scholarly journals QUALITY CHARACTERISTICS OF SURFACE WATERS AT ASPROLAKKAS RIVER BASIN, N.E. CHALKIDIKI, GREECE

2017 ◽  
Vol 43 (4) ◽  
pp. 1737
Author(s):  
E. Kelepertzis ◽  
A. Argyraki ◽  
E. Daftsis ◽  
D. Ballas
Keyword(s):  
Surface Waters ◽  
Water Samples ◽  
Major Ions ◽  
Stream Water ◽  
Water Discharge ◽  
Sampling Period ◽  
Quality Characteristics ◽  
Sampling Point ◽  
The Past ◽  
Surface Water Samples

The present study reports on a four sampling period (April 2008-July 2008-November 2008-February 2009) study of water quality in streams of NE Chalkidiki. A total of 80 surface water samples were collected and analysed for the major ions Ca2+, Mg2+, K+, Na+, Cl- , HCO3 - , SO4 2-, NO3 - and the trace elements Pb, Fe, Cd, Cu, Cr, Ni, Zn, Mn and As. Also pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Temperature, as well as the stream water discharge at each sampling point, were determined in the field. The treatment and the subsequent evaluation of the data showed that the water samples are divided into three separate groups, reflecting the chemistry of water in the three sub-basins of the area i.e., Kokkinolakkas, Kerasia and Piavitsa. The water of the first one is possibly affected by the past mining activities of the area, whereas samples from the other two reflect the influence of sulphide mineralization on the hydrogeochemistry of the corresponding streams. No effect of the seasonal differentiation of stream water discharge was observed.

scholarly journals Stable Carbon and Sulfur Isotope Characteristics of Stream Water in a Typical Karst Small Catchment, Southwest China

Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 523
Author(s):  
Yang Tang ◽  
Ruiyin Han
Keyword(s):  
Water Samples ◽  
Chemical Weathering ◽  
Stream Water ◽  
Mean Value ◽  
Small Catchment ◽  
Temperature And Precipitation ◽  
Δ13c Value ◽  
Different Seasons ◽  
Sources Of Solutes ◽  
Surface Water Samples

Surface water samples from the Maolan National Natural Reserved Park (MNNRP) were analyzed from Sept. 2013 to June 2014, for major ion concentrations (K+, Na+, Ca2+, Mg2+, Cl−, SO42−, HCO3−), δ13C-DIC and δ34S-SO42− to quantify the sources of solutes and chemical weathering. The results show that HCO3− and SO42− are the main anions in Banzhai watershed, which account for 86.2 and 10.4% of the total anion equivalent, respectively. While Ca2+ and Mg2+ account for 76.9 and 20.5%, respectively. Considerable Mg2+ in stream water indicates that it may be affected by dolomite weathering. stream water samples present the δ13C-DIC values in the range of −16.9‰~−10.8‰ (mean value was −13.9‰), which were lower than that of the groundwater. The δ34S-SO42− values ranged from −15.2‰ to 1.7‰ (mean value was −4.4‰). There was a negative correlation between HCO3− content and δ13C value, implying the result of the interaction of temperature and precipitation intensity in different seasons. The significant positive correlation between SO42− content and δ13C-DIC indicates that H2SO4 may be involved in the weathering process of carbonate rocks in small watershed scale. The content of SO42− in a school sample site was much higher than that of other sample sites for the interference from human sources. The δ34S values show that the average δ34S-SO42− in most sites is close to the δ34S isotopic values of Guizhou coal and rain, indicating that they may be affected by local coal.

scholarly journals Water Quality Assessment of Surface Waters and Wastewaters by Traditional and Ecotoxicological Indicators in Ogosta River, Bulgaria

