scholarly journals Stable Carbon and Sulfur Isotope Characteristics of Stream Water in a Typical Karst Small Catchment, Southwest China

Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 523
Author(s):  
Yang Tang ◽  
Ruiyin Han

Surface water samples from the Maolan National Natural Reserved Park (MNNRP) were analyzed from Sept. 2013 to June 2014, for major ion concentrations (K+, Na+, Ca2+, Mg2+, Cl−, SO42−, HCO3−), δ13C-DIC and δ34S-SO42− to quantify the sources of solutes and chemical weathering. The results show that HCO3− and SO42− are the main anions in Banzhai watershed, which account for 86.2 and 10.4% of the total anion equivalent, respectively. While Ca2+ and Mg2+ account for 76.9 and 20.5%, respectively. Considerable Mg2+ in stream water indicates that it may be affected by dolomite weathering. stream water samples present the δ13C-DIC values in the range of −16.9‰~−10.8‰ (mean value was −13.9‰), which were lower than that of the groundwater. The δ34S-SO42− values ranged from −15.2‰ to 1.7‰ (mean value was −4.4‰). There was a negative correlation between HCO3− content and δ13C value, implying the result of the interaction of temperature and precipitation intensity in different seasons. The significant positive correlation between SO42− content and δ13C-DIC indicates that H2SO4 may be involved in the weathering process of carbonate rocks in small watershed scale. The content of SO42− in a school sample site was much higher than that of other sample sites for the interference from human sources. The δ34S values show that the average δ34S-SO42− in most sites is close to the δ34S isotopic values of Guizhou coal and rain, indicating that they may be affected by local coal.

2017 ◽  
Vol 43 (4) ◽  
pp. 1737
Author(s):  
E. Kelepertzis ◽  
A. Argyraki ◽  
E. Daftsis ◽  
D. Ballas

The present study reports on a four sampling period (April 2008-July 2008-November 2008-February 2009) study of water quality in streams of NE Chalkidiki. A total of 80 surface water samples were collected and analysed for the major ions Ca2+, Mg2+, K+, Na+, Cl- , HCO3 - , SO4 2-, NO3 - and the trace elements Pb, Fe, Cd, Cu, Cr, Ni, Zn, Mn and As. Also pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Temperature, as well as the stream water discharge at each sampling point, were determined in the field. The treatment and the subsequent evaluation of the data showed that the water samples are divided into three separate groups, reflecting the chemistry of water in the three sub-basins of the area i.e., Kokkinolakkas, Kerasia and Piavitsa. The water of the first one is possibly affected by the past mining activities of the area, whereas samples from the other two reflect the influence of sulphide mineralization on the hydrogeochemistry of the corresponding streams. No effect of the seasonal differentiation of stream water discharge was observed.


1975 ◽  
Vol 30 (8) ◽  
pp. 962-967 ◽  
Author(s):  
Jörg Schröder

Abstract A method is described to determine for the first time the 85 Kr concentration in seawater. Samples of 220 l of seawater are degassed aboard a research vessel. The krypton contained in the gas sample is isolated in the laboratory and its 8s Kr activity is measured in a gas counter. The background of the lowel-level counting-array is 0.026 cpm; surface water samples yield a netto count-rate of 0.13 cpm. The reproducibility of the method was checked by gas standards (krypton-air mixtures) and moreover by three surface water samples; both sets agree within ± 1 σ, or ± 5%. The mean value of three samples of great depths (1600, 2000, 2000 m) is 5% of the surface water concentration. This figure represents the possible contamination of the samples by atmospheric 85 Kr during the various preparation stages (blank value). Two profiles have been measured from the North Atlantic (about 40°N, 18°W, November 1972). A strong decrease of the 85 Kr concentration is found in the upper 1000 m. In a simple one-dimensional vertical diffusion-advection model the profiles can be simulated with a coefficient of apparent vertical eddy diffusion of 5 cm 2 / sec in the depth range of 300 to 1000 m (main thermocline). A possible application of oceanic 85 Kr data is the combination of depth profiles with those of other tracers, in particular 3 H. Another application of the 85 Kr method is the dating of groundwaters younger than 20 years.


2006 ◽  
Vol 6 (2) ◽  
pp. 47-53 ◽  
Author(s):  
D. Simazaki ◽  
M. Asami ◽  
T. Nishimura ◽  
S. Kunikane ◽  
T. Aizawa ◽  
...  

Nationwide surveys of 1,4-dioxane and methyl-t-butyl ether (MTBE) levels in raw water used for the drinking water supply were conducted at 91 water treatment plants in Japan in 2001 and 2002, prior to the revision of the drinking water quality standards. 1,4-dioxane was widely and continuously detected in raw water samples and its occurrence was more frequent and its concentrations higher in groundwater than in surface water. However, its maximum concentration in raw water was much lower than its new standard value (50 μg/L), which was determined as a level of 10−5 excessive cancer risk to humans. Trace levels of MTBE were also detected in several surface water samples.


