Chloride Ion Diffusion of Phosphoaluminate Cement Concrete

2009 ◽  
Vol 79-82 ◽  
pp. 99-102 ◽  
Author(s):  
Zhu Ding ◽  
Feng Xing ◽  
Ming Zhang ◽  
Peng Liu
Keyword(s):  
Portland Cement ◽  
Chloride Ion ◽  
Chloride Ions ◽  
Hydration Products ◽  
Portland Cement Concrete ◽  
Ion Diffusion ◽  
Cement Concrete ◽  
Dense Microstructure ◽  
Corrosion Of Steel ◽  
Chloride Ion Diffusion

Penetration and diffusion of chloride ions in concrete can lead to the corrosion of steel bar and shorten the service life of concrete structures. Phosphoaluminate cement (PAC) is a new cementitious material which has many special properties compared to Portland cement (PC). In the study, chloride ion diffusion in PAC concrete was tested with RCM method. The phase composition and morphology of hydration products, pore volume of hardened paste cured for 28d were analyzed with X-ray diffraction (XRD) and mercury intrusion porosimetry (MIP). The results show that chloride ion diffusion coefficient of PAC concrete is much lower than that of Portland cement concrete under the same test conditions. The hydration products of PAC are main micro-crystalline phase and gel of phosphate and/or phophoaluminate, which formed a dense microstructure. There is no calcium hydroxide produced in the PAC hydration system. In hardened PAC paste, chloride ions might replace the atom group [OH] - and [PO4]3- of hydrates and become stable compounds. The resistance to chloride ion diffusion of PAC concrete will increase with the hydration age, because its microstructure becomes denser with the hydration age increasing.

scholarly journals EVALUATION OF CONCRETE RESISTANCE TO CHLORIDE IONS PENETRATION BY MEANS OF ELECTRIC RESISTIVITY MONITORING

2005 ◽  
Vol 11 (2) ◽  
pp. 109-114 ◽  
Author(s):  
Marta Kosior-Kazberuk ◽  
Walery Jezierski
Keyword(s):  
Portland Cement ◽  
Salt Solution ◽  
Chloride Ion ◽  
Chloride Ions ◽  
Chloride Salt ◽  
Test Results ◽  
Ion Permeability ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Concrete Resistivity

The chloride‐induced corrosion of reinforcing steel is the major reason for the premature deterioration and degradation of field concrete structures built in a salt‐laden environment. The results of investigation of the bituminous addition effect on Portland cement concrete resistance to chloride ions penetration are presented in this paper. Chloride penetration was simulated by subjecting samples to cyclic loading with salt solution and drying. Concrete resistivity development was monitored during 12 months. The test results have been analysed to verify the effect of addition content, the time of exposure in aggressive environment, as well as the sort of cement on chloride ion permeability of Portland cement concrete. The statistical analysis showed that bituminous addition significantly improves the concrete resistance to chloride salt solution penetration.

Experimental Study on Mix Design of Chloride Resistant Cementitious Spacers

2014 ◽  
Vol 629-630 ◽  
pp. 351-357
Author(s):  
Chen Huang ◽  
Wen Ying Guo ◽  
Yi Bo Yang ◽  
Hui Zhao ◽  
Zhen Jie Li ◽  
...  
Keyword(s):  
Diffusion Coefficient ◽  
Design Method ◽  
Chloride Ion ◽  
Chloride Ions ◽  
Mix Design ◽  
Easy Access ◽  
Ion Diffusion ◽  
Electric Flux ◽  
Chloride Environment ◽  
Chloride Ion Diffusion

Chloride resistant HPC and protective cover are two basic measurements to improve the durability of concrete in chloride environment. Though it provides crucial cover for concrete to resist chloride ions, spacer has limited chloride resistant ability, which is overlooked by past researchers. Cementitious spacers are easy access for chloride ions to penetrate into concrete resulting in reduction of structural durability. To improve cementitious spacers’ performance, a systematic study was conducted. Test results showed that there was major difference between mortar and concrete in terms of chloride coulomb electric flux but minor difference in terms of chloride ion diffusion coefficient, which implied using chloride ion diffusion coefficient as spacer’s durability indicator was preferable; parameters of mix design had a similar influence on mortar and concrete and, with the same mixing parameters, the strength and chloride resistant ability of mortar were weaker than concrete’s; it was feasible to develop the mix design of chloride resistant cementitious spacers based on concrete’s design method with certain adjustments, such as using stricter mix proportion, adding small-size coarse aggregate, lowering water-binder ratio and optimizing the binder proportion, to achieve higher strength and durability.

scholarly journals Experimental Study on Chloride Ion Diffusion in Concrete under Uniaxial and Biaxial Sustained Stress

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5717
Author(s):  
Xiaokang Cheng ◽  
Jianxin Peng ◽  
C.S. Cai ◽  
Jianren Zhang
Keyword(s):  
Diffusion Coefficient ◽  
Compressive Stress ◽  
Stress Level ◽  
Chloride Concentration ◽  
Chloride Ion ◽  
Chloride Ions ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Ion Diffusion ◽  
Chloride Ion Diffusion

