Preparation and Characterization of Melt-Spun Poly( Acrylonitrile-Methylacrylate) Hollow Fiber

2011 ◽  
Vol 332-334 ◽  
pp. 339-342
Author(s):  
Wei Wei Peng ◽  
Na Han ◽  
Xiao Fen Tang ◽  
Hai Hui Liu ◽  
Xing Xiang Zhang
Keyword(s):  
Hollow Fiber ◽  
Melt Spinning ◽  
Raw Materials ◽  
Thermo Gravimetric Analysis ◽  
Feed Ratio ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Single Screw Extruder ◽  
Heat Preservation

In this study, a 85/15 AN/MA copolymer (acrylonitrile – methylacrylate copolymer with feed ratio of 85/15 mol%) was synthesized by emulsion polymerization at 60 °C, and then the copolymer was used to produce hollow fiber (abbreviated as PAN hollow fiber )by melt spinning using a single screw extruder machine. The PAN hollow fiber was characterized by using Scanning Electron Microscope (SEM), Thermo-gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). The hollow fiber of melt-spinning PAN with high hollow rate of 51.1% has a homogeneous wall and regular section. The hollow fiber is potentially used as raw materials to fabricate heat preservation fabric for comfort clothing.

Synthesis and Characterization of the Bismaleimides Containing Aliphatic-ether Chain for Microelectronics Application

e-Polymers ◽  
2006 ◽  
Vol 6 (1) ◽  
Author(s):  
J. L. Feng ◽  
C. Y. Yue ◽  
K. S. Chian
Keyword(s):  
Chain Length ◽  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Degradation Temperature ◽  
Dielectric Thermal Analysis ◽  
Aliphatic Ether ◽  
Synthetic Reaction

AbstractThis project aims to develop and characterize a series of bismaleimide (BMI) polymers based on maleic anhydride and aliphatic-ether diamines. The effects of varying the chain length of aliphatic-ether diamines on the resultant bismaleimide systems were evaluated so that their suitability for microelectronics applications could be evaluated. The synthetic reaction and properties of the bismaleimide materials were investigated using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), Thermo- Gravimetric Analysis (TGA), Dielectric Thermal Analysis (DEA) and rheometry. Results showed that thermal, dielectric and rheological properties were all affected by the main chain length of BMI. The magnitude of the dielectric constant at 100 kHz increases with the increasing chain length. The curing peak temperature, curing heat and degradation temperature of BMI, all decrease with the increasing chain length.

Optically active polymer: synthesis and characterization of new optically active poly (hydrazide-imide)s incorporating L- leucine

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Abdol Reza Hajipour ◽  
Saeed Zahmatkesh ◽  
Arnold E. Ruoho
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Specific Rotation ◽  
Optically Active ◽  
Gravimetric Analysis ◽  
Optically Active Polymer ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Good Thermal Stability ◽  
H Nmr

AbstractThis paper deals with the polycondensation between a chiral diacyl chloride (N,N′-Pyromelliticdiimido-di-L-leucine chloride) and six different dihydrazides. The corresponding poly (hydrazide-imide)s which have been obtained in quantitative yields are moderately soluble in polar aprotic solvents, have good thermal stability and optical activity. The synthetic compounds have been characterized by IR, UV and 1H NMR spectroscopy, elemental analysis and specific rotation. The thermal properties of the polymers (10 and 15) have been studied by thermo gravimetric analysis (TGA) and differential scanning calorimetry (DSC).

Experimental Investigation of Kevlar KM2Plus Nano-Reinforced Laminated Composite Thermo-Mechanical Properties

2016 ◽  
Author(s):  
Abdel-Hamid I. Mourad ◽  
Omar G. Ayad ◽  
Ashfakur Rahman ◽  
Ali Hilal-Alnaqbi ◽  
Basim I. Abu-Jdayil
Keyword(s):  
Mechanical Properties ◽  
Thermo Gravimetric Analysis ◽  
Laminated Composite ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Three Point Bending ◽  
Multi Walled Carbon Nanotube ◽  
Thermal Stability Of

This work is concerned with the synthesis and characterization of Multi-Walled Carbon Nanotube (MWCNT) reinforced Kevlar KM2Plus composites with various MWCNT contents (0.2, 0.3, 0.4, 0.5, 0.6, and 0.8 wt. %), by the wet lay-up technique. These samples were experimentally investigated for their thermo-mechanical properties using Thermo-Gravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), tensile testing and three-point bending techniques. The mechanical properties showed remarkable improvement with increasing MWCNT wt.% up to certain content. The results revealed that the addition of MWCNT fillers has no significant effect on the thermal stability of the composites.

