Research on Nitrogen Removal Performance of Leachate Treatment of WSIP Reactor

2011 ◽  
Vol 55-57 ◽  
pp. 789-795
Author(s):  
Xiu Ju Duan ◽  
Qiang He ◽  
Ya Li Liu

This thesis put forward the treatment concept of “without Biomass Retention Sequential Batch Intensified Pretreatment (WSIP)” in leachate treatment, for sake of improving performance of nitrogen removal, optimizing excess water’s nutritional ratio and benefitting the follow-up aerobic biological treatment. Based on orthogonal experiment of WSIP Reactor’s leachate treatment performance, Conclusions can be drew: the removal performance of ammonia nitrogen and TN is higher of WSIP, in which short-cut nitrification and denitrification can be realized; HRT, DO and sequential period are remarkable factors of ammonia removal performance, TN removal performance and realization of short-cut nitrification and denitrification; In normal temperature, the most perfect functional parameter of WSIP Reactor is: HRT=4d, DO=0.75mg/L and sequential period is 6h.

2013 ◽  
Vol 448-453 ◽  
pp. 536-539
Author(s):  
Bin Liu ◽  
Xu Ya Peng ◽  
Qi Tian ◽  
Hua Zhao

Landfill leachate treatment is a major problem to be solved in the field of environmental protection, and ammonia nitrogen is one of the major pollutants in landfill leachate, whose processing technology needs further improvement. In this paper, ultrasound/ultraviolet co-oxidation technology was directly applied to the treatment of high concentration landfill leachate without the pretreatment operations of dilution, filter, and adjusting the pH conditions. The results showed that: ultrasonic and ultraviolet had certain effects on the ammonia nitrogen removal, and the ammonia nitrogen removing effects became better when the ultrasonic power was greater, or the ultraviolet wavelength was shorter. When the ultrasonic power was 100 W, the ammonia nitrogen removal efficiency was 25.2%, and the UV of 254 nm could decompose 20.2% of the ammonia nitrogen in landfill leathate. In the condition of aeration, ultrasonic and ultraviolet had good synergistic effect on leachate ammonia nitrogen treatment. When the ultrasonic power was 100 W, UV wavelength was 254 nm, and the aeration rate was 150 L/h, the ammonia removal efficiency of high concentration leachate (ammonia nitrogen concentration of 1800 mg/L) reached 98.5% after 6 hours. The paper's research results provide a useful reference for the removal of landfill leachate ammonia nitrogen.


1994 ◽  
Vol 29 (10-11) ◽  
pp. 409-416 ◽  
Author(s):  
F. Çeçen ◽  
I. E. Gönenç

The kinetics of nitrogen removal was studied in upflow submerged nitrification and denitrification filters in series. Nitrification followed first-, half-, and zero-order kinetics. For the half-order range the half-order rate constant was about 0.9gNH4-N1/2m−1/2d−1. The zero-order rate constants for the DO ranges of 2-3 mg/L and 4-5 mg/L were found as 0.47 gNH4-Nm−2d−1 and 1.82 gNH4-Nm−2d−1, respectively. In the zero-order region ammonia removal proceeded as a half-order reaction in oxygen concentration and the half-order rate constants were about 1.4-2.7 gO21/2m−1/2d−1. Nitrite accumulation reached a considerable degree at bulk oxygen to bulk ammonia ratios lower than 5 since the formation of nitrate was inhibited. Similar to nitrification half- and zero-order kinetic regions were also observed in denitrification. The half- and zero-order rate constants for carbon unlimited cases (influent COD/NOx-N>5) were about 0.23 gNOx-N1/2m−1/2d−1 and 1.9 gNOx-Nm−2d−1, respectively. The nitrite produced in the nitrification stage could be reduced in denitrification. The removal kinetics in the presence of nitrite was found to be similar to the kinetics when the influent consisted of nitrate only.


2015 ◽  
Vol 26 (3) ◽  
pp. 49-53 ◽  
Author(s):  
Anna Kwarciak-Kozłowska ◽  
Aleksandra Krzywicka

Abstract The goal of this article was to compare the efficiency of Fenton and photo-Fenton reaction used for stabilised landfill leachate treatment. The mass ratio of COD:H2O2 was fixed to 1:2 for every stages. The dose of reagents (ferrous sulphate/hydrogen peroxide) was different and ranged from 0.1 to 0.5. To determine the efficiency of treatment, the BOD (biochemical oxygen demand COD (chemical oxygen demand), TOC (total organic carbon) , ammonia nitrogen and BOD/COD ratio was measured. The experiment was carried out under the following conditions: temperature was 25ºC, the initial pH was adjusted to 3.0. Every processes were lasting 60 minutes. The most appropriate dose of reagents was 0.25 (Fe2+/H2O2). It was found that the application of UV contributed to increase of COD, TOC and ammonia removal efficiencies by an average of 14%.


