Phytic Acid Sepiolite Compound Adsorbent on the Adsorption of Cd2+ Performance Research of Heavy Metals

2014 ◽  
Vol 707 ◽  
pp. 199-201
Author(s):  
Jiao Sheng ◽  
Shu Mei Yan ◽  
Xian Feng ◽  
Gui Hua Zeng

This paper studies the preparation of phytic acid with sepiolite compound phytic acid compound sepiolite adsorbent of heavy metals adsorption performance is good, and the adsorption of the optimum adsorption conditions was studied, the optimum adsorption conditions for adsorbent dosage 30 g/L, temperature 40°C, pH = 3, the adsorption equilibrium time 30 min, Cd6+, concentration is lower than 50 mg/L.

2014 ◽  
Vol 707 ◽  
pp. 195-198
Author(s):  
Jiao Sheng ◽  
Shu Mei Yan ◽  
Xian Feng ◽  
Ai Cui He ◽  
Gui Hua Zeng

The modified clay have excellent adsorption performance. This paper discussed the adsorbent dosage, pH, temperature, adsorption equilibrium time and so on the influence of factors on the adsorbent adsorption performance, the results show that the microbial fermentation of rice bran to Cd2+ has good adsorption effect. The best adsorption conditions for: dosage of microbial fermentation of rice bran 18 g/L, temperature 30 °C, pH = 3.8, Cd2 + mass concentration is lower than 50 mg/L, the adsorption equilibrium time 30 min, adsorption rate can reach 93.5%, and its application foreground is prospected in wastewater treatment.


2013 ◽  
Vol 2 (3) ◽  
pp. 29-32
Author(s):  
Krisnawati ◽  
Jasinda ◽  
Iriany

Harzadous waste water is the waste that can be harmful to human’s health. One of heavy metals that contains in harzadous waste is cadmium. This research aims to investigate the characteristic of cadmium adsorption, equilibrium time, percentage adsorption, adsorption kinetic, adsorption isotherm and capacity of cadmium adsorption by using duck egg’s shell adsorbent. Duck egg’s shell adsorbent that had been activated at 600 oC were put into cadmium solution and mixed together. Every 10 minutes experimental samples were analyzed using AAS. The results indicated that percentage adsorption increases and the longer equilibrium time will be reached with an increase of adsorbent dosage. The Lagergen first order Models was applied as adsorption kinetics model and the Bangham Models was applied as adsorption isotherms models.


2013 ◽  
Vol 726-731 ◽  
pp. 2585-2588
Author(s):  
Xiu Yan Zhou ◽  
Xiang Xin Xue

In this study, the sorption of heavy metals (Cu2+, Pb2+, Zn2+ and Cd2+) from simulated metallurgical wastewater by sepiolite under different dosage, pH, adsorption time and temperature conditions was investigated. The results showed that adsorption increased with the increase of adsorbent dosage until the adsorption equilibrium was reached. When the pH is 6, adsorption of heavy metal ions by sepiolite was in the order of Cu2+ > Zn2+ > Pb2+ > Cd2+ and removal rates of the metal ion were 91%, 90%, 91%, 84%, respectively. The effect of adsorption time on adsorption was not significant. At room temperature, with the adsorption time 45 min, the adsorption of metal ions is almost saturated, adsorption of Cu2+, Pb2+, Cd2+ and Zn2+ was 13.05mg/g, 85.47mg/g, 62.36mg/g and 15.67mg/g, respectively.


1999 ◽  
Vol 40 (7) ◽  
pp. 109-116 ◽  
Author(s):  
M. H. Ansari ◽  
A. M. Deshkar ◽  
P. S. Kelkar ◽  
D. M. Dharmadhikari ◽  
M. Z. Hasan ◽  
...  

