High Strength Alkali Activated Slag Cements with Controlled Setting Times and Early Strength Gain

2015 ◽  
Vol 1100 ◽  
pp. 44-49 ◽  
Author(s):  
Pavel Krivenko ◽  
Oleg Petropavlovsky ◽  
Vit Petranek ◽  
Vasiliy Pushkar ◽  
Grigorii Vozniuk
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Water Glass ◽  
High Strength ◽  
Strength Gain ◽  
Setting Times ◽  
Alkaline Activator ◽  
Early Strength ◽  
Activated Slag ◽  
Alkali Activated

The paper discusses approaches to compositional build-up of high strength alkali activated cements made using water glass as alkaline activator represented by commercial products in a form of powder and liquid. The purpose was to study the influence of fineness of ground granulated blast-furnace slags, admixtures and additives, compatible with alkali activated cements, water glass and mode of manufacturing technology in order to reach high compressive strength (≥ 80 MPa at standard age (28 days)) and early strength (≥ 20 MPa after 3 h of hardening in normal conditions).

Properties of Alkli-Activated Slag Cement Compounded with Soluble Glasses with a High Silicate Modulus

2013 ◽  
Vol 712-715 ◽  
pp. 905-908
Author(s):  
Qun Pan ◽  
Bin Zhu ◽  
Xiao Huang ◽  
Lin Liu
Keyword(s):  
Compressive Strength ◽  
Cement Mortar ◽  
Strength Characteristics ◽  
Slag Cement ◽  
Alkali Activated Slag ◽  
Cement Mortars ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Alkali Activated ◽  
High Silicate

Properties of alkali-activated slag cements compounded with soluble glasse with a high silicate modulus Ms=2.6 were detailedly studied in this paper, including compressive strength and flexure strength characterictics at the ages of 3,7,28 days and flow values of fresh cement mixtures on a jolting table. As a result, with the compressive strength at the age of 28 days of 95.6-107.8 MPa has been developed, and the flow values and strength characteristics of alkali-activated slag cement mortars increased with increase in a water to cement (alkaline activator solution to slag) ratio, and the flow value (determined on the cement mortar mixtures) would reach 145 mm. Moreover, the development speed of strength characteristics of mortar specimens would be affected negatively by increasing of water demand (requirement).

scholarly journals Effect of Sodium Aluminate Dosage as a Solid Alkaline Activator on the Properties of Alkali-Activated Slag Paste

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Bin Chen ◽  
Jun Wang ◽  
Jinyou Zhao
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Setting Time ◽  
Sodium Aluminate ◽  
Hydration Reaction ◽  
Hydration Products ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Alkali Activated

Extensive research into alkali-activated slag as a green gel material to substitute for cement has been done because of the advantages of low-carbon dioxide emissions and recycling of industrial solid waste. Alkali-activated slag usually has good mechanical properties, but the too fast setting time restricted its application and promotion. Changing the composition of alkaline activator could optimize setting time, usually making it by adding sodium carbonate or sodium sulfate but this would cause insufficient hydration reaction power and hinder compressive strength growth. In this paper, the effect of sodium aluminate dosage as an alkaline activator on the setting time, fluidity, compressive strength, hydration products, and microstructures was studied through experiments. It is fair to say that an appropriate amount of sodium aluminate could obtain a suitable setting time and better compressive strength. Sodium aluminate provided enough hydroxyl ions for the paste to promote the hydration reaction process that ensured obtaining high compressive strength and soluble aluminium formed precipitate wrapped on the surface of slag to inhibit the hydration reaction process in the early phase that prolonged setting time. The hydration mechanism research found that sodium aluminate played a key role in the formation of higher cross-linked gel hydration products in the late phase of the process. Preparing an alkali-activated slag with excellent mechanical properties and suitable setting time will significantly contribute to its application and promotion.

Chemical Activation of Cementing Properties of Granulated Blast Furnace Slags

2012 ◽  
Vol 454 ◽  
pp. 11-16
Author(s):  
Xian Jun Lu ◽  
Shu Gang Hu ◽  
Zi Qiao Jin
Keyword(s):  
Blast Furnace ◽  
Portland Cement ◽  
Amorphous Materials ◽  
Chemical Activation ◽  
Xrd Analysis ◽  
Hydration Products ◽  
X Ray ◽  
Early Strength ◽  
Activated Slag ◽  
Alkali Activated

