Electrochemical Evaluation on the Corrosion Properties of Welding Zones of 304 Stainless Steel

2010 ◽  
Vol 146-147 ◽  
pp. 1238-1242
Author(s):  
Kyung Man Moon ◽  
Yun Hae Kim ◽  
Sung Jin Kim ◽  
Ji Hyeong Yoon ◽  
Youn Chang Lee ◽  
...  

Two types of welding methods were performed on austenitic 304 stainless steel: laser welding and TIG welding. The differences of the corrosion characteristics of the welded zones from the two welding methods were investigated with electrochemical methods, such as measurement of the corrosion potential, polarization curves, cyclic voltammogram, etc. The Vickers hardness of all laser-welded zones (WM:Weld Metal, HAZ:Heat-Affected Zone, BM:Base Metal) was relatively higher while their corrosion current densities exhibited a comparatively lower value than those which were TIG welded. In particular, the corrosion current density of the TIG-welded HAZ had the highest value among all other welding zones, which suggests that chromium depletion due to the formation of chromium carbide occurs in the HAZ, which is in the sensitization temperature range, thus it can easily be corroded with an active anode. Intergrenular corrosion was also observed at the TIG-welded HAZ and WM zones. Consequently, we can see that corrosion resistance of all austenitic 304 stainless steel welding zones can be improved via the use of laser welding.

2010 ◽  
Vol 146-147 ◽  
pp. 899-903
Author(s):  
Kyung Man Moon ◽  
Yun Hae Kim ◽  
Myung Hoon Lee

Two kinds of welding methods were performed on 22APU stainless steel: laser welding and TIG welding. In this case, the differences of the corrosion characteristics of the welded zones between the two welding methods mentioned above were investigated with electrochemical methods such as the measurement of corrosion potential, polarization curves, cyclic voltammogram, etc. The Vickers hardness of all welded zones (WM:Weld Metal, HAZ:Heat-Affected Zone, BM:Base Metal) was relatively higher for the laser welding than for the TIG welding. Furthermore, the laser welding method’s corrosion current densities in all welding zones were also observed to have a lower value compared to TIG welding. In particular, the corrosion current density of BM, regardless of the welding method, was the lowest value among all other welding zones. Intergranular corrosion was not observed at the corroded surface of all laser-welded welding zones; however, it was observed at the TIG-welded WM and HAZ welding zones, which suggests that chromium depletion due to the formation of chromium carbide occurs on the WM and HAZ which are in the range of sensitization temperatures, therefore the zones can easily be corroded with a more active anode. Consequently, we can see that corrosion resistance of all welding zones of 22APU stainless steel may be improved by the use of laser welding. Keywords: Laser welding, TIG welding, Corrosion potential, Weld metal, Heat affected zone, Polarization curves, Chromium depletion1.Introduction In recent years, use of austenitic stainless steel, which has a high corrosion resistance, has been increasing due to the development of industries, such as atomic energy, aerospace, petro chemical, etc. When stainless steel was welded for numerous kinds of structures, intergranular corrosion would often be observed at the area surrounding the welding zone due to chromium depletion; in addition, there are numerous papers which have investigated both general corrosion and intergranular corrosion[1-6]. However, there are few experimental results on the effect of corrosion control at the welding zones when laser or TIG welding are used for the purpose of constructing heat exchangers with 22 APU stainless steel. Although laser welding is more expensive than TIG welding, laser welding is often used instead of TIG welding for the production of heat exchangers. Consequently, it has been suggested that, from a long-term point of view, laser welding is more economic than TIG welding. In this study, when TIG and laser welding are performed on the stainless steel, the differences of the corrosion characteristics in the welding zone was investigated with electrochemical methods. The experimental results are therefore expected to provide useful reference data for the appreciation of mechanical and corrosion characteristics in the welding zones.


2013 ◽  
Vol 331 ◽  
pp. 536-539
Author(s):  
Jian Bin Zhang ◽  
Dong Mei Yu ◽  
Jian Lin Xu

The layer of Al-modified austenitic stainless steel was formed by laser cladding with pre-placed FeNiCrAl powder on 304SS surface. No porosity and free of cracks was observed at power density of 31.25 w·s·mm-2. The microstructure of cladded layer was observed by OM (optical microscope) and SEM (scanning electron microscope). Compared with 304 (the substrate), laser cladding FeNiCrAl layer exhibit excellent pitting resistance in mixed acid solution. Anodic polarization curve indicated that the corrosion potential of laser cladding layer was 70 mV higher than that of 304SS (-345.7 mV), while self-corrosion current density of 304SS was 2.4 times as high as that of laser cladding layer.


1999 ◽  
Vol 23 (1) ◽  
pp. 38-39
Author(s):  
N. Bellakhal ◽  
K. Draou ◽  
J. L. Brisset

Exposure of a 304 stainless steel sample to an inductively coupled low pressure radio frequency (RF) nitrogen plasma leads to the formation of a nitriding layer. The protective properties of this layer are investigated by electrochemical methods. The corrosion potential of the steel in an aqueous solution depends on the working parameters of the plasma such as the time exposure and the distance between the steel sample and the high voltage (HV) coil of the treatment reactor.


2021 ◽  
Vol 13 (1) ◽  
pp. 152-160
Author(s):  
Yanjie Wang ◽  
Xuru Hou ◽  
Lin Zhao ◽  
Yun Peng ◽  
Chengyong Ma ◽  
...  

304 stainless steel test block was fabricated by continuous melting wire with CMT and pulse mixed mode, and the path of additive manufacturing is layered slice S-shaped. The relationship between microstructure and properties of the specimen was investigated by microscope, SEM, EBSD, XRD, tensile, impact and electrochemical experiments. The results show that molding between weld and weld is very good, and the microstructure is mainly Austenite, Ferrite and a little of σ, and there are three kinds of Ferrite morphology: cellular, wormlike and lath. σ phase precipitates easily in regions with high ferrite content and is distributed at the boundary between austenite and ferrite. The specimen has good low temperature toughness. The microscopic fracture surface is mainly dimple, and the precipitates in the fracture surface are mainly fine carbide particles. The tensile strength of the additive manufacturing 304 specimen is higher than the forged specimen, and the type of fracture is ductile fracture. The electrochemical analysis of 304 stainless steel specimens and forgings shows that CMT and pulse arc additive manufacturing specimen has excellent corrosion resistance and its corrosion current is slightly lower than the forging.


2013 ◽  
Vol 815 ◽  
pp. 778-781
Author(s):  
Xiao Hong Wu

Used YAG pulse laser to weld 304 stainless steel nuts, studied about the parameters such as peak power, pulse width, defocus distance impacting on the performance of the joints welded by laser. The studies showed that the tensile strength and torque of the nuts increased as the peak power and the pulse width increased.Burn through in welding easy occur when laser pulse energy is too big, pulse width is too wide or defocus distance is too low.


2015 ◽  
Vol 52 (4) ◽  
pp. 041403
Author(s):  
刘东宇 Liu Dongyu ◽  
李东 Li Dong ◽  
李凯斌 Li Kaibin ◽  
陈倩倩 Chen Qianqian

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