scholarly journals Application of the method determining the pressure of the spreading coal and blends, as a method of extending the life of coke oven batteries

2019 ◽  
Vol 119 ◽  
pp. 98-106
Author(s):  
A. V. Sytnik
Keyword(s):  
Coke Oven ◽  
Raw Material ◽  
Bursting Pressure ◽  
Material Base ◽  
Coal Blend ◽  
Coke Ovens ◽  
Standard Value ◽  
Coke Batteries ◽  
Refractory Masonry ◽  
Selection Of

The analysis the state of coke batteries was carried out, with the help of which the main types of masonry wear the coke oven heating walls were established. The dynamics and nature of the damage suggest that for batteries with a long service life an individual approach is needed, both in the choice of the technological mode and in the selection of the raw material base coking, taking into account the pressure magnitude of coking blend. Since, in the process of coking coal blends, one the external manifestations of this process is a development of pressure expansion to the walls of coke oven chambers, when calculating the strength of coke ovens, the pressure of 7 kPa is taken as the critical pressure expansion. Exceeding this value leads to an increase in amperage and drilling of furnaces during the coke delivery of, premature wear of the refractory masonry, which requires more frequent repairs, and in extreme cases, deformation the walls of coking chambers. Therefore, coal blend, it is necessary to compile, taking into account not only the production of coke with the necessary mechanical strength, but also ensuring a bursting pressure not exceeding the standard value. To do this, in a laboratory setting to determine the pressure expansion, it is necessary to classify the incoming coal concentrates according to the indicator of pressure expansion, in order to compile blends with a safe value of pressure expansion.

scholarly journals MEASUREMENT OF THE CONTENT OF MONOETHANOLAMINE DURING THE CONTROL OF THE TECHNOLOGICAL PROCESS OF DESULFURIZATION AND IN THE ENVIRONMENTAL OBJECTS

2021 ◽  
Vol 1 ◽  
pp. 28-36
Author(s):  
A.Yu. Martynova ◽  
A.I. Larina ◽  
V.A. Saraeva
Keyword(s):  
Sodium Hydroxide Solution ◽  
Coke Oven ◽  
Coke Production ◽  
Sulfur Compounds ◽  
Raw Material ◽  
Test Substance ◽  
Material Base ◽  
Chemical Production ◽  
Coke Oven Gas ◽  
Environmental Objects

The problem of cleaning coke oven gas from sulfur compounds, despite their recent decrease in the raw material base of coking, remains relevant in connection with the requirements to reduce sulfur dioxide emissions into the atmosphere. When using monoethanolamine for the purification of coke oven gas from sulfur compounds, production workers are faced with the problems of determining the exact concentration both in solutions and in coke oven gas and in environmental objects. The article provides an overview of the currently existing methods for the quantitative determination of the content of monoethanolamine in liquid and gaseous media. The results of studies of the possibility of their use in the conditions of by-product coke production are presented, directions of improvement of the known methods are determined in order to eliminate the influence of accompanying components inherent in by-product coke production (in particular, ammonia, amines, phenols, etc.), which distort the analysis results. The authors describe the methods of increasing the selectivity of analytical methods for determining the content of monoethanolamine in: – coke oven gas - based on the absorption of the test substance from coke oven gas by a solution of orthoboric acid, followed by its determination in a solution with pnitrophenyldiazonium; – the air of the working area under the conditions of by-product coke production - it was proposed to eliminate the negative effect of hydrogen sulfide and phenol using an absorber containing a sodium hydroxide solution located in front of the absorber with a hydrochloric acid solution for monoethanolamine (a revised measurement procedure with additions set out in accordance with the requirements of the current legislation in the field of metrology and established metrological characteristics, agreed by the Chief Sanitary Doctor of Ukraine). The directions of research necessary for the development of a method for determining the content of monoethanolamine in process waters of coke-chemical production are outlined. Keywords: desulfurization, monoethanolamine, content determination, selectivity, ammonia, p-nitrophenyldiazonium, coke oven gas, complex compound, color intensity, photometry, measurements. Corresponding author A.Yu. Martynova, e-mail: [email protected]

scholarly journals The selection of technological basis of deep processing of coal.

