Research on Smelting Vanadium Steel by Silicothermic Reduction Direct Alloying with V2O5

2012 ◽  
Vol 476-478 ◽  
pp. 164-169
Author(s):  
Wei Xiang Wang ◽  
Zheng Liang Xue ◽  
Sheng Qiang Song ◽  
Ping Li ◽  
Zhi Chao Chen

The basic thermodynamic analysis of silicothermic reduction during direct alloying to smelting vanadium steel with V2O5 was discussed in this paper. The high-temperature carbon tube furnace and medium frequency vacuum induction furnace were used to study the phase compositions of the reduction products and the change law of the yield of vanadium when V2O5 was reduced by ferrosilicon. The research shows that the main phases of the silicothermic reduction products were VSi2、FeVO4 and Ca2SiO4 under the condition of using CaO to restrain the volatile of V2O5. Yield of vanadium was gradually improved with the increase of ferrosilicon during the direct alloying. The yield of vanadium in the steel is as high as 95.25% when the addition of ferrosilicon is 35%.

2017 ◽  
Vol 62 (4) ◽  
pp. 2449-2453 ◽  
Author(s):  
G. Siwiec ◽  
P. Buliński ◽  
M. Palacz ◽  
J. Smołka ◽  
L. Blacha

AbstractThe paper presents analysis and assessment of operating power of vacuum induction furnace in relation to the efficiency of lead removal from Cu-Pb alloy in VIM (vacuum induction melting) technology. Thermodynamic analysis of the process is performed as well.


2013 ◽  
Vol 634-638 ◽  
pp. 3084-3087
Author(s):  
Bin Jie Jia ◽  
Ji Jun Wu ◽  
Wen Hui Ma ◽  
Yan Long Li

Removal of boron is one of the greatest barriers in the process of upgrading metallurgical grade silicon (MG-Si) to solar grade silicon (SoG-Si). In this work, a chloride molten salt was used as a new refining reagent for removal of boron from MG-Si. The theoretical supporting for chloride molten salt refining was studied by the thermodynamic analysis at first, which testified that boron could be volatilized and removed from MG-Si melt by generating the gaseous boron chloride species. Then the experiments for the removal of boron were carried out using the chloride molten salt with the different conditions of refining time and the ratio of chloride molten salt to MG-Si. The results showed that the boron content in refined silicon was successfully reduced from 22.0×10-6 to 3.0×10-6 in a medium frequency induction furnace at 1695 K for 2h.


2010 ◽  
Vol 638-642 ◽  
pp. 1348-1352
Author(s):  
Yoshitaka Iwabuchi ◽  
Isao Kobayashi

NiAl possesses the superior oxidation resistant and Ni3Al shows the good high temperature strength. Various castings with NiAl and Ni3Al were used in order to investigate the influence of Ni content on the properties. The heats were made by using vacuum induction furnace and its properties were evaluated. This article described the density, hardness, oxidation resistance, corrosion resistance and compression strength of the castings in comparison of other structural materials.


1951 ◽  
Vol 34 (5) ◽  
pp. 161-163 ◽  
Author(s):  
HAROLD T. SMYTH ◽  
ROBERT H. MEINKEN ◽  
LEONARD G. WISNYI

2013 ◽  
Vol 32 (4) ◽  
pp. 375-381
Author(s):  
Hong-guang Zheng ◽  
Li-jiang Yao ◽  
Heng Xu

AbstractThe solidification structure of two 500 g cylindrical ingots of Fe-36Ni invar alloy, which were melted in a carbon tube furnace and cast adding Ce and Zr-Ti refiners respectively, were investigated. The results showed that the grain size became smaller. With the increase of refiner content, the ratio of equiaxed grains of ingot increased and the equiaxed grain size decreased. As for the 100 kg flat ingot, which was melted in a vacuum induction furnace and cast with Ce and Zr-Ti refiners respectively, the situation was different slightly. When adding Ce the dendritic grain diameter of the flat ingot became finer and the equiaxed grain ratio remained low; however, the mechanical property deteriorated. While adding Zr-Ti complex refiners, the solidification structure of the alloy was improved dramatically. Therefore, the mechanical properties at room temperature of as-cast flat ingots were improved. Furthermore, its high temperature ductility range expanded and the expansion coefficient of its hot-rolling plate remained almost the same.


Vacuum ◽  
1952 ◽  
Vol 2 (1) ◽  
pp. 93
Author(s):  
H.T. Smyth ◽  
R.H. Meinken ◽  
L.G. Wisnyi

2018 ◽  
Vol 115 (2) ◽  
pp. 204
Author(s):  
Deng Ma ◽  
Wei Wu ◽  
Shifan Dai ◽  
Zhibin Liu

In this study, the feasibility of the carburization of vanadium-bearing hot metal was first investigated by thermodynamic analysis. Next, three carburizers, namely a low-nitrogen carburizer, anthracite, and coke, were used for carburization of 500 g of vanadium-bearing hot metal at 1450 °C, 1500 °C, and 1550 °C, respectively. The carbon increments for the low-nitrogen carburizer, anthracite and coke followed decreasing order in the temperature range from 1450 °C to 1550 °C. Anthracite was the most cost-effective carburizer. Hence, anthracite is used in pilot-scale experiments of the vanadium-bearing hot metal (100 kg and 200 kg). Finally, vanadium extraction experiments of the vanadium-bearing hot metal were carried out in a top-bottom-combined blowing induction furnace. It is proved that the average superheat degree of semi-steel increases from 100 °C to 198 °C by the carburization of vanadium-containing hot metal.


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