The existence of axial and lateral compressive stress affect the diffusion of chloride ions in concrete will lead to the performance degradation of concrete structure. This paper experimentally studied the chloride diffusivity properties of uniaxial and biaxial sustained compressive stress under one-dimensional chloride solution erosion. The influence of different sustained compressive stress states on chloride ion diffusivity is evaluated by testing chloride concentration in concrete. The experiment results show that the existence of sustained compressive stress does not always inhibit the diffusion of chloride ions in concrete, and the numerical value of sustained compressive stress level can affect the diffusion law of chloride ions in concrete. It is found that the chloride concentration decreases most when the lateral compressive stress level is close to 0.15 times the compressive strength of concrete. In addition, the sustained compressive stress has a significant effect on chloride ion diffusion of concrete with high water/cement ratio. Then, the chloride diffusion coefficient model under uniaxial and biaxial sustained compressive stress is established based on the apparent chloride diffusion coefficient. Finally, the results demonstrate that the chloride diffusion coefficient model is reasonable and feasible by comparing the experimental data in the opening literature with the calculated values from the developed model.

scholarly journals Influence of Pore Size and Fatigue Loading on NaCl Transport Properties in C-S-H Nanopores: A Molecular Dynamics Simulation

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 700 ◽  
Author(s):  
Qingyu Cao ◽  
Yidong Xu ◽  
Jianke Fang ◽  
Yufeng Song ◽  
Yao Wang ◽  
...  
Keyword(s):  
Diffusion Coefficient ◽  
Pore Size ◽  
Transport Properties ◽  
Diffusion Rate ◽  
Chloride Ion ◽  
Fatigue Loading ◽  
Chloride Ions ◽  
Water Molecules ◽  
Ion Diffusion ◽  
Chloride Ion Diffusion

The transport properties of chloride ions in cement-based materials are one of the major deterioration mechanisms for reinforced concrete (RC) structures. This paper investigates the influence of pore size and fatigue loading on the transport properties of NaCl in C-S-H nanopores using molecular dynamics (MD) simulations. Molecular models of C-S-H, NaCl solution, and C-S-H nanopores with different pore diameters are established on a microscopic scale. The distribution of the chloride ion diffusion rate and the diffusion coefficient of each particle are obtained by statistically calculating the variation of atomic displacement with time. The results indicate that the chloride ion diffusion rate perpendicular to C-S-H nanopores under fatigue loading is 4 times faster than that without fatigue loading. Moreover, the diffusion coefficient of water molecules and chloride ions in C-S-H nanopores increases under fatigue loading compared with those without fatigue loading. The diffusion coefficient of water molecules in C-S-H nanopores with a pore size of 3 nm obtained from the MD simulation is 1.794 × 10−9 m2/s, which is slightly lower than that obtained from the experiment.

scholarly journals Correlation between diffusion coefficient values of chloride ions obtained through column and ion migration tests in cementitious matrices with varying contents of silica fume and mortar

2022 ◽  
Vol 15 (3) ◽  
Author(s):  
Silas de Andrade Pinto ◽  
Sandro Lemos Machado ◽  
Daniel Véras Ribeiro
Keyword(s):  
Silica Fume ◽  
Coarse Aggregate ◽  
Chloride Ion ◽  
Chloride Ions ◽  
Transport Mechanisms ◽  
Ion Diffusion ◽  
Column Tests ◽  
Ion Migration ◽  
Chloride Migration ◽  
Chloride Ion Diffusion

Abstract Corrosion is one of the main phenomena that lead to pathological manifestations in reinforced concrete structures under aggressive environments. with the chloride ion being the most responsible for its occurrence. In this way, understanding the transport mechanisms of this ion through the microstructure of the concrete is of fundamental importance to prevent or delay the penetration of these aggressive agents to guarantee a durable structure. In the literature, there are extensive studies concerning the diffusion of chlorides in concrete and the influence of pozzolanic additions in this mechanism. However, only a few correlate the different methods of analysis. This work aims to determine the chloride ion diffusion coefficients in concrete containing various levels of silica fume (5%, 10%, and 15%) or varying the mortar content (54%, 80%, and 100%), and compares the results obtained through column tests and chloride migration tests. It was observed that, although the techniques used were quite distinct, the diffusion values obtained were similar, contributing to the validation of both techniques. Furthermore, the variation in the mortar ratio causes a reduction in the interfacial transition zone of coarse aggregate/mortars and an increase in the content of aluminates, which promotes a similar effect to the use of silica fume.

Development of Performance Specifications for Shrinkage of Portland Cement Concrete

2003 ◽  
Vol 1834 (1) ◽  
pp. 40-47 ◽  
Author(s):  
David W. Mokarem ◽  
Richard E. Weyers ◽  
D. Stephen Lane
Keyword(s):  
Portland Cement ◽  
Prediction Models ◽  
Drying Shrinkage ◽  
Chloride Ions ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Volume Changes ◽  
Code Model ◽  
Concrete Mixtures ◽  
Performance Specifications

During its service life, concrete experiences volume changes. One of the types of deformation experienced by concrete is shrinkage. There are four main types of shrinkage associated with concrete: plastic, autogenous, carbonation, and drying shrinkage. The volume changes in concrete from shrinkage can lead to the cracking of the concrete. In the case of reinforced concrete, cracks in the cover concrete provide a direct path for chloride ions to reach and corrode the reinforcing steel. The development of concrete drying-shrinkage performance specifications with an associated test procedure was assessed for concrete mixtures purchased by the Virginia Department of Transportation (VDOT). Five existing shrinkage-prediction models were also assessed to determine the accuracy and precision of each model as it pertains to the VDOT mixtures used in this study. The five models are the ACI 209 Code model, CEB90 Code model, Bazant B3 model, Gardner–Lockman model, and Sakata model. The percentage length change limits for the portland cement concrete mixtures were found to be 0.0300% at 28 days and 0.0400% at 90 days. The CEB90 Code model was judged as the best prediction model for the VDOT portland cement concrete mixtures.

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