scholarly journals Synthesis and applications of carbon nanomaterials for energy generation and storage

2016 ◽  
Vol 7 ◽  
pp. 149-196 ◽  
Author(s):  
Marco Notarianni ◽  
Jinzhang Liu ◽  
Kristy Vernon ◽  
Nunzio Motta

The world is facing an energy crisis due to exponential population growth and limited availability of fossil fuels. Over the last 20 years, carbon, one of the most abundant materials found on earth, and its allotrope forms such as fullerenes, carbon nanotubes and graphene have been proposed as sources of energy generation and storage because of their extraordinary properties and ease of production. Various approaches for the synthesis and incorporation of carbon nanomaterials in organic photovoltaics and supercapacitors have been reviewed and discussed in this work, highlighting their benefits as compared to other materials commonly used in these devices. The use of fullerenes, carbon nanotubes and graphene in organic photovoltaics and supercapacitors is described in detail, explaining how their remarkable properties can enhance the efficiency of solar cells and energy storage in supercapacitors. Fullerenes, carbon nanotubes and graphene have all been included in solar cells with interesting results, although a number of problems are still to be overcome in order to achieve high efficiency and stability. However, the flexibility and the low cost of these materials provide the opportunity for many applications such as wearable and disposable electronics or mobile charging. The application of carbon nanotubes and graphene to supercapacitors is also discussed and reviewed in this work. Carbon nanotubes, in combination with graphene, can create a more porous film with extraordinary capacitive performance, paving the way to many practical applications from mobile phones to electric cars. In conclusion, we show that carbon nanomaterials, developed by inexpensive synthesis and process methods such as printing and roll-to-roll techniques, are ideal for the development of flexible devices for energy generation and storage – the key to the portable electronics of the future.

2012 ◽  
Vol 2012 ◽  
pp. 1-21 ◽  
Author(s):  
Yuancheng Qin ◽  
Qiang Peng

Dye-sensitized solar cells (DSSCs) have attracted considerable attention in recent years due to the possibility of low-cost conversion of photovoltaic energy. The DSSCs-based ruthenium complexes as sensitizers show high efficiency and excellent stability, implying potential practical applications. This review focuses on recent advances in design and preparation of efficient ruthenium sensitizers and their applications in DSSCs, including thiocyanate ruthenium sensitizers and thiocyanate-free ruthenium sensitizers.


2021 ◽  
Vol 13 (15) ◽  
pp. 8421
Author(s):  
Yuan Gao ◽  
Jiandong Huang ◽  
Meng Li ◽  
Zhongran Dai ◽  
Rongli Jiang ◽  
...  

Uranium mining waste causes serious radiation-related health and environmental problems. This has encouraged efforts toward U(VI) removal with low cost and high efficiency. Typical uranium adsorbents, such as polymers, geopolymers, zeolites, and MOFs, and their associated high costs limit their practical applications. In this regard, this work found that the natural combusted coal gangue (CCG) could be a potential precursor of cheap sorbents to eliminate U(VI). The removal efficiency was modulated by chemical activation under acid and alkaline conditions, obtaining HCG (CCG activated with HCl) and KCG (CCG activated with KOH), respectively. The detailed structural analysis uncovered that those natural mineral substances, including quartz and kaolinite, were the main components in CCG and HCG. One of the key findings was that kalsilite formed in KCG under a mild synthetic condition can conspicuous enhance the affinity towards U(VI). The best equilibrium adsorption capacity with KCG was observed to be 140 mg/g under pH 6 within 120 min, following a pseudo-second-order kinetic model. To understand the improved adsorption performance, an adsorption mechanism was proposed by evaluating the pH of uranyl solutions, adsorbent dosage, as well as contact time. Combining with the structural analysis, this revealed that the uranyl adsorption process was mainly governed by chemisorption. This study gave rise to a utilization approach for CCG to obtain cost-effective adsorbents and paved a novel way towards eliminating uranium by a waste control by waste strategy.


