Thermal Conductivity and Electrical Resistivity in Polycrystalline and Nanocrystalline Nickel

2011 ◽  
Vol 409 ◽  
pp. 561-565 ◽  
Author(s):  
S. Wang ◽  
I. Brooks ◽  
J.L. McCrea ◽  
G. Palumbo ◽  
G. Cingara ◽  
...  

The grain-size dependences of thermal conductivity and electrical resistivity of polycrystalline and nanocrystalline nickel were measured by the flash method and four-point probe method, respectively. Nanocrystalline nickel (grain size: 28 nm) was made by the pulsed-current electrodeposition process, while polycrystalline nickel (grain size: 57 μm) was the same material in fully annealed condition. Noticeable differences in thermal conductivity and electrical resistivity were observed for both materials. These results can be explained on the basis of the rapid increase in the intercrystalline grain boundary and triple junction volume fractions at very small grain sizes. The relationship between thermal conductivity and electrical resistivity of nanocrystalline nickel follows the classic Wiedemann-Franz law.

2012 ◽  
Vol 535-537 ◽  
pp. 801-804
Author(s):  
Sen Tian ◽  
Quan Xi Cao ◽  
Bo Wang ◽  
Fu Min Xu

High quality, transparent 1.0at% Nd:YAG ceramics were fabricated successfully by a solid-state reaction and vacuum sintering, and the characteristics were also identified in different methods. The lowest transmittance is 44.85% and the highest is 71.98%. 9 samples were used for thermal diffusivity detecting using laser flash method. Thermal diffusivity decreases as temperature increases, and The diffusivity increases as average grain size grows. However, when average grain size is smaller than 8μm, the diffusivity decreases much faster. Mechanical advantages be ensured, the average grain size should be above 8μm.


2018 ◽  
Vol 229 ◽  
pp. 261-264 ◽  
Author(s):  
Xin Tong ◽  
Guoqiang You ◽  
Yuhan Ding ◽  
Hansong Xue ◽  
Yichang Wang ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1212 ◽  
Author(s):  
Changchun Wang ◽  
Lele Song ◽  
Yupeng Xie

Single-phase tungsten diboride (WB2) was synthesized at high pressure and high temperature. The different grain sizes ranging from 300 nm to 3 µm were successfully obtained in WB2 by controlling the experimental conditions. The effects of grain size on hardness and resistivity properties were investigated. The Vickers hardness of WB2 was modulated with grain size. The maximum asymptotic Vickers hardness is 25.5 GPa for WB2 with a grain size of 300 nm which is a 10% increase compared to WB2 with a grain size of 3 µm. The optimal electrical resistivity of WB2 was 10−7 Ωm with the biggest grain size of 3 µm, which is ascribed to low grain boundary density. The superior properties of hardness and electrical resistivity demonstrate that WB2 should be a new functional hard material replacing WC which is widely used in industrial production.


2001 ◽  
Vol 691 ◽  
Author(s):  
Donny W. Winkler ◽  
Terry M. Tritt ◽  
Robert Gagnon ◽  
J. Strom-Olsen

ABSTRACTQuasicrystals have properties associated with both crystalline and amorphous materials. These properties appear to be sensitive to both composition and annealing conditions. Therefore, it is important to investigate the influence of the microstructure on the electrical and thermal transport properties of quasicrystals. AlPdMn quasicrystal samples were prepared with various levels of Re substituted for the Mn (Al70Pd20Mn10−XReX) and then subjected to different annealing conditions. Electrical resistivity, thermopower and thermal conductivity were measured on each as grown and annealed sample over a broad range of temperature, 10 K < T < 300 K. The relationship between the electrical and thermal transport properties and microstructure will be presented and discussed.


2015 ◽  
Vol 661 ◽  
pp. 105-112
Author(s):  
Yeong Maw Hwang ◽  
Tso Lun Yeh

Material’s plastic deformation by hot forming processes can be used to make the materials generate dynamic recrystallization (DRX) and fine grains and accordingly products with more excellent mechanical properties, such as higher strength and larger elongation can be obtained. In this study, compression tests and water quenching are conducted to obtain the flow stress of the materials and the grain size after DRX. Through the regression analysis, prediction equations for the magnesium alloy microstructure were established. Simulations with different rolling parameters are conducted to find out the relationship between the DRX fractions or grain sizes of the rolled products and the rolling parameters. The simulation results show that rolling temperature of 400°C and thickness reduction of 50% are the optimal conditions. An average grain size of 0.204μm-0.206μm in the microstructure is obtained and the strength and formability of ZK60 magnesium alloys can be improved.


2010 ◽  
Vol 45 (11) ◽  
pp. 1209-1216 ◽  
Author(s):  
A.M. Zihlif ◽  
Ziad Elimat ◽  
G. Ragosta

The thermal, viscoelastic, mechanical behavior of polymers filled with dispersed zeolite and oil shale is studied as a function of temperature, grain size, and filler concentration. It was found that the thermal conductivity of epoxy—zeolite composite increases with different zeolite grain sizes and takes a higher value in case of the 63 μm grain size composite. The observed enhancement in the thermal conductivity of zeolite composites correlates well with that of the electrical conductivity. The thermodynamic results exhibit a slight increase in the glass transition temperature of the polystyrene/oil shale composites, and shift in the observed relaxation peaks with increasing the oil shale content. The plastic deformation of PS/oil shale composites shows that the elastic modulus increases and the compressive yield stress decreases with oil shale content. The Eyring theory of yielding could predict the dependence of the yield stress on the applied strain rate. The predicted activation volume and activation energy showed dependence on the oil shale grains sizes and content.