2021 ◽  
Vol 4 ◽  
pp. 15-21
Author(s):  
M.O. Gordienko
Keyword(s):  
Melting Point ◽  
Environmental Safety ◽  
Coke Production ◽  
Raw Material ◽  
State Enterprise ◽  
Material Base ◽  
Deep Processing ◽  
Technological Basis ◽  
Thermochemical Processing ◽  
Selection Of

THE SELECTION OF TECHNOLOGICAL BASIS OF DEEP PROCESSING OF COAL © M.O. Gordienko (State Enterprise "Ukrainian State Research Coal Chemical Institute (UHIN)", 61023, Kharkov, Vesnina st., 7, Ukraine) The article is devoted to the analysis of the possibility of expanding the raw material base of thermal energy, as well as meeting the demand for motor fuels and chemical products through the thermochemical processing of coal, the reserves of which are large enough and available for extraction and transportation. Moreover, in contrast to technologies such as methanization and liquefaction, the most promising type of deep processing of coal seems to be its gasification. This process is carried out in sealed devices of high power according to the technologies that have a long history of improvement on an industrial scale by the world's leading companies. It was emphasized that Ukraine has significant reserves of low-calorie coal (constantly expanding due to waste of coal preparation), the thermochemical processing of which can significantly expand the domestic energy base. The basic principles of classification and technological foundations of existing industrial and industrial research installations for gasification of coal and similar materials are given. The basic diagrams and main parameters of the existing installations, which carry out the gasification process at temperatures below the melting point of the mineral (ash-forming) components of the raw material, are described - Sasol Lurgi and SES Gasification Technology (SGT). Based on the data on the world experience in the operation of thermochemical coal processing units, it is shown that low-temperature (carried out at a temperature below the melting point of the mineral ashforming components) gasification of various types of non-coking coal with certain technological solutions can be no less effective than more complex and expensive high-temperature technologies. There are grounds for believing that the efficiency of gasification with ash removal in a solid state can be further increased by using some of the technological capabilities available in coke production. Keywords: brown coal, non-coking coals, thermochemical processing, gasification, efficiency, degree of carbon conversion, energy carriers, synthesis gas, environmental safety. Corresponding author M.O. Gordienko, е-mail: [email protected]

Possibilities of Reducing the Apparent Porosity of Silica Bricks for the Coke Batteries

2014 ◽  
Vol 897 ◽  
pp. 121-124
Author(s):  
Lenka Nevřivová ◽  
Miroslav Kotouček ◽  
Karel Lang
Keyword(s):  
Compaction Pressure ◽  
Coke Oven ◽  
Coke Battery ◽  
Apparent Porosity ◽  
Point Of View ◽  
Repeated Heating ◽  
Heating And Cooling ◽  
Arc Furnaces ◽  
Coke Ovens ◽  
Coke Batteries

Silica is used for lining of the upper parts of glass furnaces and their regenerators and for lining of the lids of arc furnaces and for the coke oven batteries construction. Silica bricks represent 60% of refractory material used for a coke battery construction. Coke ovens are generally the largest oven aggregates, where silica material is used. The whole coke oven battery may reach the length up to 80 m due to the chamber sizes. A single coke oven battery contains up to 50.000 tons of refractories [1]. From the material science point of view, the durability of silica bricks depends on numerous parameters including first of all porosity and mineral composition. Microstructure of silica bricks changes during their application due to the heat load, repeated heating and cooling, and direct contact with the oven atmosphere. The paper discusses the possibility of reducing the apparent porosity and increasing of bulk density of coke oven silica bricks. It describes the effects of an iron dust, microsilica and influence of the compaction pressure on the coke oven silica microstructure. Functional characteristics of the material prepared according to the new standard recipes are compared with the properties of standard silica products.

