed by CeNi0.89Pd1.1 dispersed injection in the steam stream. Finally, the treatment was allowed to soak for 12 h, and the steam flooding was carried out again until no more oil production was observed. Among the most relevant results, functionalized nanoparticles achieved higher adsorption of both fractions as well as a lower decomposition temperature. The presence of resins did not affect the amount of asphaltene adsorption over the evaluated materials. The catalytic activity suggests that the increase in resin content promotes a higher conversion in a shorter period of time. Also, for the different steps of the dynamic test, increases of 25% and 42% in oil recovery were obtained for the dispersed injection of the nanofluid in the steam stream and after a soaking time of 12 h, compared with the base curve with only steam injection, respectively. The upgraded crude oil reached an API gravity level of 15.9°, i.e., an increase in 9.0° units in comparison with the untreated extra-heavy crude oil, which represents an increase of 130%. Also, reductions of up to 71% and 85% in the asphaltene content and viscosity were observed.

Heavy Crude Oil Recovery Enhancement and In-Situ Upgrading During Steam Injection Using Ni-Co-Mo Dispersed Catalyst

2016 ◽  
Author(s):  
S. M. Shuwa ◽  
R. S. Al-Hajri ◽  
A. Mohsenzadeh ◽  
Y. M. Al-Waheibi ◽  
B. Y. Jibril
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Steam Injection ◽  
Heavy Crude Oil ◽  
Heavy Crude

Heavy crude oil viscosity reduction and rheology for pipeline transportation

Fuel ◽  
2010 ◽  
Vol 89 (5) ◽  
pp. 1095-1100 ◽  
Author(s):  
Shadi W. Hasan ◽  
Mamdouh T. Ghannam ◽  
Nabil Esmail
Keyword(s):  
Crude Oil ◽  
Viscosity Reduction ◽  
Heavy Crude Oil ◽  
Pipeline Transportation ◽  
Oil Viscosity ◽  
Heavy Crude

Correlation of Crude Oil Steam Distillation Yields With Basic Crude Oil Properties

1983 ◽  
Vol 23 (06) ◽  
pp. 937-945 ◽  
Author(s):  
Ching H. Wu ◽  
Robert B. Elder
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Boiling Point ◽  
Steam Distillation ◽  
Recovery Process ◽  
Steam Injection ◽  
Steam Pressure ◽  
Oil Viscosity ◽  
Simulated Distillation ◽  
Distillation Yield

Abstract Steam distillation can occur in reservoirs during steam injection and in-situ combustion processes. To estimate the amount of vaporized oil caused by steam distillation, we established correlations of steam distillation yields with the basic crude oil properties. These correlations were based on steam distillation tests performed on 16 crude oils from various pans of the U.S. The gravity of oils varied from 12 to 40 deg. API [0.99 to 0.83 g/cm3]. The viscosity of oil ranged from 5 to 4,085 cSt [5 to 4085 mm /s] at 100 deg. F [38 deg. C]. The steam distillations were performed at a saturated steam pressure of 220 psia [1.5 MPa]. One oil sample was used in experiments to investigate the effect of steam pressure (220 to 500 psia [1.5 to 3.4 MPa]) on the steam distillation yield. The experiments were carried out to a steam distillation factor (Vw/Voi) of 20, with the factor defined as the cumulative volume of condensed steam used in distillation, Vw, divided by the initial volume of oil, Voi. At a steam distillation factor of 20, the distillation yields ranged from 13 to 57% of the initial oil volume. Several basic crude oil properties can be used to predict steam distillation yields reasonably well. A correlation using oil viscosity in centistokes at 100 deg. F [38 deg. C] can be used to predict the steam distillation yield within a standard error of 4.3 %. The API gravity can be used to estimate wields within 5.6%. A gas chromatographic analysis was made for each crude oil to obtain the component boiling points (simulated distillation temperatures). A correlation parameter was selected from the simulated distillation results that can be used to estimate the steam distillation yields within 4.5%. Introduction Steamflooding has been used commercially to recover heavy oils for several decades. Although it is considered a heavy-oil recovery process, it has been demonstrated to be an effective and commercially feasible process for recovering light oils. To enhance the effectiveness of the oil recovery process, it is important to fully understand and utilize the basic steamflooding mechanisms. Willman et al. investigated the mechanisms of steamflooding. They concluded that oil viscosity reduction, oil volume expansion, and steam distillation are the major mechanisms for oil recovery. Since then, more research has been done on all phases of steam injection. However, steam distillation and its ramifications on recovery have not been quantified fully because of lack of experimental data. Steam distillation can lower the boiling point of a water/oil mixture below the boiling point of the individual components. SPEJ P. 937^

Extra-Heavy Crude Oil Downhole Upgrading Process using Hydrogen Donors under Steam Injection Conditions

2001 ◽  
Author(s):  
Cesar Ovalles ◽  
Carlos Vallejos ◽  
Tito Vasquez ◽  
Jorge Martinis ◽  
Alfredo Perez-Perez ◽  
...  
Keyword(s):  
Crude Oil ◽  
Steam Injection ◽  
Heavy Crude Oil ◽  
Hydrogen Donors ◽  
Heavy Crude
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