scholarly journals Biochemical approach to assess groundwater pollution by heavy metals pollutants and organics (case Reghaia Lake, Algeria)

2020 ◽  
Author(s):  
Boussaid Khadidja ◽  
Chebouti–Meziou Nadjiba

The article deals with the determination of the factors responsible for the degradation of the Reghaia nature reserve. The objective of this research was to evaluate the spatial variation of chemical pollutants including the accumulation of some heavy metals (Iron, Zinc, Copper, Cobalt, Cadmium, Silver, Nickel and Lead) in the water of Lake Reghaia, Algiers. The study was carried out on 64 water samples taken from Reghaia Lake. For physico-chemical parameters and for MTEs that have been assayed by atomic absorption spectrophotometry. On the chemical level, high levels of nitrates have been recorded in water between 4mg / l, 30mg / l and concerning the phosphate, it has a high content (5.7 mg / l). Surface waters have high levels of suspended solids. BOD5 and COD are high, with COD / DBO5 ratios well above 3, dissolved oxygen values do not comply with WHO standards with P = 0.000001. Water degradation is caused by the presence of latrines, piles of garbage, farms, draining of sanitation facilities in nature and especially in watercourses. Heavy metal pollution is significant and has been reported for Plomp (Pb), copper (Cu), iron (Fe) and cobalt (Co), which reached the high risk level (p <0.01) especially upstream of the Reghaia Lake. And that the MTE contents vary irregularly from one station to another and from one depth to another. The results reveal that the waters of the Réghaia Lake are of very poor quality and the degradation of the ecosystem is more and more increased, to this effect a treatment is recommended.

2013 ◽  
Vol 39 (2) ◽  
pp. 3-16 ◽  
Author(s):  
Aleksandra Ibragimow ◽  
Barbara Walna ◽  
Marcin Siepak

Abstract The occurrence of heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) has been determined in the fluvial sediment samples collected along three transects in the Middle Odra River (western Poland) with a width of 360 m. The total concentrations of the metals were obtained after HNO3 microwave digestion and the available fractions of heavy metals were determined by single extraction procedures using two extractants: 0.01M CaCl2 and 0.05M EDTA. The measurement of physico-chemical parameters was also performed. The determination of total and available fractions of heavy metals, except potential available fractions of Cr, revealed high concentrations of studied elements detected in the sediment samples characterized by high content of coarse and very coarse-grained sand fraction and high content of organic matter. It was found that the concentrations of total and available fractions of metals could increase along with the content of organic matter, Eh values and concentrations of H+. Apart from the above, those concentrations become the lowest, the higher the content of medium grain size fractions is. Furthermore, the amounts of CaCl2 and EDTA extractable metals increase in the sediments samples characterized by the lowest total and available concentrations of heavy metals.


2011 ◽  
Vol 17 (1) ◽  
pp. 107-115 ◽  
Author(s):  
Nada Babovic ◽  
Dejan Markovic ◽  
Vojkan Dimitrijevic ◽  
Dragan Markovic

This paper shows the results obtained in field analysis performed at the Tamis River, starting from the settlement Jasa Tomic - border between Serbia and Romania to Pancevo - confluence of Tamis into the Danube. The Tamis is a 359 km long river rising in the southern Carpathian Mountains. It flows through the Banat region and flows into the Danube near Pancevo. During the years the water quality of the river has severely deteriorated and badly affected the environment and the river ecosystem. In situ measurements enabled determination of physico-chemical parameters of water quality of the Tamis River on every 400 m of the watercourse, such as: water temperature, pH value, electrical conductivity, contents of dissolved oxygen and oxygen saturation. The main reason of higher pollution of Tamis is seen in connection to DTD hydro system. Sampling was performed at 7 points with regard to color, turbidity, total hardness, alkalinity, concentration of ammonium nitrogen, nitrite nitrogen, nitrate nitrogen, iron, chlorides and sulphates in samples. The aim of the present work was to evaluate water quality in the Tamis River taking into account significant pollution, which originates from settlements, industry and agriculture, and to suggest appropriate preventive measures to further pollution decreasing of the river's water.


2020 ◽  
Vol 65 (2) ◽  
pp. 17-37
Author(s):  
Georgiana Grosu ◽  
◽  
Carmen Andreea Roba ◽  
Ramona Bălc ◽  
Maria Lucia Bizău-Cârstea ◽  
...  