scholarly journals SELECTION OF THE MASHING MODE IN THE PREPARATION OF BEER WORT BY USING THE WHEAT MALT

2021 ◽  
Vol 447 (3) ◽  
pp. 94-98
Author(s):  
A. Tyan ◽  
M.M. Bayazitova
Keyword(s):  
Colloidal Stability ◽  
Raw Materials ◽  
Raw Material ◽  
Cereal Crops ◽  
Material Base ◽  
Consumer Market ◽  
Low Protein ◽  
Alternative Crops ◽  
Selection Of ◽  
Promising Type

In recent years, according to the sharp increase in the number of breweries and high competition on the consumer market, it is very important to extend the raw material base of the industry and the range of produced beer from the recommended raw materials. One of the ways to expand the raw material base of breweries is developing recommendations for the use of new zoned varieties of barley, in particular as well as the use of special malts, wheat malt, the development of new recipes and technologies for beer producing. As it is known, barley, wheat, rye, and malt produced from these cereal crops are processed to a greater extent at present. Along with traditional types of cereals, such cereals as amaranth, buckwheat, triticale, sorghum, oats, etc. are used. Among the listed alternative crops, wheat should be noted as the most promising type of cereal raw materials. Wheat (Triticum) is an herbaceous annual plant of the cereal family. Hard wheat (T. durum) and soft wheat (T. aestivum) are the most important. Both species are holo-grain, i.e., the grain is covered with fruiting and seed shells, fused and consisting of several layers of cells, and do not have flower (chaff) shells. At present time, high-yielding winter and spring wheat (T.aestivum) is mainly cultivated. This species has loose floury grains and rather low protein content. It should be noted that unmalted wheat is rarely used in brewing. This is because that the use of this cereal as unmalted material leads to significant deviations in the technological process, in particular, the filtration of wort and beer slows down, reduces the colloidal stability of the final product. At the same time, as a raw material for malt, wheat has some advantages over barley. The article deals with the effect of different amounts of wheat malt on the mashing process, the percentage of mashing and mashing modes of barley and wheat malt are selected experimentally.

scholarly journals Raw material base for coking of the Coke Production of PJSC "ARCELORMITTAL KRYVYI RIH" in the period from 2017 to 2021.

2021 ◽  
Vol 4 ◽  
pp. 4-9
Author(s):  
N.V. Mukina ◽  
D.V Miroshnichenko
Keyword(s):  
Quality Indicators ◽  
Coke Oven ◽  
Ash Content ◽  
Raw Material ◽  
Material Base ◽  
Chemical Production ◽  
Total Sulfur Content ◽  
Blast Furnace Coke ◽  
Coal Charge ◽  
Furnace Coke

RAW MATERIAL BASE FOR COKING OF THE COKING PRODUCTION OF PJSC "ARCELORMITTAL KRYVYI RIH" IN THE PERIOD FROM 2017 TO 2021 © N.V. Mukina (Coke-chemical production of PJSC "ArcelorMittal Kryvyi Rih", 50095, Dnepropetrovsk region, Kryvyi Rih, Krivorozhstal st., 1, Ukraine), D.V. Miroshnichenko, Doctor of Technical Sciences (NTU "Kharkiv Polytechnic Institute", 61002, Kharkiv, st. Kirpicheva, 2, Ukraine) The article presents the data on coal components that were used in the charge for coking coke oven batteries №№1-4 (bulk coal charge) and №№ 5, 6 (tamped coal charge) of the coke-chemical production of PJSC "ArcelorMittal Kryvyi Rih" in the period from 2017 to 2021, as well as averaged information on some quality indicators of the produced coke. In general, the coal raw material base of the enterprise for the last five years has been of a stable inter-basin nature with a predominance of coals from the USA, Kazakhstan, and the Russian Federation. It is shown that, as the tamping technology suggests, moisture content, bulk density and content of classes less than 0.16 and less than 3.0 mm in coal charges supplied to the coal waste plant. №№ 5, 6 are significantly higher than the values of similar indicators of coal charges supplied to the numbers 1-4. Along with this, due to the use of coals of a certain quality, ash content, total sulfur content and the thickness of the plastic layer in coal charges supplied to the coal bunker №№ 1-4, is slightly higher than similar indicators of coal charges supplied to the boiler №№ 5, 6. In total, during 2017-2021, the composition and quality indicators of the coal charge for the production of coke at the boiler plant №№ 1-4 practically did not change, while in the coal charge for the production of coke on coke oven batteries №№ 5, 6 there is a decrease in the share of highly volatile coals with a simultaneous increase in the content of medium-volatile and low-volatile components. The given values of the quality indicators of the obtained blast-furnace coke indicate that the use of tamping technology makes it possible to obtain blast-furnace coke of a higher quality than by using a traditional technology. In particular, the coke obtained at the oven batteries №№ 5, 6 are characterized by lower values of ash content, total sulfur content and abrasion (M10) with higher values of mechanical strength in terms of M25 and post-reaction strength (CSR). Keywords: coal, inter-basin raw material base, coking, charge tamping, coke quality. Corresponding author N.V. Mukina, е-mail: [email protected]