Production of Ceramic Materials Using only Waste as Raw Materials

2015 ◽  
Vol 663 ◽  
pp. 62-71 ◽  
Author(s):  
R.J. Galán-Arboledas ◽  
Salvador Bueno
Keyword(s):  
Power Plant ◽  
Bending Strength ◽  
Raw Materials ◽  
Equilibrium Diagram ◽  
Thermo Gravimetric Analysis ◽  
Main Tool ◽  
Ceramic Materials ◽  
Absorption Capacity ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry

From a selection of inorganic industrial waste (screen glass, steelworks ashes, coal power plant ashes, biomass power plant ash and sludge from cutting marble industry) and a waste with organic fraction (diatomaceous earth from oil filtration) it is expected to obtain ceramic materials with properties similar to those of ceramic materials used in construction and porous materials with thermal insulating capability. The ternary phase equilibrium diagram SiO2-Al2O3-CaO has been used as the main tool for the formulation of these materials. The dynamic sintering study was carried out using dilatometry techniques (DIL), thermo gravimetric analysis and differential scanning calorimetry (TG-DSC). Characterization of the manufactured material allows determining a set of basic technological properties such as fired bulk density, water absorption capacity and bending strength, in addition to thermal conductivity and microstructure by SEM-EDX, in order to obtain the necessary data to determine technical feasibility.

Synthesis of LiFePO4 Cathode Materials by a Chemical Method

2011 ◽  
Vol 197-198 ◽  
pp. 1049-1052
Author(s):  
Yuan Sun ◽  
Xiu Juan Zhao ◽  
Guo Jun Li ◽  
Rui Ming Ren
Keyword(s):  
Chemical Method ◽  
Single Phase ◽  
Raw Materials ◽  
Thermo Gravimetric Analysis ◽  
Precipitation Method ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Co Precipitation

The olivine-type LiFePO4powder was prepared by a chemical method using the synthesized FePO41.78H2O, LiOH, citric acid and PEG as raw materials. The synthesized FePO41.78H2O precursor powder was obtained by co-precipitation method. LiFePO4powder was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermo-gravimetric analysis (TGA)/differential scanning calorimetry (DSC). The results showed that the calcined LiFePO4was in a single phase when fabricated by using the synthesized FePO41.78H2O powder at pH of 3.5 in argon atmosphere.

Preparation and Characterization of Sulfonated Poly(ether Sulfone) Using 4,4-Bis(4-Hydroxylphenyl)valeric Acid for Proton Exchange Membrane Fuel Cell Application

2009 ◽  
Vol 620-622 ◽  
pp. 73-76 ◽  
Author(s):  
Dong Wan Seo ◽  
Young Don Lim ◽  
M. S. Islam Mollah ◽  
Soon Ho Lee ◽  
Sang Ho Moon ◽  
...  
Keyword(s):  
Proton Exchange Membrane ◽  
Thermo Gravimetric Analysis ◽  
Proton Exchange ◽  
Valeric Acid ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Fuel Cell Application ◽  
Exchange Membrane ◽  
Sulfonated Poly

Poly(ether sulfone)s (PES) containing 25-75 mol % valeric acid were prepared with bisphenol A, bis(4-chlorophenyl)sulfone and 4,4-Bis(4-hydroxylphenyl)valeric acid using potassium carbonate in DMAc (dimethylacetamide) at 160 °C. Copolymers containing carboxylacid group were reduced to hydroxy group by BH3 solution 1M in THF and NaBH4 co-catalyst. Sulfonated poly(ether sulfone)s (S-PES) were obtained by reaction of 1,3-propanesultone and the reduced copolymer (PES-OH) with potassium t-butoxide. A series of copolymers were studied by 1H-NMR spectroscopy, differential scanning calorimetry (DSC), and thermo gravimetric analysis (TGA). Sorption experiments were conducted to observe the interaction of sulfonated polymers with water and methanol. The S-PES membranes exhibited proton conductivities from 1.20  10-3 to 3.40  10-3 S/cm, water swell from 12.25 to 31.50 %, IEC from 0.43 to 0.72 meq/g and methanol diffusion coefficients from 3.60  10-7 to 4.90  10-7 cm2/S at 25 °C.