2021 ◽  
Vol 25 (1) ◽  
pp. 25-40
Author(s):  
Galina Yotova ◽  
◽  
Svetlana Lazarova ◽  
Veronika Mihaylova ◽  
Tony Venelinov ◽  
...  
Keyword(s):  
Water Quality ◽  
Surface Waters ◽  
Water Samples ◽  
Arsenic Concentration ◽  
Sample Pretreatment ◽  
Water Quality Assessment ◽  
Natural Processes ◽  
Ecotoxicological Effect ◽  
Wastewater Samples ◽  
Surface Water Samples

Surface water samples in Ogosta River, Bulgaria and wastewater samples at the inlet and outlet of WWTP–Montana were tested for the traditional parameters and ecotoxicological effect. The river and Dam surface waters comply with category A1 of Directive 75/440/EEC for pH, EC, COD, TSS, NO3–, Cl–, SO42–, B, Ba, Co, Cr, Cu, Hg, Mn, Ni, Pb, Se, V and Zn; with category A2 for BOD5, NH4+–N and Fe; and with category A3 for TNb and As. The average annual concentrations of Al, Cr (III), Cr (VI) and U are lower than the set limits in the Water Framework Directive. Arsenic concentration in all the samples exceeds the maximum allowed concentration, a results from natural processes. All the levels of the studied parameters in the outlet wastewater samples are lower than the limits, set in Directive 91/271/EEC and in the complex permit of the WWTP. The results of the biotest Phytotoxkit F™ show low ecotoxicity of the water samples. Optimization of the sample pretreatment prior to this ecotoxicological test is analyzed and discussed.

scholarly journals Concentration and Detection of Cryptosporidium Oocysts in Surface Water Samples by Method 1622 Using Ultrafiltration and Capsule Filtration

2001 ◽  
Vol 67 (3) ◽  
pp. 1123-1127 ◽  
Author(s):  
Otto D. Simmons ◽  
Mark D. Sobsey ◽  
Christopher D. Heaney ◽  
Frank W. Schaefer ◽  
Donna S. Francy
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Hollow Fiber ◽  
Water Samples ◽  
Environmental Protection Agency ◽  
Fluorescent Antibody ◽  
Immunomagnetic Separation ◽  
Recovery Rates ◽  
Microscopic Evaluation ◽  
Surface Water Samples

ABSTRACT The protozoan parasite Cryptosporidium parvumis known to occur widely in both source and drinking water and has caused waterborne outbreaks of gastroenteritis. To improve monitoring, the U.S. Environmental Protection Agency developed method 1622 for isolation and detection of Cryptosporidium oocysts in water. Method 1622 is performance based and involves filtration, concentration, immunomagnetic separation, fluorescent-antibody staining and 4′,6-diamidino-2-phenylindole (DAPI) counterstaining, and microscopic evaluation. The capsule filter system currently recommended for method 1622 was compared to a hollow-fiber ultrafilter system for primary concentration of C. parvum oocysts in seeded reagent water and untreated surface waters. Samples were otherwise processed according to method 1622. Rates of C. parvumoocyst recovery from seeded 10-liter volumes of reagent water in precision and recovery experiments with filter pairs were 42% (standard deviation [SD], 24%) and 46% (SD, 18%) for hollow-fiber ultrafilters and capsule filters, respectively. Mean oocyst recovery rates in experiments testing both filters on seeded surface water samples were 42% (SD, 27%) and 15% (SD, 12%) for hollow-fiber ultrafilters and capsule filters, respectively. Although C. parvum oocysts were recovered from surface waters by using the approved filter of method 1622, the recovery rates were significantly lower and more variable than those from reagent grade water. In contrast, the disposable hollow-fiber ultrafilter system was compatible with subsequent method 1622 processing steps, and it recovered C. parvum oocysts from seeded surface waters with significantly greater efficiency and reliability than the filter suggested for use in the version of method 1622 tested.

scholarly journals Occurrence and Distribution of Pharmaceuticals and their Transformation Products in Luxembourgish Surface Waters

