Electrochemical trepanning of blades made of Inconel 625

In the aerospace field, difficult-to-machine materials are used widely to improve engine performance. As a nickel-based material that performs well in all aspects, Inconel 625 is used for the blisks of aircraft engines, and electrochemical trepanning (ECTr) is used widely to fabricate such blisks because of its unique advantages regarding ruled surface parts. In this study, to investigate the performance of Inconel 625 in ECTr, measurements were made of the electrochemical characteristics firstly, specifically the anodic polarization curve and the actual volumetric electrochemical equivalent curve. Then, via dynamic electric-field simulations, the processes for forming Inconel 625 blades using ECTr were examined under direct voltage (DV) and pulsed voltage. The contours and current density distributions of formed blades at different times were obtained under different duty cycles. With decreasing duty cycle, the forming accuracy improved gradually and the stray current was reduced. To verify the simulation results, ECTr experiments with Inconel 625 were performed under different voltage conditions. With DV and 90% and 80% duty cycle, the taper angles of the machined blades were 7.784°, 6.278°, and 5.191°, respectively, and the surface roughness ( Ra) values were 0.95, 0.81, and 0.72 μm, respectively. With DV, there were obvious flow marks and gullies on the microscopic surface. With decreasing duty cycle, stray corrosion was reduced effectively and the state of the flow field was improved. Overall, the simulation results were verified effectively.

Electrode processes during electrodeposition, electropolishing and oxidation of niobium

The electrode processes occurring during the electrodeposition, electropolishing and oxidation of niobium are considered. The discharge of Nb(IV) complexes during Nb electrodeposition was studied by cyclic voltammetry. The anodic polarization curve on niobium in a mixture of acids H2SO4:HF (9:1) was obtained by chronopotentiometry method, the potential range at which the highest quality and speed of electropolishing is achieved was found. The film formation mechanism of niobium pentoxide Nb2O5 on niobium was studied by cyclic voltammetry.

EFFECT OF AL2O3 NANOPARTICLES ON CORROSION BEHAVIOR OF ALUIMNUM ALLOY (AL-4.5 WT% CU-1.5 WT% MG) FABRICATED BY POWDER METALLURGY

In this research the effect of Al2O3 nanoparticles on corrosion behavior of aluminum base alloy (Al-4.5 wt% Cu-1.5 wt% Mg) has been investigated. Nanocomopsites reinforced with variable contents of 1, 3 and 5 wt% of Al2O3 nanoparticles were fabricated using powder metallurgy. All samples were prepared from the base alloy powders under the best powder metallurgy processing conditions of 6 hr of mixing time, 450 MPa of compaction pressure and 560 °C of sintering temperature. Density and micro hardness measurements, and electrochemical corrosion tests are performed for all prepared samples in 3.5 wt% NaCl solution at room temperature using potentiostate instrument. It has been found that density and micro hardness of the nanocomposite increase with increasing of wt% Al2O3 nanoparticles to Al matrix. It was found from Tafel extrapolation method that corrosion rates of the nanocomposites reinforced with alumina nanoparticles were lower than that of base alloy. From results of corrosion test by potentiodynamic cyclic polarization method, it was found the pitting corrosion resistance improves with adding of Al2O3 nanoparticles. It was noticed that the pits disappear and the hysteresis loop disappears also from anodic polarization curve.

Effect of Co-substitution on the electrocatalytic properties of Ni1.5Fe1.5O4 for oxygen evolution in alkaline solutions

Some ternary ferrites having composition CoxNi1.5-xFe1.5O4 (0.0 ≤ x ≤ 1.25) have been synthesized by NH4OH co-precipitation method at 11.5 pH. Materials, so obtained, were tested for their electrocatalytic properties towards oxygen evolution reaction (OER) in the form film on Ni-support in alkaline solution. The study showed that the electrocatalytic properties the material increased with partial substitution of Co for Ni in the base oxide (Ni1.5Fe1.5O4). The value being highest with 0.5 mol Co-substitution. At E = 850 mV vs Hg/HgO in 1M KOH at 25 ºC, the electrode showed apparent current density 206.2 mA cm-2, which is about 3 times higher than the base oxide. The Tafel slope values were ranged between 46-82 mV decade-1. A pair of redox peak, an anodic (EPa = 522±28 mV) and corresponding cathodic (EPc= 356±9 mV), was observed in the cyclic voltammetry (CV) study of the material. The thermodynamic parameters namely, standard apparent electrochemical enthalpy of activation ( ), standard enthalpy of activation ( ) and standard entropy of activation ( ) for the oxygen evolution reaction (OER) have also been determined by recording anodic polarization curve in 1M KOH. The value of was observed to be almost similar with each oxide electrode. The values were highly negative and ranged between ~ -165 and ~ -207 J deg-1 mol-1. Phase and morphology of materials have been investigated by using physical techniques X-ray diffraction, infrared spectroscopy (IR) and scanning electron microscope (SEM), respectively.