1994 ◽  
Vol 29 (10-11) ◽  
pp. 431-438 ◽  
Author(s):  
Y. Watanabe ◽  
D. Y. Bang ◽  
K. Itoh ◽  
K. Matsui

This paper concerns simultaneous nitrification and denitrification in a completely mixed bio-reactor with partially and fully submerged rotating biological contactors. The bio-reactor is designed to cause the nitrification and denitrification in partially and fully submerged biofilms, respectively. An experimental investigation was made into the effect of organic material and ratio of influent organic carbon to ammonia nitrogen concentrations(C/N ratio) on the efficiency of simultaneous nitrification and denitrification in the bio-reactor. Settled municipal wastewater and synthetic wastewater containing ammonia nitrogen and organic material such as acetate, ethylene-glycol, phenol and poly-vinyl-alcohol(PVA) were fed into the experimental units. A biofilm dominated by nitrifiers developed on the partially submerged contactors, while a biofilm dominated by heterotrophs developed on the fully submerged contactors. A micro-aerobic environment was formed and biological denitrification occurred in the submerged biofilm. In the municipal wastewater treatment where the influent C/N ratio was around 3.5, the maximum nitrogen removal efficiency was about 60 %. Acetate and ethlene-glycol were effectively used as the organic source of the denitrification. The ability to aerobically degrade PVA was induced by phenol. Once the bacteria inhibiting the biofilm gained the ability to degrade PVA, PVA became an effective organic source of the denitrification.


2007 ◽  
Vol 55 (7) ◽  
pp. 245-254 ◽  
Author(s):  
A. Valdivia ◽  
S. González-Martínez ◽  
P.A. Wilderer

In order to compare the performance of biofilms growing on different support media, three reactors were fed with municipal wastewater from the city of Garching, Germany, and operated under the sequencing batch procedure. The support media tested have the commercial names of Kaldnes, polyethylene special support for moving bed reactors with approximate diameter of 12 mm; Liapor, ceramic spheres with diameters between 4 and 6 mm; Linpor, plastic foam cut in cubes of 15 mm. The bench-top reactors were tested for COD, TSS and ammonia nitrogen removal. During 452 days runs with organic loads between 0.5 and 8.0 gCOD/m2·d were tested. Thin biofilms (Kaldnes and Liapor) perform better for COD and ammonia removal under lower organic loading values (<2.5 gCOD/m2·d). For organic loads over 3.0 gCOD/m2·d, the reactor packed with Linpor (thick biofilm) showed a better COD and ammonia nitrogen removal than the other two. Linpor achieved the highest NOx-N production reaching values between 15 and 20 mg/l. For low organic loading rates Linpor and Liapor present similar average NOx-N concentrations. Kaldnes shows the lowest concentrations throughout the whole experimental period. The difference between ammonia nitrogen removal and NOx-N generation is simultaneous denitrification inside the deep biofilms. The average mean cellular retention times were 5.4 days for Liapor, 10.0 days for Kaldnes and 22.9 days for Linpor. This is the reason why Linpor achieved complete nitrification even with higher organic loads.


1998 ◽  
Vol 25 (5) ◽  
pp. 854-863 ◽  
Author(s):  
D M Shiskowski ◽  
D S Mavinic

This bench-scale study investigated the nitrogen-removal capabilities of two different biological process configurations treating methanogenic-state landfill leachate containing up to 1200 mg N/L of ammonia. The first configuration was a pre-denitrification system known as the modified Ludzack-Ettinger (MLE) process. Large clarifier sludge recycle flows, set to yield clarifier recycle ratios of 7:1 and 8:1, were evaluated as a means to reduce effluent NOx concentrations. A pre- and post-denitrification system, known as the four-stage Bardenpho process, was the second configuration evaluated. The MLE systems (20 day aerobic solids retention time (SRT)) were capable of producing effluent containing about 50 mg N/L of ammonia and 200-235 mg N/L of total inorganic nitrogen (ammonia + NOx) when treating leachate containing approximately 1200 mg N/L of ammonia. In contrast, effluent from the four-stage Bardenpho system contained less than 1 mg N/L of ammonia and 15 mg N/L of NOx, when treating 1100 mg N/L ammonia leachate. An aerobic number 1 SRT of 20 days (total aerobic SRT approximately equal to 40 days) was used with aerobic number 1 and clarifier sludge recycle ratios of 4:1 and 3:1, respectively. The ammonia-removal potential of both systems was clearly demonstrated but each system also showed certain disadvantages, characteristic of each process.Key words: ammonia-N, anoxic denitrification, leachate treatment, nitrification, pre-denitrification.


1995 ◽  
Vol 22 (5) ◽  
pp. 992-1000 ◽  
Author(s):  
J. Paul Henderson ◽  
James W. Atwater

A pre-denitrifying anaerobic filter and a rotating biological contactor (RBC) were used to remove nitrogen from a high ammonia landfill leachate collected from a municipal and industrial solid waste landfill in Kaohsiung, Taiwan, Republic of China. The research indicated that greater than 95% ammonia removal from high ammonia-N (2140 mg/L) leachate can be achieved with RBC ammonia-N loading rates up to 1.5 g/(m2∙d). At RBC loading rates of 1.5–3.0 g/(m2∙d), ammonia removal ranged from 80% to 90%. Nitrogen removal averaged 66%, including an estimated 54% removal in the RBC. Nitrogen removal in the RBC was the result of either simultaneous nitrification and denitrification or air stripping of ammonia in combination with nitrification. Both alkalinity consumption and COD removal results support the explanation of simultaneous nitrification and denitrification (potentially aerobic denitrification); but since RBC off-gasses were not monitored, neither theory can be confirmed. The high nitrogen removal in the RBC suggests that for this leachate the anaerobic filter was not required for ammonia and nitrogen removal. BOD and COD removal averaged 92% and 49% respectively. Key words: landfill, leachate, treatment, ammonia, rotating biological contactor (RBC), nitrification, denitrification.


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