2021 ◽  
Author(s):  
Randolph Singh ◽  
Adelene Lai ◽  
Jessy Krier ◽  
Todor Kondić ◽  
Philippe Diderich ◽  
...  
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Water Samples ◽  
Transformation Products ◽  
Computational Tools ◽  
Data Files ◽  
Surface Water Samples

<p>This pre-print describes the analysis of pharmaceuticals and their transformation products in surface water samples collected in Luxembourg from 2019 to 2020. Details of the experimental and computational tools and workflows used are fully described in the manuscript. Links to the suspect lists, codes used, and data files are also provided.</p>

scholarly journals DISTRIBUTION OF CHEMICAL ELEMENTS IN SURFACE WATERS FROM THE CRNA RIVER BASIN, REPUBLIC OF MACEDONIA

2018 ◽  
Vol 39 (1) ◽  
pp. 31 ◽  
Author(s):  
Dimitri Tomovski ◽  
Trajče Stafilov ◽  
Robert Šajn ◽  
Katerina Bačeva Andonovska
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Water Samples ◽  
Inductively Coupled Plasma ◽  
Chemical Elements ◽  
Emission Spectrometry ◽  
Anthropogenic Influence ◽  
Mean Values ◽  
Republic Of Macedonia ◽  
Surface Water Samples

An investigation of the distribution of 23 chemical elements (Ag, Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sr, V and Zn) in surface water samples from the entire basin of the Crna River, Republic of Macedonia, was carried out. In total 31 water samples were collected, from which 8 samples from the Crna River and 4 samples from four main tributaries of Crna River in the Pelagonia Valley (Blato, Prilepska Reka, Dragor and Jelaška Reka). Also, surface water samples were collected from 3 locations in the Tikveš Lake, 8 locations from the Majdanska River and river of Blašnica before its inflow into the Tikveš Lake and from 7 locations of the lower course of the Crna River after the dam of Tikveš Lake until its inflow into the river of Vardar. Determination of the concen-tration of the investigated elements was performed by using atomic emission spectrometry with inductively coupled plasma (ICP-AES). All data obtained for the analyzed samples were statistically processed using software Stat Soft 11.0 where the descriptive statistical analysis of the value for the concentration of the elements was performed. The maps of spatial distribution of the concentration for each element and a histograms for the representation of elements with mean values of the concentrations by regions, were also prepared. The obtained results show that the concentration of investigated element are mainly followed the lithology of the region. However, higher concentrations of arsenic were found in the water samples from the river of Blašnica which is a result of anthropogenic influence from the abounded Allchar mine on the Kožuf Mountain. Also, the increased concentrations of nickel were found in the samples from the lower couse of the Crna River after the dam of Tikveš Lake due to the anthropogenic influence from the ferronickel smelter plant Feni Industry, which can influence the quality parameters of surface waters.

scholarly journals Chemical Quality of Surface Water of Bhola Sadar Upazila in Bangladesh for Irrigation, Aquaculture, Drinking and Livestock Consumption

2015 ◽  
Vol 6 (1) ◽  
pp. 131-140
Author(s):  
MF Karim ◽  
MW Zaman ◽  
R Sultana ◽  
MU Nizam ◽  
MR Kamruzzaman
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Water Samples ◽  
Pond Water ◽  
Magnesium Content ◽  
Low Salinity ◽  
Quality Of Water ◽  
Hard Limit ◽  
Surface Water Samples