scholarly journals EFFECT OF BULK DENSITY OF COAL BLEND ON THE CALORIFIC VALUE OF COKE

2020 ◽  
Vol 6 ◽  
pp. 4-12
Author(s):  
I.V. Miroshnichenko ◽  
D.V. Miroshnichenko ◽  
I.V. Shulga ◽  
Yu.V. Nikolaychuk
Keyword(s):  
Bulk Density ◽  
Quality Indicators ◽  
Calorific Value ◽  
Dry Weight ◽  
Raw Material ◽  
State Enterprise ◽  
Water Molecules ◽  
Material Base ◽  
Gross Calorific Value ◽  
Coal Blend

The article is devoted to laboratory studies to determine the influence of the bulk density of a coal blend (in particular, tamped) on the value of the gross calorific value of the coke obtained from it. To making up a model coal blends, coal concentrates has been selected and analyzed from the raw material base of Ukrainian coke enterprises. From the studied coals four variants of coal blends has been formed, characterized by different grades. Experimental coking of coal charges has been carried out in a 5-kg laboratory oven designed by the State Enterprise "UKHIN". The bulk coking blend has been moistened to 8 %. The blend for tamping has been moistened to 12 %, tamped into a special matrix to a density of 1.15 t/m3 , and then the tamped coal cake has been placed in a retort for coking. It has been established that the maximum value of the gross calorific value of blast-furnace coke is achieved during coking of coal blends, which are characterized by the following set of quality indicators: R0=0,91–0,94 %; Vdaf = 30,9-31,0 %; C daf = 83,80-83,83 %; Hdaf = 5,01-5,02 %; Od daf = 8,42-8,45 %. It has been shown that an increase in the bulk density of coal blends, characterized by the same set of quality indicators, from 800 to 1150 kg/m3 leads to an increase in the gross calorific value of blastfurnace coke by 0,05-0,12 MJ/kg. Hydrogen bonds are a factor that contributes to the denser packaging of coal grains in the load. For this, the number of water molecules must correspond to the number of polar bonds in carbon macromolecules. With a lack of water, not all polar functional groups present in macromolecules will participate in the formation of new bonds, which will not allow to the coal grains to be packed more tightly. On the contrary, at higher humidity, excess water molecules will take up space in the feed, not participating in the formation of bonds with carbon macromolecules, which will lead to a decrease in the bulk density in terms of dry weight.

