Fluid behavior in many geological problems is strongly influenced by extant thermal conditions and flow of heat. Recall, for example, that the coefficient A in Glen’s law for ice (3.40) varies over three orders of magnitude with a change in temperature of 50 °C. The effect of this is to strongly modulate the rate of ice deformation for a given level of stress. Recall further that we introduced several fluid properties—fluid compressibility, for example—where we asserted that our purely mechanical developments were incomplete inasmuch as they did not treat effects of varying temperature. The reasons for this will become clear in this chapter, including why it is difficult to maintain isothermal conditions when the pressure of a fluid is changing. In addition, many geological problems involve fluid flows that are induced by effects of variations in thermal conditions over time and space. These include buoyancy-driven convective motions that arise from variations in fluid density associated with variations in temperature (Chapter 16). Specific examples include convective overturning in a magma chamber, which can significantly influence how crystallizing minerals are distributed; convective circulations of water and chemical solutions in a sedimentary basin, which can influence where rock materials are dissolved and where they are precipitated as cements within pores; and convective circulation of water within the active layer above seasonally frozen ground, which may influence where patterned ground develops in periglacial environments. These processes, and viscous flows in general, invariably involve conversions of mechanical energy to heat, or vice versa. So in considering problems involving heat energy, we should recall from introductory chemistry and physics that such conversions can involve work performed on the fluid or its surroundings, and anticipate that the effects of this ought be manifest in fluid behavior. This chapter, then, is concerned with fluid pressure, temperature, and density, and how these variables are related to heat, mechanical energy, and work. We will note in digressions how these macroscopic concepts, like fluid viscosity, often have clear interpretations at a molecular scale based on kinetic theory of matter.