A study was carried out with 25 pond water samples of Bhola Sadar Upazila to assess the quality of surface water for irrigation, aquaculture, drinking and livestock consumption. Chemical analyses of different parameters were done to assess the quality of water. All of the water samples showed slightly acidic in nature. Sixteen surface water samples were not suitable for drinking and aquaculture in respect of pH (pH <6.5). Electrical conductivity (EC) categorized the waters as “low salinity” (C1) to “medium salinity” (C2) class for irrigation. With respect to total dissolved solids surface waters were within “highest desirable limit” for drinking and irrigation and suitable for livestock consumption and aquaculture. Calcium and Magnesium content rated the samples as “maximum permissible” and “highest desirable” limit for drinking. All the samples were suitable for drinking in case of Na and K, 21 samples were not suitable for aquaculture due to higher (>5.0 mg L-1) K content. Six samples were unsuitable for livestock due to higher (Cl >30mgL- 1) Cl values. SSP rated 9 samples as “good”, 1 as “excellent”, 6 as “doubtful” and 9 as “permissible” for irrigation. With respect to RSC 21 samples were “suitable”, 3 were “marginal” and 1 was “unsuitable” for irrigation. Hardness classified 14 samples within “moderately hard”, 10 within “soft” and only one as “hard” limit for irrigation and 1 sample (No. 16) was unsuitable for livestock consumption. P, B, Cu and As concentration categorized all the samples suitable for irrigation, aquaculture, drinking and livestock consumption.DOI: http://dx.doi.org/10.3329/jesnr.v6i1.22053 J. Environ. Sci. & Natural Resources, 6(1): 131-140 2013

Neonicotinoids Detection by new LC-MS/MS Method in Romanian Surface Waters

2017 ◽  
Vol 68 (8) ◽  
pp. 1716-1722 ◽  
Author(s):  
Vasile Ion Iancu ◽  
Toma Galaon ◽  
Marcela Niculescu ◽  
Carol Blaziu Lehr
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Water Samples ◽  
Solid Phase ◽  
Monitoring Program ◽  
Danube River ◽  
Limit Of Quantification ◽  
Neonicotinoid Insecticides ◽  
Relative Standard ◽  
Surface Water Samples

Increasing and widespread use of neonicotinoid insecticides in all world, together with their highly toxicity to invertebrates and environmental persistence mean that surface waters need to be monitored for these compounds. In the 2015, neonicotinoid insecticides have been incorporated in the watch list of substances for a European Union monitoring program (495/2015/ EU). A new method using automated solid phase extraction (SPE) with polymeric cartridges (OASIS HLB) followed by LC-MS/MS provided good separation of the most common neonicotindoid compounds. The method was developed for the determination of four neonicotinoid insecticides (nitenpyram, thiamethoxam, clothianidin, acetamiprid) in surface water with low limit of quantification (0.3-0.9 ng/L, nanograms per liter). Recoveries in surface water samples fortified at 200 ng/L for each compound ranged from 71.4 to 109.9 %; relative standard deviation ranged from 4 to 9%. The method was applied to water samples from four streams in Romania, Danube River and its tributaries (Arges River, Jiu River, and Olt River). The surface water samples were found to be contaminated clothianidin (1.08-6.4 ng/L) and by thiamethoxam (1.1-3.8ng/L). The highest concentrations were recorded in Danube River in Oltenita point (6.4ng/L) and in Gura-Vaii point (5.5ng/L). The concentration of acetamiprid and nitenpyram were situated below limit of quantification in all samples.

7 years of monitoring of 40K in surface water samples from Olt River, Romania

2020 ◽  
pp. 49-60
Author(s):  
Mihaela Roxana Ene ◽  
◽  
Gheorghe Bulubasa ◽  
Alina Florentina Miu ◽  
◽  
...  
Keyword(s):  
Surface Water ◽  
Water Samples ◽  
Gamma Ray ◽  
Germanium Detector ◽  
Gamma Ray Spectrometry ◽  
Sampling Point ◽  
Naturally Occurring ◽  
Significant Difference ◽  
Monitoring Study ◽  
Surface Water Samples