RESOURCE SAVING APPROACH TO RAW MATERIAL BASE OF BUILDING INDUSTRY

2011 ◽  
Vol 1 (1) ◽  
pp. 112-116 ◽  
Author(s):  
N. G ChUMAChENKO
Keyword(s):  
Building Materials ◽  
Construction Materials ◽  
Industrial Wastes ◽  
Raw Material ◽  
Building Industry ◽  
Material Base ◽  
Resource Saving ◽  
Toxic Level ◽  
Primary Products ◽  
Selection Of

An estimate of natural and technogenic raw material bases for construction materials production is given. These two groups of primary products are suggested to be considered as a united raw material base for building industry due to including industrial wastes. To be selected for an appropriate use every industrial waste sort must undergo several levels of estimation on the following criteria: toxic level; chemical and mineral composition; selection of wastes from ready-made construction materials or their components; selection of wastes from ready-made raw mixes for the production of building materials; estimation of aggregate state; estimation of the amount of formation. After such a multilevel estimation, waste is getting a certain status.

scholarly journals MEASUREMENT OF THE CONTENT OF MONOETHANOLAMINE DURING THE CONTROL OF THE TECHNOLOGICAL PROCESS OF DESULFURIZATION AND IN THE ENVIRONMENTAL OBJECTS

2021 ◽  
Vol 1 ◽  
pp. 28-36
Author(s):  
A.Yu. Martynova ◽  
V.A. Saraeva ◽  
A.I. Larina
Keyword(s):  
Sodium Hydroxide Solution ◽  
Coke Oven ◽  
Coke Production ◽  
Sulfur Compounds ◽  
Raw Material ◽  
Test Substance ◽  
Material Base ◽  
Chemical Production ◽  
Coke Oven Gas ◽  
Environmental Objects

The problem of cleaning coke oven gas from sulfur compounds, despite their recent decrease in the raw material base of coking, remains relevant in connection with the requirements to reduce sulfur dioxide emissions into the atmosphere. When using monoethanolamine for the purification of coke oven gas from sulfur compounds, production workers are faced with the problems of determining the exact concentration both in solutions and in coke oven gas and in environmental objects. The article provides an overview of the currently existing methods for the quantitative determination of the content of monoethanolamine in liquid and gaseous media. The results of studies of the possibility of their use in the conditions of by-product coke production are presented, directions of improvement of the known methods are determined in order to eliminate the influence of accompanying components inherent in by-product coke production (in particular, ammonia, amines, phenols, etc.), which distort the analysis results. The authors describe the methods of increasing the selectivity of analytical methods for determining the content of monoethanolamine in: – coke oven gas - based on the absorption of the test substance from coke oven gas by a solution of orthoboric acid, followed by its determination in a solution with pnitrophenyldiazonium; – the air of the working area under the conditions of by-product coke production - it was proposed to eliminate the negative effect of hydrogen sulfide and phenol using an absorber containing a sodium hydroxide solution located in front of the absorber with a hydrochloric acid solution for monoethanolamine (a revised measurement procedure with additions set out in accordance with the requirements of the current legislation in the field of metrology and established metrological characteristics, agreed by the Chief Sanitary Doctor of Ukraine). The directions of research necessary for the development of a method for determining the content of monoethanolamine in process waters of coke-chemical production are outlined. Keywords: desulfurization, monoethanolamine, content determination, selectivity, ammonia, p-nitrophenyldiazonium, coke oven gas, complex compound, color intensity, photometry, measurements. Corresponding author A.Yu. Martynova, e-mail: [email protected]

Teknologi Esktrasi dan Cara Pemisahannya untuk Mendapatkan Kembali Karotenoid dari Minyak Sawit : Suatu Tinjauan

2016 ◽  
Vol 9 (1) ◽  
pp. 80-95
Author(s):  
Agus Sudibyo ◽  
Sardjono Sardjono
Keyword(s):  
Vitamin A ◽  
Palm Oil ◽  
Beta Carotene ◽  
Cost Effective ◽  
Raw Material ◽  
Extraction And Separation ◽  
Molecular Product ◽  
Industrial Use ◽  
Palm Oil Mill ◽  
Selection Of

