Carbon-Based Solar Cell from Amorphous Carbon with Nitrogen Incorporation

2012 ◽  
Vol 576 ◽  
pp. 785-788 ◽  
Author(s):  
A.N. Fadzilah ◽  
K. Dayana ◽  
Mohamad Rusop
Keyword(s):  
Solar Cell ◽  
Amorphous Carbon ◽  
Temperature Increase ◽  
Low Cost ◽  
Chemical Vapor ◽  
Device Structure ◽  
Electron Hole ◽  
Nitrogen Doped ◽  
Current Voltage ◽  
Electron Hole Pair

Nitrogen doped amorphous carbon (n-C:N) solar cells were successfully prepared using a simple and low cost Chemical Vapor Deposition (CVD) method using camphor oil as a precursor. Four samples of n-C:N were deposited by varying the deposition temperature (500oC, 550oC, 600oC, 650oC). The fabricated solar cell using n-C:N with the configuration of Au/n-C:N/p-Si/Au achieved an increasing efficiency as temperature increase (0.000202% to 0.001089%). As a reference, pure a-C was deposited at 500oC and exhibit 0.000048% efficiency. The current-voltage (I-V) graph emphasized on the linear graph (ohmic) for the a-C thin films, whereas for the p-n device structure, a rectifying curve was obtained. Electrical conductitivity possesses increasing value (1.69 x 10-2 to 22 Ω-1 cm-1) due to increasing sp2 ratio in a-C as temperature increase. The rectifying curves signify the heterojunction between the n-doped a-C film and the p-Si substrate and designate the generation of electron-hole pair of the samples under illumination. Photoresponse characteristics of the deposited a-C was highlighted when being illuminated (AM 1.5 illumination: 100 mW/cm2, 25oC) and optical band gap for the nitrogen doped a-C is reported from 0.75 eV to 0.25 eV as temperature increase.

Ti3C2-MXene/Bismuth Ferrite Nanohybrids for Efficient Degradation of Organic Dye and Colorless Pollutant

2019 ◽  
Author(s):  
Ayesha Tariq ◽  
M. Abdullah Iqbal ◽  
S. Irfan Ali ◽  
Muhammad Z. Iqbal ◽  
Deji Akinwande ◽  
...  
Keyword(s):  
Surface Area ◽  
Low Cost ◽  
Bismuth Ferrite ◽  
Organic Dye ◽  
Two Dimensional ◽  
Electron Hole ◽  
Photocatalytic Application ◽  
Electron Hole Pair ◽  
Pair Generation ◽  
Photocatalytic Applications

<p>Nanohybrids, made up of Bismuth ferrites/Carbon allotropes, are extensively used in photocatalytic applications nowadays. Our work proposes a nanohybrid system composed of Bismuth ferrite nanoparticles with two-dimensional (2D) MXene sheets namely, the BiFeO<sub>3</sub> (BFO)/Ti<sub>3</sub>C<sub>2</sub> (MXene) nanohybrid for enhanced photocatalytic activity. We have fabricated the BFO/MXene nanohybrid using simple and low cost double solvent solvothermal method. The SEM and TEM images show that the BFO nanoparticles were attached onto the MXene surface and in the inter-layers of two-dimensional (2D) MXene sheets. The photocatalytic application is tested for the visible light irradiation which showed the highest efficiency among all pure-BFO based photocatalysts, i.e. 100% degradation in 42 min for organic dye (Congo Red) and colorless aqueous pollutant (acetophenone) in 150 min, respectively. The present BFO-based hybrid system exhibited the large surface area of 147 m<sup>2</sup>g<sup>-1</sup>measured via Brunauer-Emmett-Teller (BET) sorption-desorption technique, and is found to be largest among BFO and its derivatives. Also, the photoluminescence (PL) spectra indicate large electron-hole pair generation. Fast and efficient degradation of organic molecules is supported by both factors; larger surface area and lower electron-hole recombination rate. The BFO/MXene nanohybrid presented here is a highly efficient photocatalyst compared to other nanostructures based on pure BiFeO<sub>3</sub> which makes it a promising candidate for many future applications.</p>

Low Cost Environmental Sensors Using Zinc Oxide Nanowires and Nanostructures

2012 ◽  
Vol 1439 ◽  
pp. 139-144 ◽  
Author(s):  
Nima Mohseni Kiasari ◽  
Saeid Soltanian ◽  
Bobak Gholamkhass ◽  
Peyman Servati
Keyword(s):  
Zinc Oxide ◽  
Metal Oxide ◽  
High Performance ◽  
Low Cost ◽  
Chemical Vapor ◽  
Environmental Sensors ◽  
X Ray Diffraction ◽  
Zinc Oxide Nanowires ◽  
Oxide Nanowires ◽  
Current Voltage

