Investigation of the Process of Simple Distillation in Irrigated Pipe Elements

In modern chemical and oil refining complexes, separation processes are among the most popular and energy-intensive. Installations for their implementation should be equipped with nodes for creating vapor (evaporators) and liquid (deflegmators) irrigation. Evaporators of any type (film, thermosiphon, gas lift, cubic) belong to this class of devices. For example, in cubic evaporators, the gas flow is completely formed from flux bubbles that originate on the heat-conducting surface and float in the volume of the cubic liquid located in the apparatus. Due to the accompanying mass exchange, the bubbles are enriched with volatile components during ascent and noticeably increase in volume, and the growth of the bubble is determined, among other things, by the total flow. At the same time, in real bubbling-type equipment, the total mass transfer surface exceeds the cross-section of the device itself by more than two orders of magnitude. Thus, according to, the ratio of the internal cross-sectional area of the apparatus to the developed mass transfer surface is 0.0015–0.002. Based on the analysis of the integral equation of the diffusion boundary layer, it is shown that the presence of a resultant flow of substance through the phase interface (non-equimolarity of the process) in a two-phase gas (vapor)–liquid system leads to the transformation of the structure of the traditional mass transfer equation itself. The use of a new structure obtained for both binary and multicomponent mixtures makes it possible to significantly simplify the approach to the description and generalization of arbitrary mass transfer processes. The innovativeness of the proposed approach lies in its universality for non-equimolar processes. This simplifies the creation of models of any mass transfer devices and entire production lines. In addition, the proposed approach is a good auxiliary tool for various researchers and experimenters. It should also be noted that the separation processes of many products of organic origin during heating are characterized by the appearance of undesirable side reactions (thermal decomposition, condensation, polycondensation, formation of harmful impurities, etc.), which occur most intensively in the heating zones. At the same time, the evaporation and distillation units are subject to requirements for the minimum hydraulic resistance of the structure, the maximum separation capacity (efficiency), and the minimum residence time of the product in the apparatus (equivalent to the minimum holding capacity of the structure). It was noted that the specified requirements are most fully met by film-type devices.

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Evaluation of the Efficiency of Transfer Processes in a Rotary Apparatus

ENERGETIKA Proceedings of CIS higher education institutions and power engineering associations ◽

10.21122/1029-7448-2021-64-5-459-474 ◽

2021 ◽

Vol 64 (5) ◽

pp. 459-474

Author(s):

A. M. Volk ◽

A. I. Vilkotsky ◽

O. N. Pyzhcova

Keyword(s):

Mass Transfer ◽

Gas Flow ◽

Heterogeneous Media ◽

Chemical Interaction ◽

Phase Interface ◽

Experimental Studies ◽

Gas Production ◽

Liquid Droplets ◽

Working Volume ◽

Developed Surface

This paper considers the possibility of using vortex devices for interphase interaction while carrying out various physical and chemical processes in the chemical, food, gas production, construction and other industries. In the processes of mass transfer, one or several distributed components perform the transition from one phase to another through the active surface of their interface. To perform the implementation of these processes in absorbers, rectifiers, adsorbers, extractors effectively, the developed surface of the interacting phases acquire s a particular significance. Most of the chemical reactions in reaction devices and heterogeneous media occur when the initial distributed substances are supplied to the reaction zone and when the resulting products are removed from the chemical interaction zone through the phase interface. The processes under consideration are also used in solving environmental problems, viz. for sanitary cleaning of ventilation gases, wet cleaning of emissions. During evaporation, absorption, rectification, wet cleaning of gases and other processes, the problem of preventing the entrainment of liquid droplets with the gas flow is of great importance. One of the designs of a rotary multistage mass transfer apparatus is considered which makes it possible to achieve a finely dispersed liquid spray, uniform in height, with an ascending cross-flow of gas. The diagrams of installations for carrying out the experiment are given. On the basis of experimental studies, the dependence of the average diameter of dispersed liquid droplets on the geometric and hydrodynamic parameters has been obtained. The dispersed composition is described and dependences are given for determining the main characteristics used in physicochemical processes. The theoretical calculation of the movement of particles of the dispersed phase in the working volume of the apparatus at different flow rates of liquid and gas has been carried out. Theoretical and experimental methods were used to estimate the carryover of the liquid phase, an analysis of the process was carried out, and practical recommendations were given.