2021 ◽  
Vol 33 (18) ◽  
pp. 2170142
Author(s):  
Ming Zhang ◽  
Lei Zhu ◽  
Tianyu Hao ◽  
Guanqing Zhou ◽  
Chaoqun Qiu ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-1 ◽  
Author(s):  
J. Yi ◽  
Eicke R. Weber ◽  
C. W. Lan ◽  
Stephen Bremner ◽  
D. H. Kim
Keyword(s):  

Author(s):  
Li Zhang ◽  
Hui Li ◽  
Jing Zhuang ◽  
Yigang Luan ◽  
Sixuan Wu ◽  
...  

The low-cost material antimony trifluoride (SbF3) was doped into the commonly used tin dioxide (SnO2) for the first time, and the SbF3-doped SnO2 as an electron transport layer (ETL) was...


Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 964 ◽  
Author(s):  
Yue Zhang ◽  
Haiming Zhang ◽  
Xiaohui Zhang ◽  
Lijuan Wei ◽  
Biao Zhang ◽  
...  

Organic–inorganic hybrid perovskite solar cells (PSCs) have made immense progress in recent years, owing to outstanding optoelectronic properties of perovskite materials, such as high extinction coefficient, carrier mobility, and low exciton binding energy. Since the first appearance in 2009, the efficiency of PSCs has reached 23.3%. This has made them the most promising rival to silicon-based solar cells. However, there are still several issues to resolve to promote PSCs’ outdoor applications. In this review, three crucial aspects of PSCs, including high efficiency, environmental stability, and low-cost of PSCs, are described in detail. Recent in-depth studies on different aspects are also discussed for better understanding of these issues and possible solutions.


2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Guiming Peng ◽  
Xueqing Xu ◽  
Gang Xu

The ramping solar energy to electricity conversion efficiencies of hybrid organic-inorganic perovskite solar cells during the last five years have opened new doors to low-cost solar energy. The record power conversion efficiency has climbed to 19.3% in August 2014 and then jumped to 20.1% in November. In this review, the main achievements for perovskite solar cells categorized from a viewpoint of device structure are overviewed. The challenges and prospects for future development of this field are also briefly presented.


Author(s):  
Duc

Perovskites are increasingly proved to be a promising candidate for making absorber materials for high-efficiency and low-cost next-generation solar cells. There are several models proposed for perovskite solar cells similar to the conventional solar cells; their operation also has specific characteristics and requires the development of a more general physical model to study, thus optimizing the cells and improving the performance of the panels. This paper develops such a physics-based intuitive model to consider the performance of two high-efficiency types of perovskite solar cells, taking into account heterogeneous properties, with filtered transport layers, recombination, charge selection, and voltage-dependent collector. This model would allow experimentally to estimate critical parameters of perovskite solar cells, understand the performance bottleneck, and predict the performance of perovskite solar cells and suggest further study for perovskite solar cell technology development.   


Author(s):  
Salah Obayya ◽  
Nihal Fayez Fahmy Areed ◽  
Mohamed Farhat O. Hameed ◽  
Mohamed Hussein Abdelrazik

The solar energy is able to supply humanity energy for almost another 1 billion years. Optical nano-antennas (ONAs) are an attractive technology for high efficiency, and low-cost solar cells. These devices can be classified to semiconductor nano-wires and metallic nano-antenna. Extensive studies have been carried out on ONAs to investigate their ability to harvest solar energy. Inspired by these studies, the scope of the chapter is to highlight the latest designs of the two main types of ONAs. The metallic nano-antennas are discussed based on the following points: plasmon, modeling, and performance of antenna designs using different configurations and materials. Moreover, the semiconductor nano-wires are studied thoroughly in terms of photonic crystals, antenna design with different patterns, nano-wire forms and materials. Also, the applications of ONAs and their fabrication aspects such as diode challenges are presented in detail. Finally, three novel designs of ONAs are presented and numerically simulated to maximize the harvesting efficiency.


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