The aim of this study was to determine naturally occurring radionuclide 40K in surface water samples from Olt River, Romania. A monitoring study during 7 years (2012-2018) was accomplished. A number of 728 surface water samples were collected and analysed. Several hundred pollution sources were identified for the Olt River basin in Romania. This study is of particular importance since it is the first effort to evaluate the activity concentrations of 40K in surface water from Romania for such a long period. For this reason, two sampling points along the Olt River were chosen, the first one upstream of the discharge point of the magistrate channel "Deversor Olt" (reference location) and respectively the second sampling point downstream of the liquid effluents discharges point (indicator location). The radioactivity concentration of 40K was determined from the 1460.8 keV photopeak. The method used was high resolution gamma ray spectrometry performed with a hyperpure germanium detector. An activity concentration for 40K, no more than 2.14 ± 0.32 Bq l -1 , is observed, but the values recorded for the background location had a slight, but not significant difference compared with the values recorded in the second sampling point.

Relationships between pH, colour and heavy metal concentrations in the Tinto and Odiel rivers (southwest Spain)

2010 ◽  
Vol 41 (5) ◽  
pp. 406-413 ◽  
Author(s):  
M. L. de la Torre ◽  
D. Sánchez-Rodas ◽  
J. A. Grande ◽  
T. Gomez
Keyword(s):  
Heavy Metals ◽  
Surface Water ◽  
Water Samples ◽  
Mine Drainage ◽  
Iron Hydroxide ◽  
Sampling Point ◽  
Odiel River ◽  
Tinto River ◽  
Co Precipitation ◽  
Surface Water Samples

The relationships between pH, colour, Fe, Mn, Cu, Zn, Cd and sulphates in surface water samples collected from the Tinto and Odiel Rivers (southwest Spain) have been studied. These rivers are adversely affected by the inputs of acid and heavy metals due to Acid Mine Drainage (AMD). Samples were collected from both rivers on a monthly sampling basis from 1995 to 2001. The analytical results showed that pH (mean pH 3.1) in the water samples of the Odiel River presented a greater correlation with heavy metals, colour and sulphates than in the Tinto River (mean pH 2.5). The tidal effect at the sampling point at the Odiel River appears to cause a greater variation of the pH values (2.5–4.4), resulting in the precipitation of iron hydroxide and the co-precipitation of other metals when the pH increased. This phenomenon was not observed in the samples collected from the more acidic Tinto River (pH 2.1–3.2). A similar relationship was observed for the heavy metals and the colour of the surface water of both rivers.

scholarly journals Seasonal distribution of multiclass pesticide residues in the surface waters of northwest Croatia

2021 ◽  
Vol 72 (4) ◽  
pp. 280-288
Author(s):  
Sanja Fingler ◽  
Gordana Mendaš ◽  
Marija Dvoršćak ◽  
Sanja Stipičević ◽  
Želimira Vasilić ◽  
...  
Keyword(s):  
Surface Waters ◽  
Water Samples ◽  
Rural Areas ◽  
Pesticide Residues ◽  
High Performance ◽  
Solid Phase ◽  
Stream Water ◽  
Gas Chromatography Mass Spectrometry ◽  
Array Detection ◽  
Agricultural Areas

Abstract As part of our OPENTOX project, we evaluated the incidence and mass concentrations of multiclass pesticide residues in 23 river/stream water samples collected in urban and agricultural areas of northwest Croatia at various points of the pesticide application season in 2015. The study included 16 compounds of five herbicide classes and seven compounds of three insecticide classes. Pesticide residues were accumulated from water by solid-phase extraction and analysed using high performance liquid chromatography with UV-diode array detection and/or gas chromatography-mass spectrometry. Herbicide residues were more common than the insecticide ones, and, as expected, they peaked in the middle of the application season. Metolachlor showed the highest concentrations and was found in 91 % of all samples, followed by terbuthylazine, found in 70 % of the samples. The highest total mass concentration of detected pesticides was measured in the water samples of the Krapina (3992 ng/L) and Sutla (3455 ng/L) collected in rural areas with intensive agriculture. Our findings strongly speak in favour of continued monitoring of surface waters and possibly extending the list of priority water pollutants.

Sign in / Sign up

Export Citation Format

Share Document