Steamed Hoof Powder (SHP), size < 53μ, was observed to have high adsorption capacity for Hg(II) with >95% removal from a solution containing 100 mg/L of Hg(II) with only 0.1% (W/V) concentration of SHP. The SHP has good settling properties and gives clear and odour free effluent. Studies indicate that pH values between 2 and 10 have no effect on the adsorption of Hg(II) on SHP. Light metal ions like Na+, K+, Ca2+ and Mg2+ up to concentrations of 500 mg/L and heavy metals like Cu2+, Zn2+, Cd2+, Co2+, Pb2+, Ni2+, Mn2+, Cr3+, Cr6+, Fe2+ and Fe3+ up to concentrations of 100 mg/L do not interfere with the adsorption process. Anions like sulphate, acetate and phosphate up to concentrations of 200 mg/L do not interfere. Chloride interferes in the adsorption process when Hg(II) concentration is above 9.7 mg/L. The adsorption equilibrium was established within two hours. Studies indicate that adsorption occurs on the surface sites of the adsorbent.


2015 ◽  
Vol 2 (2) ◽  
Author(s):  
Wahyu Wilopo ◽  
Septiawan Nur Haryono ◽  
Doni Prakasa Eka Putra ◽  
I Wayan Warmada ◽  
Tsuyoshi Hirajima

Development of indusrialization and urbanization not only increase economic growth but also contribute to the environmental degradation, especially contamination of heavy metals in water. In other side, there are many geological materials have capability to immobilize heavy metals. Therefore, the objective of this research is to know the maximum capacity of natural zeolite from Trembono area, Gunung Kidul regency to immobilize copper (Cu2+) from water and to understand their mechanism. This experiment was carry out by a batch test. The result showed that the maximum capacity of zeolite to immobilize Cu (qmax) is 63,69 mmolCu/kg Zeolite according to Langmuir adsorption equilibrium model. In addition, the capability to immobilize Cu will increases due to decreasing the grain size. The result of this research can be used as an alternative for waste water treatment, especially Cu. Keywords: Removal, copper (Cu2+), natural zeolite, Langmuir isotherm


2019 ◽  
Vol 342 ◽  
pp. 181-192 ◽  
Author(s):  
Shengjie Sun ◽  
Jianyu Zhu ◽  
Zhihe Zheng ◽  
Jiayu Li ◽  
Min Gan

2021 ◽  
Author(s):  
Abdulkareem AS ◽  
Hamzat WA ◽  
Tijani JO ◽  
Bankole MT ◽  
Titus Egbosiuba ◽  
...  

Abstract Comparative adsorption study of some toxic metals (Ni, Fe, Cu, Cd, and Pb) from battery industrial effluent by purified and polyethylene glycol-modified carbon nanotubes (CNTs) is reported. The as-prepared CNTs via chemical vapour deposition method (A-CNTs), its acid purified form (P-CNTs), and polyethylene glycol functionalized form (PEG-CNTs) were characterized by HRTEM, BET, HRSEM, FTIR and XRD. The HRSEM and HRTEM micrograph revealed the formation of multi-walled tubular network structures of different inner and outer diameter. The BET study of PEG-CNTs and purified CNTs showed surface areas of 970.81 m2/g and 781.88 m2/g, respectively. The nanomaterials batch adsorption effect of various parameters such as contact time, nano-adsorbent dosage and temperature was conducted. The optimum equilibrium to achieve maximum removal of Cd (83.41 %), Ni (92.79 %), Fe (95.93%), Pb (97.16 %) Cu (99.9 9%) using PEG-CNTs was 90 min of contact time, 0.3 g of nano-adsorbent dosage and 60 oC temperature. While the maximum percentage removal efficiencies accomplished using P-CNTs under the same applied conditions were Cd (78.64 %), Ni (76.12 %), Fe (92.87 %), Pb (90.7 2%) Cu (99.09 %). PEG-CNTs was seen as more effective than P-CNTs. Adsorption data of Ni on P-CNTs followed Langmuir isotherm while the adsorption equilibrium model (Freundlich isotherm) of Ni, Fe, Cu and Pb on PEG-CNTs were fitted well. However, in both cases, the sorption kinetic study followed the pseudo-second-order model. The thermodynamics showed that the removal of toxic metals from battery wastewater was spontaneous and endothermic irrespective of the nano-adsorbents. The study found that surface modification of CNTs by polyethylene glycol adequately improved the nanotubes, thus leading to relatively adsorption capacities of heavy metals from industrial battery effluent.


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