The Corrosion Behavior of Stainless Steel 316L in Novel Quaternary Eutectic Molten Salt System

In this article, the corrosion behavior of stainless steel 316L in a low melting point novel LiNO3-NaNO3-KNO3-NaNO2 eutectic salt mixture was investigated at 695 K which is considered as thermally stable temperature using electrochemical and isothermal dipping methods. The passive region in the anodic polarization curve indicates the formation of protective oxides layer on the sample surface. After isothermal dipping corrosion experiments, samples were analyzed using SEM and XRD to determine the topography, corrosion products, and scale growth mechanisms. It was found that after long-term immersion in the LiNO3-NaNO3-KNO3-NaNO2 molten salt, LiFeO2, LiFe5O8, Fe3O4, (Fe, Cr)3O4 and (Fe, Ni)3O4 oxides were formed. Among these corrosion products, LiFeO2 formed a dense and protective layer which prevents the SS 316L from severe corrosion.

Corrosion Resistance Dependence of Rare Earth NiCrMoY Alloy Coatings

The wear and corrosion of rare earth NiCrMoY alloy manufactured by atomization and oxygen-acetylene flame spray and high frequency induction remelting technique are investigated by a combination of scanning electron microscopy (SEM), energy spectrum, X-ray diffraction meter (XRD), uniform corrosion method of laboratory immersion test, anodic polarization curve of three electrodes potentiodynamic scan. The results indicate that Corrosion rate of NiCrMoY alloy coatings is better than that of Ni60A coatings in HCl, H2SO4, HNO3 and artificial seawater, and its wear is much better than those of Ni60A coatings.

Microstructural Study of the Magnesium Alloy (Az31) Galvanostatically Etched for Different Periods Followed by Copper Electrodeposition in the Alkaline Copper-Sulfate Bath

A well adherent copper deposit on the Mg alloy (AZ31) can be obtained with a pretreatment with galvanostatic etching then followed by copper electrodeposition in an alkaline copper-sulfate plating bath. Experimental results show that the effect of galvanostatic etching on copper electrodeposition depends strongly on potential variation during anodic etching period. Oxygen-rich Cu and Mg layers were observed in the initial stage of galvanostatic etching. However, increasing the gavanostatic etching period to the potential plateau of its anodic polarization curve, the oxygen-rich Cu and Mg layers were almost removed and an activated surface of AZ31 can be achieved, which is suitable for Cu electrodeposition in the alkaline Cu-sulfate plating bath. The above-mentioned results were evidenced from the microstructure study with scanning transmission electron microscope.

Passing Aged Years to Polarization Characteristics of the Steel Bar Embedded in Mortar Specimen (W/C:0.4)

The structures of reinforced concrete has been extensively increased with rapid development of industrial society. Furthermore, these reinforced concretes are often exposed to severely corrosive environments such as sea water, contaminated water, acid rain and seashore etc.. Thus, the corrosion problem of a steel bar embedded in the concrete is very important in terms of the safety and economic points of view. In this study, a multiple mortar test specimen (W/C:0.4) that had six types of cover thickness was prepared and immerged in flowing seawater for five years. And the effects of cover thickness and immersion years on the corrosion properties of the steel bars were investigated using electrochemical methods such as measuring corrosion potential, anodic polarization curve, and impedance. At the beginning of immersion (0 year), corrosion potentials exhibited increasingly nobler value with increasing the cover thickness. However, after being immersed for 5 years, the corrosion potentials conversely shifted in the positive direction with decreasing the cover thickness. As a result, the relationships between corrosion potential and cover thickness were not in good agreement with each other after 5 years. In addition, after 5 years, the thinner cover thickness, the higher value of impedance at 0.01Hz. It is considered that corrosive products deposited on the surface of the steel bar embedded in mortar specimen in the case of thinner cover thickness played the role as a resistance polarization which resulted in decreasing the corrosion current density. Consequently, it seemed to be somewhat problem that evaluation on the corrosion property in reinforced steel would be estimated by only the corrosion potential measurement. Therefore, it is suggested that we should take into account various parameters such as cover thickness, corrosion potential, and immersed years etc. for its accurate assessment. Keywords : Cover thickness, Corrosion potential, Anodic polarization curve, Impedance, Resistance polarization

Effect of Nitrite Ions on Polarization Behavior of Steel Immersed in Simulated Concrete Pore Environments

The influence of nitrite concentration on the linear polarization curves of steel, Tafel slope and Stern-Geary constant B have been investigated in three different pH environments simulating the highly alkaline environment, carbonated environment and neutral environment that really existed on the surface of steel in concrete. The results indicate that when the steel is in passive state, the presence of nitrite has little influence on anodic/cathodic polarization curves and Stern-Geary constant B; but when the steel is corroded, the presence of nitrite not only reduces the current density of anodic polarization curve but also decreases the value of Stern-Geary constant B. If this influence is not considered in practical corrosion measurement, the corrosion current will be overestimated.

Corrosion Properties of Al-Modified Austenitic Stainless Steel Prepared by Laser Cladding

The layer of Al-modified austenitic stainless steel was formed by laser cladding with pre-placed FeNiCrAl powder on 304SS surface. No porosity and free of cracks was observed at power density of 31.25 w·s·mm-2. The microstructure of cladded layer was observed by OM (optical microscope) and SEM (scanning electron microscope). Compared with 304 (the substrate), laser cladding FeNiCrAl layer exhibit excellent pitting resistance in mixed acid solution. Anodic polarization curve indicated that the corrosion potential of laser cladding layer was 70 mV higher than that of 304SS (-345.7 mV), while self-corrosion current density of 304SS was 2.4 times as high as that of laser cladding layer.