A Study on Chemical Foaming Geopolymer Building Materials

2013 ◽  
Vol 853 ◽  
pp. 202-206 ◽  
Author(s):  
Tsung Yin Yang ◽  
Chuan Chi Chien

Zinc and aluminum powders were used as foaming agents and organosilane was innovatively used as a modifier to synthesize a foamed geopolymer. The produced foamed geopolymer with enhanced compressive strength and low thermal conductivity is an ideal material for fire protection, sound absorption and thermal insulation. The low thermal conductivity was achieved by increasing the porosity in the foamed geopolymer and the enhanced compressive strength was realized by adding the modifier. The pore numbers in the foamed geopolymer were greatly increased by releasing the hydrogen gas, which was produced from the chemical reaction of zinc and aluminum powders in a base solution. The modifier decreased the foaming reaction rate and generated homogeneously-distributed small pores in the foamed geopolymer with improved compressive strength.

Author(s):  
Viola Hospodarova ◽  
Nadezda Stevulova ◽  
Vojtech Vaclavik ◽  
Tomas Dvorsky ◽  
Jaroslav Briancin

Nowadays, construction sector is focusing in developing sustainable, green and eco-friendly building materials. Natural fibre is growingly being used in composite materials. This paper provides utilization of cellulose fibres as reinforcing agent into cement composites/plasters. Provided cellulosic fibres coming from various sources as bleached wood pulp and recycled waste paper fibres. Differences between cellulosic fibres are given by their physical characterization, chemical composition and SEM micrographs. Physical and mechanical properties of fibre-cement composites with fibre contents 0.2; 0.3and 0.5% by weight of filler and binder were investigated. Reference sample without fibres was also produced. The aim of this work is to investigate the effects of cellulose fibres on the final properties (density, water absorbability, coefficient of thermal conductivity and compressive strength) of the fibrecement plasters after 28 days of hardening. Testing of plasters with varying amount of cellulose fibres (0.2, 0.3 and 0.5 wt. %) has shown that the resulting physical and mechanical properties depend on the amount, the nature and structure of the used fibres. Linear dependences of compressive strength and thermal conductivity on density for plasters with cellulosic fibres adding were observed.


2020 ◽  
Vol 10 (4) ◽  
pp. 1314
Author(s):  
Haihua Wu ◽  
Kui Chen ◽  
Yafeng Li ◽  
Chaoqun Ren ◽  
Yu Sun ◽  
...  

The 3D graphite/ceramic composite prototyping parts directly prepared by selective laser sintering (SLS) were porous, which led to poor strength and low thermal conductivity. In order to obtain low thermal conductivity and high strength, its thermal conductivity and compressive strength were adjusted by changing the mixture powder composition and adding post-processing. The result showed that the addition of silicon powder in the mixture powder could significantly improve the compressive strength and thermal conductivity. The addition of expanded graphite was beneficial to the formation of the closed pores in the matrix, which slightly reduced the compressive strength but significantly reduced the thermal conductivity. The 3D graphite/ceramic composite part showed an order of magnitude improvement in compressive strength (from 1.25 to 13.87 MPa) but relatively small change in thermal conductivity (from 1.40 to 2.12 W·m−1K−1) and density (from 0.53 to 1.13 g·cm−3) by post-processing. Reasonable mixture powder composition and post-processing were determined and realized the possibility of fabricating a 3D graphite/ceramic composite part with low thermal conductivity but high compressive strength. Furthermore, it could be used for the repeated casting of steel castings, and through the comparative analysis of casting defects, the prepared graphite/ceramic composite part was expected to replace water glass sand mold.


2016 ◽  
Vol 7 (15) ◽  
pp. 2759-2764 ◽  
Author(s):  
Gaigai Duan ◽  
Shaohua Jiang ◽  
Tobias Moss ◽  
Seema Agarwal ◽  
Andreas Greiner

Ultralight hydrophobic polymer sponges with enhanced compressive strength prepared by electrospinning and PPX coating showed tuneable density, compression strength, and water contact angle, and low thermal conductivity. On holding a piece of such a sponge in hand, one does not feel the cold from dry ice.


Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1199 ◽  
Author(s):  
Marie Viel ◽  
Florence Collet ◽  
Sylvie Prétot ◽  
Christophe Lanos

In order to meet the requirement of sustainable development, building materials are increasingly environmentally friendly. They can be partially or fully bio-based or recycled. This paper looks at the development of fully bio-based composites where agro-resources are valued as bio-based aggregates (hemp) and as binding materials (wheat). In a previous work, a feasibility study simultaneously investigated the processing and ratio of wheat straw required to ensure a gluing effect. In this paper, three kinds of hemp-straw composites are selected and compared with a hemp-polysaccharides composite. The gluing effect is analyzed chemically and via SEM. The developed composites were characterized multi-physically. They showed sufficiently high mechanical properties to be used as insulating materials. Furthermore, they showed good thermal performances with a low thermal conductivity (67.9–69.0 mW/(m · K) at 23 ° C, dry).