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Experimental Study of Heat and Mass Transfer in a Swirling Gas Flow

Heat Transfer Research ◽

10.1615/heattransres.v37.i8.20 ◽

2006 ◽

Vol 37 (8) ◽

pp. 663-673

Author(s):

A. A. Yudakov ◽

O. N. Tsybul'skaya

Keyword(s):

Mass Transfer ◽

Experimental Study ◽

Heat And Mass Transfer ◽

Gas Flow

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Mass Transfer Coefficients during Steel Decarburization in a RH Degasser

Defect and Diffusion Forum ◽

10.4028/www.scientific.net/ddf.273-276.679 ◽

2008 ◽

Vol 273-276 ◽

pp. 679-684

Author(s):

Roberto Parreiras Tavares ◽

André Afonso Nascimento ◽

Henrique Loures Vale Pujatti

Keyword(s):

Mass Transfer ◽

Reynolds Number ◽

Transfer Coefficient ◽

Mass Transfer Coefficient ◽

Gas Flow ◽

Vacuum Chamber ◽

Volumetric Mass Transfer Coefficient ◽

Gas Flow Rate ◽

Rh Process ◽

Kinetics Of

The RH process is a secondary refining process that can simultaneously attain significant levels of removal of interstitial elements, such as carbon, nitrogen and hydrogen, from liquid steel. In the RH process, the decarburization rate plays a very important role in determining the productivity of the equipment. The kinetics of this reaction is controlled by mass transfer in the liquid phase. In the present work, a physical model of a RH degasser has been built and used in the study of the kinetics of decarburization. The effects of the gas flow rate and of the configurations of the nozzles used in the injection of the gas have been analyzed. The decarburization reaction of liquid steel was simulated using a reaction involving CO2 and caustic solutions. The concentration of CO2 in the solution was evaluated using pH measurements. Based on the experimental results, it was possible to estimate the reaction rate constant. A volumetric mass transfer coefficient was then calculated based on these rate constants and on the circulation rate of the liquid. The logarithm of the mass transfer coefficient showed a linear relationship with the logarithm of the gas flow rate. The slope of the line was found to vary according to the relevance of the reaction at the free surface in the vacuum chamber. A linear relationship between the volumetric mass transfer coefficient and the nozzle Reynolds number was also observed. The slopes of the lines changed according to the relative importance of the two reaction sites, gas-liquid interface in the upleg snorkel and in the vacuum. At higher Reynolds number, the reaction in the vacuum chamber tends to be more significant.

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Mass Transfer in Tubular Ceramic Membranes for Polluted Water Treatment - Numerical Simulation

Diffusion Foundations ◽

10.4028/www.scientific.net/df.20.16 ◽

2018 ◽

Vol 20 ◽

pp. 16-33 ◽

Cited By ~ 1

Author(s):

J. Saraiva de Souza ◽

S. José dos Santos Filho ◽

Severino Rodrigues de Farias Neto ◽

A.G. Barbosa de Lima ◽

H.A. Luma Fernandes Magalhães

Keyword(s):

Mass Transfer ◽

Water Treatment ◽

Produced Water ◽

Ceramic Membrane ◽

Porous Ceramic ◽

Ceramic Membranes ◽

Numerical Results ◽

Polluted Water ◽

Separation Processes ◽

Water Separation

Innovative technologies are needed to attend the increasingly strict requirements for produced water treatment, since most of the separation processes are limited to particles larger than 10 μm. Separation processes using ceramic membranes are attracting great interest from academic and industrial community. Nevertheless, few studies, especially numerical, regarding the inorganic membrane’s application for the polluted water separation have been reported. In the present work, therefore, a study of fluid-flow dynamics for a laminar regime in porous tubes (tubular porous ceramic membrane) has been performed. The mass, momentum and mass transport conservation equations were solved with the aid of a structured mesh using ANSYS CFX commercial package. The velocity of local permeation was determined using the resistance in series model. The specific resistance of the polarized layer was obtained by Carman-Kozeny equation. The numerical results were evaluated and compared with the results available in the literature, where by a good agreement with each other was found. The numerical results, obtained by the proposed shell and tubular membrane separation module, indicate that there is facilitation of mass transfer and hence a reduction in the thickness of the polarized boundary layer occurs.