Using CaO, NaOH and Na2CO3 as activators, the effects of dosage and combination of the activators on the cementing property of granulated blast furnace slags were investigated, and the hydration products of the activated slags were detected by X-ray powder diffraction (XRD) analysis. Results indicate that CaO can be used as an effective activator for the slag samples and its optimum dosage is about 10%, but the CaO activated slags shows much lower early strength than the Portland cement. However, the early strength of the CaO activated slag can be remarkably improved by the addition of NaOH or Na2CO3. Under the addition of about 6% NaOH or Na2CO3, the overall compressive strength of the alkali activated slag is higher than a 42.5MPa Portland cement. XRD analysis revealed that the hydration products of the alkali activated slags are mainly amorphous materials, which is quite different from that of the Portland cement.

scholarly journals The Effects of Aluminium Sulphate on Slag Paste Activated with Sodium Hydroxide and Sodium Silicate

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2286
Author(s):  
Taewan Kim ◽  
Sungnam Hong ◽  
Choonghyun Kang
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Sodium Hydroxide ◽  
Blast Furnace Slag ◽  
Aluminium Sulphate ◽  
The Third ◽  
Granulated Blast Furnace Slag ◽  
Activated Slag ◽  
Furnace Slag ◽  
Alkali Activated

This study investigates the characteristics of alkali-activated slag cement using aluminium sulphate (ALS) as an activator. The alkalis NaOH and Na2SiO3 were used as additional activators (denoted by alkali) at 5% and 10% of the weight of the ground granulated blast furnace slag (GGBFS). Three types of activators were considered. The first was when ALS was used alone. For the second, ALS and 5% alkali were used together. The third was when ALS and 10% alkali were used. ALS was used at concentrations of 2%, 4%, 6%, 8%, and 10% based on binder weight. Experimental results show that when ALS was used as a sole activator, the activity of GGBFS was low and its strength was below 1 MPa. However, compressive strength was improved when 5% or 10% alkali and ALS were used at the same time. This was effective at improving mechanical and microstructural performance when used with an additional activator capable of forming a more alkaline environment than using ALS as a sole activator.

Factors Influencing the Strength of Alkali-Activated Slag Cement

2011 ◽  
Vol 368-373 ◽  
pp. 3240-3245
Author(s):  
Zhi Jun Zhou ◽  
Hui Li ◽  
Qiang Song ◽  
Bao Jing Shen
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Silica Fume ◽  
Water Glass ◽  
Slag Cement ◽  
Alkali Activated Slag ◽  
Factors Influencing ◽  
Activated Slag ◽  
Alkali Activated

In this paper, water glass was chosen as activator to prepare Alkali-activated slag(AAS) cement. Effects of modulus and dosage of water glass, and admixture (fly ash, slag and silica fume) on the strength of AAS cement was investigated. It was found that the modulus of water glass had great effect on the strength of AAS cement when the mixing amount of water glass was less than 12%. With the incorporation of fly ash or slag, the strength of AAS cement decreased, however the incorporation of silica fume could promote the flexural and compressive strength of AAS cement slightly.

Effect of Sodium Hydroxide (NaOH) Concentration on Compressive Strength of Alkali-Activated Slag (AAS) Mortars

2015 ◽  
Vol 754-755 ◽  
pp. 300-304 ◽  
Author(s):  
Aimi Noorliyana Hashim ◽  
Kamarudin Hussin ◽  
Noorzahan Begum ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamrosni Abdul Razak ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Sodium Hydroxide ◽  
Blast Furnace Slag ◽  
Alkali Activated Slag ◽  
Granulated Blast Furnace Slag ◽  
Environmental Friendly ◽  
Activated Slag ◽  
Furnace Slag ◽  
Alkali Activated

Energy saving in building technology is among the most critical problems in the world. Thus it is a need to develop sustainable alternatives to conventional concrete utilizing more environmental friendly materials. One of the possibilities to work out is the massive usage of industrial wastes like ground granulated blast furnace slag (GGBS) to turn them to useful environmental friendly and technologically advantageous cementitious materials. In this study, ground granulated blast furnace slag (GGBS) is used to produce of alkali activated slag (AAS) mortar with the effect of alkaline activator concentration. Alkali activated slag (AAS) mortar is accelerated using alkaline solution of sodium silicate mixed with sodium hydroxide. The fixed ratio of sodium silicate to sodium hydroxide is 1.7 and the concentration of sodium hydroxide is varied from 6M to 12M. Concentration of 10M NaOH promotes the best properties of mortar by achieving the greatest compressive strength. Substitution of mineral admixture also influences strength performance of AAS mortars. The mortar with 20% calcium carbonate demonstrates the maximum compressive strength. The used of alkaline activation system is the best method to prepare industrial byproduct concrete. Moreover, alkali activated product itself gains superior properties which lead to the system become the most interesting method to produce sustainable concrete.