ABSTRACTZinc oxide (ZnO) nanowires (NW) are grown on both silicon and sapphire substrates using conventional chemical vapor deposition (CVD) system. As-grown nanostructures are characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) as well as energy dispersive spectroscopy (EDS) and the results confirm high-quality c-axis growth of single-crystalline zinc oxide nanowires. Nanowire are dispersed in solvent and then placed between micro-patterned gold electrodes fabricated on silicon wafers using low cost and scalable dielectrophoresis (DEP) process for fabrication of oxygen and humidity sensors. These sensors are characterized in a vacuum chamber connected to a semiconductor analyzer. Current-voltage characteristics of each device are systematically investigated under different hydrostatic pressure of various gaseous environments such as nitrogen, argon, dry and humid air. It is observed that the electrical conductivity of the nanowires is significantly dependent on the number of oxygen and water molecules adsorbed to the surface of the metal oxide nanowire. These results are critical for development of low cost metal oxide sensors for high performance ubiquitous environmental sensors of oxygen and humidity.

scholarly journals GaInP/GaAs three-terminal heterojunction bipolar transistor solar cell

2021 ◽  
Author(s):  
Marius Zehender ◽  
Simon Svatek ◽  
Myles Steiner ◽  
Ivan Garcia ◽  
Pablo Garcia-Linares ◽  
...  
Keyword(s):  
Solar Cell ◽  
Low Cost ◽  
Open Circuit ◽  
Bipolar Transistor ◽  
Heterojunction Bipolar Transistor ◽  
Power Extraction ◽  
Current Voltage ◽  
Double Junction ◽  
New Perspective ◽  
Interconnecting Layers

Abstract We demonstrate a heterojunction bipolar transistor solar cell (HBTSC), a device that exhibits the performance of a double-junction solar cell in a more compact npn (or pnp) semiconductor structure. The HBTSC concept has the advantages of being a three-terminal device, such as low spectral sensitivity and high tolerance to non-optimal band-gap energies, while it has a lower fabrication and operation complexity than other multi-terminal architectures: it can produce independent power extraction from the two junctions without the need for extra isolating or interconnecting layers between them. The two junctions in our proof-of-concept HBTSC prototype, which is made of epitaxial GaInP/GaAs, exhibit independent current-voltage characteristics under AM1.5G illumination, with respective open-circuit voltages of 1.33 and 0.95 V. The HBTSC opens a new perspective in the understanding of multi-junction devices, and it is an excellent candidate for the application of low-cost fabrication techniques, and for the implementation of III-V-on-silicon tandems.

Rapid Photo-Thermal Chemical Vapor Deposition of Amorphous Carbon From Diiodomethane

1999 ◽  
Vol 593 ◽  
Author(s):  
M. Lindstam ◽  
M. Boman ◽  
K. Piglmayer
Keyword(s):  
Electron Microscopy ◽  
Amorphous Carbon ◽  
High Efficiency ◽  
Low Cost ◽  
Substrate Surface ◽  
Chemical Vapor ◽  
Deposition Process ◽  
Substrate Material ◽  
Halogen Lamp ◽  
X Ray

ABSTRACTA novel approach to deposit amorphous carbon from the precursor CH2I2 at low cost and high efficiency is reported. The combination of thermal and quantum photo effects shows new interesting growth behaviour. The radiation of a halogen-lamp was used to heat the substrate material and to split photolytically the precursor molecules above the substrate surface. The deposition process was investigated as a function of lamp power, gas phase partial pressures and substrate materials. The films were analysed by Raman spectroscopy, scanning electron microscopy, energy dispersive x-ray spectroscopy, x-ray photon spectroscopy, transmission electron microscopy and atomic force microscopy.

Influence of Deposition Time on Amorphous Carbon Thin Films Performance with Aerosol-Assisted Chemical Vapor Deposition

2013 ◽  
Vol 832 ◽  
pp. 712-717
Author(s):  
A.N. Fadzilah ◽  
Dayana Kamaruzaman ◽  
Yosri M. Siran ◽  
M. Rejab Syahril Anuar ◽  
Ahmad Jaril Asis ◽  
...  
Keyword(s):  
Thin Films ◽  
Amorphous Carbon ◽  
Vapor Deposition ◽  
Deposition Time ◽  
Electrical Characterization ◽  
Chemical Vapor ◽  
Argon Atmosphere ◽  
Carbon Precursor ◽  
Solar Simulator ◽  
Current Voltage

Pure amorphous Carbon (a-C) thin films had been deposited by Aerosol-Assisted CVD (AACVD) onto glass substrate in Argon atmosphere. The camphor oil was chosen as the carbon precursor to prepare the a-C thin films with the deposition time of 15 minutes, 30 minutes, 45 minutes, 60 minutes and 75 minutes. The electrical, optical and structural properties of the deposited a-C were discussed by using the current-voltage solar simulator system, UV-Vis-Nir spectrophotometer and Raman spectroscope respectively. For the electrical characterization, the samples showed the photoresponse performance when being illuminated under AM 1.5 illuminations: 100 mW/cm2, 25°C. Transmittance value for the a-C thin films was also considered high ~80% and the structural analysis by using Raman spectroscope exhibit two main peaks known as the D-peak and G-peak which is typical for the a-C.

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