Synthesis and Characterization of Porous Polyurethane-Chitosan Blends

2009 ◽  
Vol 28 (3) ◽  
pp. 179-191 ◽  
Author(s):  
Imelda Olivas-Armendariz ◽  
Perla E. García-Casillas ◽  
Alberto Martínez-Villafañe ◽  
Carlos A. Martinez-Pérez
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Thermo Gravimetric Analysis ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Chitosan Blends ◽  
Scanning Electron

In this work the synthesis and characterization of polyurethane (PU)-chitosan(CH) porous prepared by thermal induced phase separation (TIPS) is described, the obtained products were characterized by thermo gravimetric analysis (TGA) and differential scanning calorimetry (DSC), evidence of the interaction between both polymers was acquired from infrared spectroscopy. The morphology of the scaffolds was studied by scanning electron microscopy also the mechanical properties were acquired. The results showed that the TIPS technique is appropriate for the production of PU-CH porous materials.

scholarly journals Synthesis and Characterization of Natural Oil Doped PVA Membrane

2020 ◽  
pp. 32-36
Author(s):  
X. S. Gama
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Appropriate Technology ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Thermo Gravimetric ◽  
Improve Accuracy ◽  
Natural Oil ◽  
Basil Oil

In deciding the workable layout of any network an appropriate technology plays a major role and can improve accuracy and flexibility efficiently, if chosen and implemented in best possible way. The growth in the infrared applications has created a need for knowledge of its optical characteristics in the spectral region for the purpose of designing. Very little work is previously reported in natural oil doped PVA membranes. In this work, a simple attempt is made synthesize and characterize the wintergreen oil and basil oil doped PVA membranes. In investigation, basil oil and wintergreen oil doped PVA membranes were prepared and is made to characterize. The resulting membranes were characterized by Fourier transform infrared spectroscopy (FTIR), wide-angle X-ray diffraction (WXAD), thermo-gravimetric analysis (TGA) and differential scanning Calorimetry (DSC).

Coordination Compounds of Some 3d-Transition Metal Ions with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)- thiosemicarbazide

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Madalina Angelusiu ◽  
Maria Negoiu ◽  
Stefania-Felicia Barbuceanu ◽  
Tudor Rosu
Keyword(s):  
Coordination Compounds ◽  
Magnetic Moments ◽  
Thermo Gravimetric Analysis ◽  
Electronic Spectroscopy ◽  
Transition Metal Ions ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
New Compounds

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

scholarly journals Rapid four-component synthesis of dihydropyrano[2,3-c]pyrazoles using nano-eggshell/Ti(IV) as a highly compatible natural based catalyst

BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Arefeh Dehghani Tafti ◽  
Bi Bi Fatemeh Mirjalili ◽  
Abdolhamid Bamoniri ◽  
Naeimeh Salehi
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Reaction Times ◽  
Diffraction Field ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Solvent Free Conditions ◽  
High Yields ◽  
Work Up

AbstractNano-eggshell/Ti(IV) as a novel naturally based catalyst was prepared, characterized and applied for the synthesis of dihydropyrano[2,3-c]pyrazole derivatives. The characterization of nano-eggshell/Ti(IV) was performed using Fourier Transform Infrared spectroscopy, X-ray Diffraction, Field Emission Scanning Electron Microscopy, Energy-Dispersive X-ray Spectroscopy, and Thermo Gravimetric Analysis. Dihydropyrano[2,3-c]pyrazoles were synthesized in the presence of nano-eggshell/Ti(IV) via a four component reaction of aldehydes, ethyl acetoacetate, malononitrile and hydrazine hydrate at room temperature under solvent free conditions. The principal affairs of this procedure are mild condition, short reaction times, easy work-up, high yields, reusability of the catalyst and the absence of toxic organic solvents.

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