Crude palm oil (CPO)is the richest natural plant source of carotenoids in terms of retinol (pro-vitamin A) equivalent, whereas palm oil mill effluent (POME) is generated from palm oil industry that contains oil and carotenes that used to be treated before discharge. Carotenoids are importance in animals and humans for the purpose of the enhancement of immune response, conversion of vitamin A and scavenging of oxygen radicals. This component has different nutritional  functions and benefits to humaan health. The growing interest in the other natural sources of beta-carotene and growing awareness to prevent pollution has stimulated the industrial use of CPO and POME as a raw material for carotenoids extraction. Various technologies of extraction and separation have been developed in order to recover of carotenoids.This article reports on various technologies that have been developed in order to recover of carotenoids from being destroyed in commercial refining of palm oil and effects of some various treatments on the extraction end separation for carotenoid from palm oil and carotenoids concentration. Principally, there are different technologies, and there is one some future which is the use of solvent. Solvent plays important role  in the most technologiest, however the problem of solvents which are used is that they posses potentiaal fire health and environmental hazards. Hence selection of the  most safe, environmentally friendly and cost effective solvent is important to design of alternative extraction methods.Chemical molecular product design is one of the methods that are becoming more popular nowadays for finding solvent with the desired properties prior to experimental testing.ABSTRAKMinyak sawit kasar merupakan sumber karotenoid terkaya yang berasal dari tanaman sawit sebagai senyawa yang sama dengan retinol atau pro-vitamin A; sedangkan limbah pengolahan minyak sawit dihasilkan dari industri pengolahan minyak sawit yang berisi minyak dan karotene yang perlu diberi perlakuan terlebih dahulu sebelum dibuang. Karotenoid merupakan bahan penting yang diperlukan pada hewan dan manusia guna memperkuat tanggapan terhadap kekebalan, konversi ke vitamin A dan penangkapan gugus oksigen radikal. Dengan berkembangnya ketertarikan dalam mencari beta-karotene yang bersumber dari alam lain dan meningkatnya kesadaran untuk mencegah adanya pencemaran lingkungan, maka mendorong suatu industri untuk menggunakan CPO dan POME sebagai bahan baku untuk diekstrak karotenoidnya. Berbagai macam teknologi guna mengekstrak dan memisahkan karotenoid telah dikembangkan untuk mendapatkan kembali karotenoidnya. Makalah ini melaporkan dan membahas berbagai jenis teknologi yang telah dikembangkan guna mendapatkan kembali senyawa karotenoid dari kerusakan di dalam proses pemurnian minyak sawit secara komersial dan pengaruh beberapa perlakuan terhadap ekstrasi dan pemisahan karotenoid dari minyak sawit dan konsentrasi karotenoidnya. Pada prinsipnya, berbagai teknologi yang digunakan untuk mengekstrak dan memisahkan karotenoid terdapat perbedaan, dan terdapat salah satu teknologi yang digunakan untuk esktrasi dan pemisahan karotenoid adalah menggunakan bahan pelarut. Pelarut yang digunakan mempunyai peranan yang penting dalam teknologi ekstrasi; namun pelarut yang digunakan untuk mengekstrak tersebut mempunyai persoalan karena berpotensi mengganggu kesehatan dan membahayakan cemaran lingkungan. Oleh karena itu, pemilihan jenis teknologi yang aman, ramah terhadap lingkungan dan biaya yang efektif untuk penggunaan pelarut merupakan hal penting sebelum dilakukan desain metode/teknologi alternatif untuk esktrasi karotenoid. Pola produk molekuler kimia merupakan salah satu metode yang saat ini menjadi lebih populer untuk mencari pelarut dengan sifat-sifat yang dikehendaki sebelum diujicobakan. Kata kunci :    karotenoid, ekstrasi, pemisahan, teknologi, minyak sawit kasar, limbah industri pengolahan sawit.

The interasin raw material base of coke-chemical production of Ukraine: Problems of charge formation, its preparation and coking

2018 ◽  
Vol 5 (6) ◽  
pp. 3-7 ◽  
Author(s):  
E.S. Popov ◽  
V.I. Gavrilyuk ◽  
N.V. Mukina ◽  
E.T. Kovalev ◽  
I.D. Drozdnik ◽  
...  
Keyword(s):  
Raw Material ◽  
Material Base ◽  
Chemical Production ◽  
Charge Formation
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