Effect of the Combined Using of Fly Ash and Granulated Blast Furnace Slag on Properties of Cementless Alkali-Activated Mortar

2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Curing Temperature ◽  
Mixture Ratio ◽  
Granulated Blast Furnace Slag ◽  
Alkaline Activator ◽  
Furnace Slag ◽  
Alkali Activated

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.

scholarly journals Effect of Dosage of Alkaline Activator on the Properties of Alkali-Activated Slag Pastes

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Zhenzhen Jiao ◽  
Ying Wang ◽  
Wenzhong Zheng ◽  
Wenxuan Huang
Keyword(s):  
Compressive Strength ◽  
Room Temperature ◽  
Setting Time ◽  
Drying Shrinkage ◽  
Engineering Properties ◽  
Alkali Activated Slag ◽  
Alkaline Activator ◽  
Activated Slag ◽  
Good Workability ◽  
Alkali Activated

This study focused on the engineering properties of alkali-activated slag (AAS) pastes prepared by mixing an activator consisting of sodium silicate and sodium hydroxide at room temperature. The water-to-slag ratio of AAS paste was kept constant at 0.35 by mass. AAS pastes were prepared using the activator with five different silicate moduli of 1, 1.2, 1.4, 1.6, and 1.8 and three different Na2O contents of 6%, 8%, and 10%. The results showed that both the silicate moduli and Na2O contents had significant effects on the engineering properties of AAS pastes. All the AAS pastes exhibited properties such as fast setting, good workability, and high early compressive strength. The final setting time varied from 9 to 36 min, and the fluidity was in the range of 147–226 mm. The 1 d compressive strength of all the AAS pastes, which could be easily achieved, had values above 55 MPa, whereas the highest strength obtained was 102 MPa with the silicate modulus of 1 and Na2O content of 8% at room temperature. The drying shrinkage increased as the silicate modulus increased. Furthermore, the hydration products and microstructures of AAS pastes were explained according to the microanalysis methods.

Effect of Dosage and Modulus of Water Glass on AC Impedance Properties of Alkali-Activated Slag Cement Mortar

2013 ◽  
Vol 423-426 ◽  
pp. 1018-1026
Author(s):  
Fu Qiang He ◽  
Xiao Peng An
Keyword(s):  
Compressive Strength ◽  
Water Glass ◽  
Cement Mortar ◽  
Ac Impedance ◽  
Slag Cement ◽  
Bulk Resistance ◽  
Alkali Activated Slag ◽  
Activated Slag ◽  
Alkali Activated

Compressive strength and AC impedance of mortar made with water-glass-activated slag were investigated as a dependence of modulus (0.5-2.0) and dosage (2-6%) of the water-glass. Results shown that when the dosage of water glass is 2- 4 %, the modulus of the water glass has a little effect on the compressive strength. In the case of the dosage of water glass is beyond 4 %, when modulus of the water glass change from 0.5-1.0, the compressive strength obviously increases with increase of modulus of water glass and when modulus of the water glass change from 1.0-2.0, the modulus of the water glass has a little effect on the compressive strength. The strength increases with increase of the dosage from 2 to 6%. In the case same dosage and modulus, there is a rather good power correlation between the bulk resistance and the activated age. With increase of the dosage, the bulk resistance significantly decreases when the dosage is below 4%. The decreasing degree is small when the dosage is beyond 4%. The decreasing degree derived from the dosage increases with the activated age. The effect of the modulus on the bulk resistance depends on range of the dosage. However, it can be regarded that when the dosage is 4% and 6%, the modulus has small effect on the bulk resistance in the case of all the dosages.

scholarly journals The use of limestone sludge for the geopolymer preparation

2021 ◽  
Vol 1205 (1) ◽  
pp. 012002
Author(s):  
D Kubatova ◽  
I Khongova ◽  
M Krejci Kotlanova ◽  
A Zezulova ◽  
M Bohac
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Linear Correlation ◽  
Blast Furnace Slag ◽  
Water Glass ◽  
Setting Time ◽  
Sludge Waste ◽  
Alkaline Activator ◽  
Positive Effect ◽  
Furnace Slag

Abstract The study investigates the effect of sludge waste from mining and washing of limestone on the properties of geopolymer binders based on metakaolin and blast furnace slag. The effect of adding two types of limestone sludge on workability, setting time, compressive strengths, durability and pore distribution was investigated. Limestone sludge was dosed in an amount of 0–30 %. Sodium water glass was used as an alkaline activator in the ratio of 5:4. A linear correlation between the flowability and limestone sludge content was observed, and very satisfactory results of compressive strength after 90 days were obtained for samples with sodium water glass (about 55 MPa). The positive effect of CaCO3 on strength was confirmed. The increased content of clay components resulted in a reduction of compressive strength.

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