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An experimental investigation of mass transfer from a gas flow to liquid jets

International Journal of Heat and Mass Transfer ◽

10.1016/0017-9310(80)90124-6 ◽

1980 ◽

Vol 23 (3) ◽

pp. 355-361 ◽

Cited By ~ 1

Author(s):

H.T. Karlsson ◽

S. Åberg ◽

I. Bjerle

Keyword(s):

Mass Transfer ◽

Experimental Investigation ◽

Gas Flow ◽

Liquid Jets

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Computational study of unsteady gas flow in the combustion chamber of a ramjet engine with heat transfer

Вычислительные технологии ◽

10.25743/ict.2020.25.6.003 ◽

2021 ◽

pp. 50-61

Author(s):

Надежда Петровна Скибина

Keyword(s):

Heat Transfer ◽

Numerical Simulation ◽

Supersonic Flow ◽

Combustion Chamber ◽

Gas Flow ◽

Stokes Equations ◽

Heat Conducting ◽

Measuring Device ◽

Ramjet Engine ◽

Mach Numbers

Проведено численное исследование нестационарного турбулентного сверхзвукового течения в камере сгорания прямоточного воздушно-реактивного двигателя. Описана методика экспериментального измерения температуры на стенке осесимметричного канала в камере сгорания двигателя. Математическое моделирование обтекания исследуемой модели двигателя проводилось для скоростей набегающего потока M = 5 ... 7. Начальные и граничные условия задачи соответствовали реальному аэродинамическому эксперименту. Проанализированы результаты численного расчета. Рассмотрено изменение распределения температуры вдоль стенки канала с течением времени. Проведена оценка согласованности полученных экспериментальных данных с результатами математического моделирования. Purpose. The aim of this study is a numerical simulation of unsteady supersonic gas flow in a working path of ramjet engine under conditions identical to aerodynamic tests. Free stream velocity corresponding to Mach numbers M=5 ... 7 are considered. Methodology. Presented study addresses the methods of physical and numerical simulation. The probing device for thermometric that allows to recording the temperature values along the wall of internal duct was proposed. To describe the motion of a viscous heat-conducting gas the unsteady Reynolds averaged Navier - Stokes equations are considered. The flow turbulence is accounted by the modified SST model. The problem was solved in ANSYS Fluent using finite-volume method. The initial and boundary conditions for unsteady calculation are set according to conditions of real aerodynamic tests. The coupled heat transfer for supersonic flow and elements of ramjet engine model are realized by setting of thermophysical properties of materials. The reliability testing of numerical simulation has been made to compare the results of calculations and the data of thermometric experimental tests. Findings. Numerical simulation of aerodynamic tests for ramjet engine was carried out. The agreement between the results of numerical calculations and experimental measurements for the velocity in the channel under consideration was obtained; the error was shown to be 2%. The temperature values were obtained in the area of contact of the supersonic flow with the surface of the measuring device for the external incident flow velocities for Mach numbers M = 5 ... 7. The process of heating the material in the channel that simulated the section of the engine combustion chamber was analyzed. The temperature distribution was studied depending on the position of the material layer under consideration relative to the contact zone with the flow. Value. In the course of the work, the fields of flow around the model of a ramjet engine were obtained, including the region of supersonic flow in the inner part of axisymmetric channel. The analysis of the temperature fields showed that to improve the quality of the results, it is necessary to take into account the depth of the calorimetric sensor. The obtained results will be used to estimate the time of interaction of the supersonic flow with the fuel surface required to reach the combustion temperature.

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Mass Transfer Enhancement for CO2 Absorption in Structured Packed Absorption Column

Journal of the chemical society of pakistan ◽

10.52568/000803/jcsp/41.05.2019 ◽

2019 ◽

Vol 41 (5) ◽

pp. 820-820

Author(s):

Pongayi Ponnusamy Selvi and Rajoo Baskar Pongayi Ponnusamy Selvi and Rajoo Baskar

Keyword(s):

Mass Transfer ◽

Transfer Coefficient ◽

Mass Transfer Coefficient ◽

Gas Flow ◽

Aqueous Ammonia ◽

Volume Flow Rate ◽

Packed Column ◽

Operating Conditions ◽

Co2 Absorption ◽

Absorption Column

The acidic gas, Carbon dioxide (CO2) absorption in aqueous ammonia solvent was carried as an example for industrial gaseous treatment. The packed column was provided with a novel structured BX-DX packing material. The overall mass transfer coefficient was calculated from the absorption efficiency of the various runs. Due to the high solubility of CO2, mass transfer was shown to be mainly controlled by gas side transfer rates. The effects of different operating parameters on KGav including CO2 partial pressure, total gas flow rates, volume flow rate of aqueous ammonia solution, aqueous ammonia concentration, and reaction temperature were investigated. For a particular system and operating conditions structured packing provides higher mass transfer coefficient than that of commercial random packing.

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