Corrosion Behavior of Ultra-Fine Grain Chromium Bronze Prepared by Equal-Channel Angular Pressing in HCl Solution

2013 ◽  
Vol 662 ◽  
pp. 258-261
Author(s):  
Ya Ni Zhang ◽  
Tian Han Xu ◽  
Dang Hui Wang

The corrosion resistance of Ultra-fine grain (UFG) chromium bronze, prepared by Equal-channel angular pressing (ECAP) processing, was investigated in HCl solution at room temperature and atmospheric pressure by electrochemistry technique and immersion experiment. The results shows that the corrosion potential of chromium bronze is decreased with ECAP processing. But the corrosion resistance is deteriorated slightly. According to the immersion tests, the weight-loss of UFG chromium bronze, compared with its counterpart, is higher in the initial stage and lower in the later stage, and the gap is in the range of 5%-15%. The corrosion mechanism on the UFG chromium bronze is deduced from the experiment data and corrosion morphology.

2011 ◽  
Vol 194-196 ◽  
pp. 554-557
Author(s):  
Ya Ni Zhang ◽  
Chang Zheng Xu ◽  
Mao Sheng Zheng ◽  
Jie Wu Zhu

The corrosion resistance of Ultra-fine grain (UFG) chromium bronze, prepared by Equal-channel angular pressing (ECAP), was investigated at room temperature and atmospheric pressure by electrochemistry technique and immersion experiment. The electrochemistry experiment showed that ECAP processing don’t change the corrosion nature of chromiun bronze, the corrosion potential of UFG chromium bronze is a little more positive than that of CG chromium bronze, the differences are in the range of 10mV-20mV. Meantime, the immersion experiment showed that the UFG chromium bronze is more resistant to corrosion than its CG counterpart. The difference between UFG chromium bronze and its CG counterpart is also significant in terms of corrosion morphology. Though the structure is uniform corrosion, the microstructure is honeycomb-like morphology for CG chromium bronze and the corrosion pit is deeper. The shallower corrosion pits are displayed for UFG chromium bronze and grain drop off in local region.


Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 607
Author(s):  
A. I. Alateyah ◽  
Mohamed M. Z. Ahmed ◽  
Yasser Zedan ◽  
H. Abd El-Hafez ◽  
Majed O. Alawad ◽  
...  

The current study presents a detailed investigation for the equal channel angular pressing of pure copper through two regimes. The first was equal channel angular pressing (ECAP) processing at room temperature and the second was ECAP processing at 200 °C for up to 4-passes of route Bc. The grain structure and texture was investigated using electron back scattering diffraction (EBSD) across the whole sample cross-section and also the hardness and the tensile properties. The microstructure obtained after 1-pass at room temperature revealed finer equiaxed grains of about 3.89 µm down to submicrons with a high density of twin compared to the starting material. Additionally, a notable increase in the low angle grain boundaries (LAGBs) density was observed. This microstructure was found to be homogenous through the sample cross section. Further straining up to 2-passes showed a significant reduction of the average grain size to 2.97 µm with observable heterogeneous distribution of grains size. On the other hand, increasing the strain up to 4-passes enhanced the homogeneity of grain size distribution. The texture after 4-passes resembled the simple shear texture with about 7 times random. Conducting the ECAP processing at 200 °C resulted in a severely deformed microstructure with the highest fraction of submicron grains and high density of substructures was also observed. ECAP processing through 4-passes at room temperature experienced a significant increase in both hardness and tensile strength up to 180% and 124%, respectively.


2013 ◽  
Vol 803 ◽  
pp. 226-229
Author(s):  
Da Ran Fang ◽  
Chun Liu ◽  
Feng Fang Liu

Al-3.9wt.%Cu alloy was subjected to equal channel angular pressing (ECAP) and subsequent low temperature annealing treatment, and the corrosion resistance of the samples was investigated by potentiodynamic polarization measurements in 3.5% NaCl solution. The results show that the corrosion rate of the ultrafine-grained alloy increases, in comparison with the coarse-grained alloy. Meanwhile, it is noted that the corrosion resistance of the alloy subjected to ECAP can be improved by relief annealing.


2006 ◽  
Vol 114 ◽  
pp. 91-96 ◽  
Author(s):  
Maxim Yu. Murashkin ◽  
M.V. Markushev ◽  
Julia Ivanisenko ◽  
Ruslan Valiev

The effects of equal channel angular pressing (ECAP), further heat treatment and rolling on the structure and room temperature mechanical properties of the commercial aluminum alloys 6061 (Al-0.9Mg-0.7Si) and 1560 (Al-6.5Mg-0.6Mn) were investigated. It has been shown that the strength of the alloys after ECAP is higher than that achieved after conventional processing. Prior ECAP solution treatment and post-ECAP ageing can additionally increase the strength of the 6061 alloy. Under optimal ageing conditions a yield strength (YS) of 434 MPa and am ultimate tensile strength (UTS) of 470 MPa were obtained for the alloy. Additional cold rolling leads to a YS and UTS of 475 and 500 MPa with 8% elongation. It was found that the post-ECAP isothermal rolling of the 1560 alloy resulted in the formation of a nano-fibred structure and a tensile strength (YS = 540 MPa and UTS = 635 MPa) that has never previously been observed in commercial non-heat treatable alloys.


2013 ◽  
Vol 423-426 ◽  
pp. 267-270
Author(s):  
Jian Hui Li ◽  
Zu Jian Yu ◽  
Da Zhi Xiao ◽  
Li Ping Zhang

To enhancing strength and toughness of metals, severe plastic deformation (SPD) grain refinement was a typical method. As one of the SPD method, equal channel angular pressing is an effective method in fabricating ultra-fine grain metallic materials. In this paper, the rigid-plastic finite element method was used to analyze the aluminum alloy ECAP processing, to reveal the material flow character and its effect on microstructure evolution. The simulation results were agreed with plastic mechanics and experiment well, and it was shown that distribution of maximum principal stress was not uniform, material located at the front-end of sample flow easily and material located at the top of die channel corner flow difficultly.


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