The present study was conducted in the proximity of a contaminated site from Cluj-Napoca city (Cluj County, Romania), where metal processing activities have been carried out for decades. Metal content and physico-chemical parameters were analyzed in soil, water and sediment samples, while organic matter (OM) and total organic carbon (TOC) was additionally analyzed for the soil samples. The sources of heavy metals were evaluated based on multivariate statistical analysis, while the soil and sediment contamination degree was assessed based on specific pollution indices. The calculated indices indicated a significant pollution with Cd and Pb, which may represent a risk if the area would become a residential area. Keywords: heavy metals, contaminated site, soil pollution indices, multivariate statistical analysis, Cluj-Napoca


2018 ◽  
Vol 13 (3) ◽  
pp. 612-620
Author(s):  
Filipe Sousa dos Santos ◽  
Eduarda Medran Rangel ◽  
Pedro José Sanches Filho

Abstract Determination of trace metals was carried out in Mangueira Lagoon, in the southern zone of Rio Grande do Sul. Samples were collected at five points to evaluate the concentrations of the following trace metals: copper, zinc, lead, chromium, nickel and iron. Metals were determined by digestion with concentrated nitric acid and pre-concentrated in Chelex 100 resin analyzed by atomic absorption spectrophotometry. In parallel, the physical-chemical parameters pH, chlorides, alkalinity, hardness and organic matter in the water were determined. Potassium and sodium metals were analyzed by atomic emission spectrometry. The analyzes of pH and conductance were analyzed in the field while the others were done in the laboratory of the research group of environmental contaminants (GPCA). Through the results of physical-chemical parameters of the water, the Mangueira Lagoon exhibits a low degree of contamination, but in the future may compromise the biota of the lagoon. Regarding the focus of this work, of Cu, Cr, Fe, Ni, Pb, and Zn (heavy metals), only lead and iron obtained the values above that are established in CONAMA 357/2005.


2015 ◽  
Vol 75 (1) ◽  
Author(s):  
S. Y. Chung ◽  
S. Venkatramanan ◽  
N. Park ◽  
T. Ramkumar ◽  
S. B. Sujitha ◽  
...  

2012 ◽  
Vol 66 (1) ◽  
pp. 105-112 ◽  
Author(s):  
Ayodele Rotimi Ipeaiyeda ◽  
Adekunle Johnson Odola

A co-precipitation technique for nickel(II), chromium(II), manganese(II), lead(II) and zinc(II) with the aid of copper(II) cyclo-hexylmethyldithiocarbamate was established. The influences of some analytical parameters such as pH, sample volume, amounts of cyclo-hexylmethyldithiocarbamate and copper(II) on the recovery of metal ions were investigated. The heavy metals in the precipitate were determined by flame atomic absorption spectrophotometry. The range of detection limits for the heavy metals was 0.003–0.005 mg/L. The atomic spectrometric technique with co-precipitation procedure was successfully applied for the determination of Ni, Cr, Mn, Pb and Zn in industrial wastewater and sediment samples from Ladipo stream in Lagos, Nigeria. The mean concentrations for these metals using co-precipitation procedure were not significantly different from corresponding concentrations obtained using spectrometric techniques without co-precipitation procedure.


2015 ◽  
Vol 13 (4) ◽  
pp. 1073-1084 ◽  
Author(s):  
Nida Gul ◽  
Mohammad Tahir Shah ◽  
Sardar Khan ◽  
Nimat Ullah Khattak ◽  
Said Muhammad

The present study was conducted to investigate the physico-chemical characteristics in drinking water of Mardan District, Pakistan. Furthermore, water quality was evaluated for the risk assessment of arsenic and heavy metals (HMs) and their contamination sources. Representative groundwater samples of shallow and deep sources were collected in the study area. These samples were analyzed for physical parameters, anions, light metals (LMs) and HMs. Results were compared with the drinking water guideline values set by the World Health Organization and the US Environmental Protection Agency. Average concentrations of anions, LMs and HMs were found within the maximum allowable contaminant levels except for bicarbonates, Fe, Cu, and Pb. Results revealed that hazard quotients &gt;1 were observed for shallow groundwater for 10% samples only, suggesting potential health risk from water consumption. Correlation analysis and principal component analysis showed a relationship among various physico-chemical parameters in both shallow and deep groundwater. Statistical analyses suggested the geogenic and anthropogenic sources for possible enhancement of various physico-chemical parameters in the aquifer system of the study area.


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