Author(s):  
Kamran Bashir ◽  
Zhimin Luo ◽  
Guoning Chen ◽  
Hua Shu ◽  
Xia Cui ◽  
...  

Griseofulvin (GSF) is clinically employed to treat fungal infections in humans and animals. GSF was detected in surface waters as a pharmaceutical pollutant. GSF detection as an anthropogenic pollutant is considered as a possible source of drug resistance and risk factor in ecosystem. To address this concern, a new extraction and enrichment method was developed. GSF-surface molecularly imprinted polymers (GSF-SMIPs) were prepared and applied as solid phase extraction (SPE) sorbent. A dispersive solid phase extraction (DSPE) method was designed and combined with HPLC for the analysis of GSF in surface water samples. The performance of GSF-SMIPs was assessed for its potential to remove GSF from water samples. The factors affecting the removal efficiency such as sample pH and ionic strength were investigated and optimized. The DSPE conditions such as the amount of GSF-SMIPs, the extraction time, the type and volume of desorption solvents were also optimized. The established method is linear over the range of 0.1–100 µg/mL. The limits of detection and quantification were 0.01 and 0.03 µg/mL respectively. Good recoveries (91.6–98.8%) were achieved after DSPE. The intra-day and inter-day relative standard deviations were 0.8 and 4.3% respectively. The SMIPs demonstrated good removal efficiency (91.6%) as compared to powder activated carbon (67.7%). Moreover, the SMIPs can be reused 10 times for water samples. This is an additional advantage over single-use activated carbon and other commercial sorbents. This study provides a specific and sensitive method for the selective extraction and detection of GSF in surface water samples.


Chemosphere ◽  
2009 ◽  
Vol 77 (10) ◽  
pp. 1285-1291 ◽  
Author(s):  
Hing-Biu Lee ◽  
Thomas E. Peart ◽  
M. Lewina Svoboda ◽  
Sean Backus

2014 ◽  
Vol 1010-1012 ◽  
pp. 1059-1063
Author(s):  
Wei Guan ◽  
Tao Fan ◽  
Xiu Qin Zhu

To elucidate the relationship between stable isotopes of precipitation (SIP) and the extreme drought in Kunming area, based on the stable isotopes data of the GNIP in Kunming site from 1986 to 2003, the precipitation line equation is brought forward and the seasonal change rule of stable isotopes are discussed. The stable isotopic compositions of precipitation exhibit great diversities in different seasons during to influences of multiple factors, such as monsoon, rainfall amount moisture source and others. The δ18O values in rainwater exhibit significant seasonal variations, the average of-10.12‰ in rainy season, the dry season is-4.5‰, having lower values in the rainy season and higher one in the dry season. The amount effect of precipitation is very distinct, that concealed the temperature effect. Got the special geographical position,dvalues present unique characteristics, the average ofdvalues is 10.78‰ in rainy season, and is 4.86‰ in dry season, the mean value is generally lower than most parts of the world.


2018 ◽  
Vol 319 (3) ◽  
pp. 907-916 ◽  
Author(s):  
Bhupender Singh ◽  
Krishan Kant ◽  
Maneesha Garg ◽  
Ajit Singh ◽  
B. K. Sahoo ◽  
...  

2015 ◽  
Vol 63 (1) ◽  
pp. 59-60 ◽  
Author(s):  
S Mandal ◽  
N Khuda ◽  
MR Mian ◽  
M Moniruzzaman ◽  
N Nahar ◽  
...  

Abstract not available DOI: http://dx.doi.org/10.3329/dujs.v63i1.21770 Dhaka Univ. J. Sci. 63(1): 59-60, 2015 (January)


2021 ◽  
Vol 25 (1) ◽  
pp. 25-40
Author(s):  
Galina Yotova ◽  
◽  
Svetlana Lazarova ◽  
Veronika Mihaylova ◽  
Tony Venelinov ◽  
...  

Surface water samples in Ogosta River, Bulgaria and wastewater samples at the inlet and outlet of WWTP–Montana were tested for the traditional parameters and ecotoxicological effect. The river and Dam surface waters comply with category A1 of Directive 75/440/EEC for pH, EC, COD, TSS, NO3–, Cl–, SO42–, B, Ba, Co, Cr, Cu, Hg, Mn, Ni, Pb, Se, V and Zn; with category A2 for BOD5, NH4+–N and Fe; and with category A3 for TNb and As. The average annual concentrations of Al, Cr (III), Cr (VI) and U are lower than the set limits in the Water Framework Directive. Arsenic concentration in all the samples exceeds the maximum allowed concentration, a results from natural processes. All the levels of the studied parameters in the outlet wastewater samples are lower than the limits, set in Directive 91/271/EEC and in the complex permit of the WWTP. The results of the biotest Phytotoxkit F™ show low ecotoxicity of the water samples. Optimization of the sample pretreatment prior to this ecotoxicological test is analyzed and discussed.


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