1998 ◽  
Vol 517 ◽  
Author(s):  
Y.-N. Hsu ◽  
D. E. Laughlin ◽  
D. N. Lambeth

AbstractThe effects of sputtering argon pressures and sputtering power on the microstructure, texture and magnetic properties of NiAI underlayers on CoCrPt films were investigated. In this paper, the relationship between the sputtering conditions, microstructure, crystallographic texture and magnetic properties of these thin films will be discussed. By controlling the sputtering pressure and sputtering power, the texture and microstructure of NiAI underlayers were found to vary. This in turn was found to influence the magnetic properties of CoCrPt thin films. It was found that 10 mtorr is the optimum pressure to deposit the NiAl thin films to obtain the best magnetic properties for our system. At this argon pressure, the coercivity reached a maximum value because of the strongest CoCrPt (1010) texture and smallest grain size. At lower argon pressures (< 10 mtorr), NiAI tended to have a (110) texture reducing the CoCrPt (1010) texture, which in turn reduced the CoCrPt coercivity and S*. Also, high NiAl deposition pressures (>30 mtorr) yielded larger grains and a weaker CoCrPt (1010) texture, thereby decreasing the coercivity of the CoCrPt films. Increasing the sputtering power has been found to increase the CoCrPt coercivity and S* value. However, the grain sizes of the CoCrPt/NiAl thin films deposited at higher sputtering power were larger than those obtained at lower sputtering power.


2021 ◽  
Author(s):  
Alberto Carrera ◽  
Jacopo Boaga ◽  
Paolo Scotton ◽  
Antonio Galgaro

&lt;p&gt;The growing demand for renewable energy leads to an increase in the development of alternative energy applications. In this way, shallow geothermics assumes an important role in the global energy transition of building air conditioning. The design of Ground Source Heat Pumps (GSHP) requires a multidisciplinary approach including a good understanding of the underground geological setting, such as hydrogeological aspects and heat flow conditions. Classic monitoring strategies often rely on local and point-based measurements to monitor changes of underground temperature in time, with the limit of not succeeding in a whole delimitation of the Thermal Active Zone (TAZ). In this context, Electrical Resistivity Tomography (ERT) can bring relevant information on the temperature distribution for monitoring the induced thermal plume within BHEs (Borehole Heat Exchangers) systems. Geophysics helps the understanding of the thermal processes, in order to front the difficulties arising from Ground Source Heat Pumps (GSHP) implementation. Thermal conductivity and electrical resistivity depend equally in a complex way on different common subsurface and environmental attributes such as, among the main, mineralogical composition, grain size, density, porosity and saturation. Besides, thermal conductivity increases significantly with temperature in wet ground, by making it clear a relationship between both parameters.&lt;/p&gt;&lt;p&gt;ERT is particularly sensitive to the porous medium temperature and, when applied in time-lapse (TL), could provide spatially distributed information on the changes over time of water content, salinity or temperature. For this reason, in this work we monitored the complex TAZ temporal evolution during a heat injection experiment using a 3D time-lapse ERT survey, arranged in a reduced scale physical model. For a better understanding of measured electrical resistivity values, focused on mapping the extent of a geothermal plume around a borehole, a specific laboratory device was utilized. Grain size distribution, bulk density and saturation of the porous medium are known and established, as well as reliable temperature values acquired through sensors with which calibrate the ERT results. Thus, changes in resistivity can be interpreted to track the evolution of the plume of heated water and used to estimate the temperature change. The propagation of the heat plumes into the ground is also highly sensitive to interstitial water flow rate, thus also this condition was recreated and monitored varying the hydraulic gradient in the experimental device.&lt;/p&gt;&lt;p&gt;The present work aims to demonstrate the ability of ERT to provide complementary insights about the sub-surface spatio-temporal dynamic for monitoring the extension of TAZ caused by BHEs probes. In addition, the detailed scale adopted and the variable control within a laboratory setup ease the study of the interaction between thermal and electrical properties.&lt;/p&gt;


2011 ◽  
Vol 409 ◽  
pp. 550-554 ◽  
Author(s):  
B.T.F. Tang ◽  
Uwe Erb ◽  
I. Brooks

The work hardening behavior of electrodeposited nanocrystalline (grain size: 100 nm) and fully annealed polycrystalline nickel (grain size: 160 µm) was examined by hardness indentation analysis. First, plastic strain was introduced into the materials through large Rockwell hardness indentations. A series of Vickers micro-hardness traces below and away from the Rockwell indentation then measured the change in hardness as a function of distance from the plastic zone. The results showed that polycrystalline nickel exhibited considerable strain hardening, with micro-hardness values closest to the Rockwell indentation averaging twice the hardness value of the bulk material. On the other hand, for the nanocrystalline nickel the Vickers micro-hardness values changed only by a few percent indicating a limited strain hardening capacity.


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