2011 ◽  
Vol 99-100 ◽  
pp. 1117-1120 ◽  
Author(s):  
Mao Quan Xue

As new building materials, plastic has light weigh, corrosion resistance, low thermal conductivity, thermal insulation, waterproof, energy-saving, molding convenient, high recycling characteristic, widely used in building materials. According to the research of improving its flame retardancy, strength, thermal insulation, waterproof properties, the application of plastic use in doors and windows, pipeline, building walls and roofs of buildings, etc. were reviewed, and the developing direction was discussed.


2016 ◽  
Vol 8 (1) ◽  
pp. 31-40 ◽  
Author(s):  
Jurga Šeputytė-Jucikė ◽  
Marijonas Sinica

The main objective of this study is to create a lightweight aggregate concrete (LWAC) with a low thermal conductivity coefficient using expanded glass (EG) aggregate, produced from waste glass or crushed expanded polystyrene waste, obtained by crushing waste packing tare of household appliances. Research related to the effects of the amount of Portland cement (PC) as well as EG aggregates and crushed expanded polystyrene waste on physical (density, thermal conductivity coefficient, water absorption and capillary coefficient) and mechanical (compressive strength) properties of LWAC samples are provided. Insulating LWAC based on a small amount of PC and lightweight EG aggregates and crushed expanded polystyrene waste, with especially low thermal conductivity coefficient values (from 0.070 to 0.098 W/ (m·K)) has been developed. A strong relationship between thermal conductivity coefficient and density of LWAC samples was obtained. The density of LWAC samples depending on the amount of PC ranged between 225 and 335 kg/m3. A partial replacement of EG aggregate by crushed expanded polystyrene waste, results in relative density decrease of LWAC samples. In LWAC samples the increased amount of PC results in increased compressive strength.


Author(s):  
Mauricio H. Cornejo ◽  
Jan Elsen ◽  
Bolivar Togra ◽  
Haci Baykara ◽  
Guillermo Soriano ◽  
...  

Mordenite-rich tuff is one of most available zeolitic rocks all over the world. Because of this, the research of natural mordenite as a raw material of geopolymeric materials can provide an almost unlimited source of solid precursor for manufacturing such building materials. Despite efforts to shed light on the behaviour of mordenite-rich tuff during geopolymeric reaction, the performance of these novel materials is barely understood. The aim of this study is to explore the effect of the content of calcium hydroxide, CH, and water-to-solid ratio, W/S, as mixing parameters on compressive strength of mordenite-based geopolymers, MBG, and its thermal conductivity. As solid precursor was used mordenite-rich tuff and mixed with sodium hydroxide (NaOH) at 10M that kept constant during the experiment. Two experimental parameters were selected as independent variables i.e, the content of CH and water-to-solid ratio, and their levels, according to a central composite experimental design. All these designed mixes were characterized by using quantitative X-ray diffraction (QXRD), Fourier Transform Infrared spectroscopy (FTIR), Thermogravimetry and differential scanning calorimetry (TGA-DSC), scanning electron microscopy coupled with energy dispersed spectroscopy (SEM-EDS), in addition thermal conductivity tests were also run according to standard method ASTM C177 at 9, 24, 39°C. The overall results suggested that MBG can be used as building material, however its thermal conductivity was higher than that of commercial isolate building material. The experimental design analysis indicated that the optimum water-to-solid ratio was 0.35, but in the case of the content of CH, the optimum value was not observed on this experimental range because the compressive strength increased as the content of CH increased as well. The compressive strength of MBG was observed in the range between 8.7 and 11.3 MPa. On the other hand, QXRD and FTIR showed that mordenite reacted during the geopolymeric reaction, but instead quartz, also found in zeolitic tuff, acted as inert filler.


2013 ◽  
Vol 357-360 ◽  
pp. 1441-1445
Author(s):  
Xiao Lin Li ◽  
Zheng Fang ◽  
Dong Ji ◽  
Zhi Dong Wan ◽  
Kai Guo

The synthesis of a novel class of diamine-based polyols derivatives and the potentials and the limitations of these polyols were reported. This class of diamine-based polyols with high hydroxyl values and no acid values can be used in rigid polyurethane foams. The prepared rigid foams show the properties of low density, high closed cell content, low thermal conductivity, and high compressive strength.


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