Dissolution Resistance of Bovine Teeth-Derived Hydroxyapatite

2010 ◽  
Vol 97-101 ◽  
pp. 2257-2260
Author(s):  
Dong Seok Seo ◽  
Kyu Hong Hwang ◽  
Hwan Kim ◽  
Jong Kook Lee

Dissolving behavior of hydroxyapatite ceramics prepared from bovine teeth (BTHA) was investigated. The bovine teeth were soaked in 0.1 M of NaOH at 80°C for 1 h. After soaking, the teeth were calcined at 800°C for 1 h, and then they were attritor-milled for 24 h. BTHA powder consisted of mainly HA and small amount of MgO. The powders obtained were cold isostatically pressed and sintered at 1200°C with a dwell time of 1 h. Sintered density of BTHA was about 70%. After polishing the surface of sintered specimen, BTHA was immersed in buffered water at 37°C for 3 and 7 days. After immersion period, there is no evidence of dissolution for BTHA at the end of the immersion time. In addition, there is no change of peak intensity in XRD after immersion time. It was found that hydroxyapatite from bovine teeth was more stable than commercial HA in liquid environment.

2011 ◽  
Vol 488-489 ◽  
pp. 428-431
Author(s):  
Dong Seok Seo ◽  
Kyu Hong Hwang ◽  
Jong Kook Lee

Mechanical degradation of hydroxyapatite ceramics due to the slow crack growth was observed in water. Microstructural crack on the surface of hydroxyapatite initiated by grain boundary dissolution in liquid environment resulting in particle loosening and microstructural-level degradation, followed by a drastic decrease of mechanical properties. In this study, slow crack growth by the dissolution behavior of hydroxyapatite ceramics was investigated based on microstructural observation by field emission microscopy. The crack growth and morphological change of hydroxyapatite surface, especially at the initial stage of dissolution and related surface roughness were observed with immersion time. The surface dissolution occurred from the initial stage of immersion showing increase in surface roughness. Following certain period of immersion time, the surface dissolution initiated at grain boundaries and generated many separated grains.


2010 ◽  
Vol 97-101 ◽  
pp. 2261-2264
Author(s):  
Dong Seok Seo ◽  
Yong Gook Kim ◽  
Jong Kook Lee

Hydroxyapatite (HA) ceramics derived from tuna bone (THA) was prepared and their mechanical property was investigated with immersion in buffered water. Tuna bones were soaked in 0.1 M of NaOH solution at 80°C for 1 h. After soaking, the bones were calcined at 800°C for 1 h to completely remove organic, and then attritor-milled for 24 h. The powders obtained were cold isostatically pressed and sintered at 1300°C with a dwell time of 1 h. Sintered densities of the THA was about 93%. After polishing, the THA were immersed in buffered water at 37 °C for 3 and 7 days. The THA ceramics consisted of HA and small amount of magnesium oxide. Immersion test revealed that there was no clear evidence of dissolution for the THA which sintered at high temperatures. Vickers hardness test showed that the hardness value of THA ceramics was not changed with immersion time indicating that dense hydroxyapatite from tuna bone was stable in liquid environment.


2013 ◽  
Vol 686 ◽  
pp. 44-48 ◽  
Author(s):  
Noor Faeizah Amat ◽  
Andanastuti Muchtar ◽  
Norziha Yahaya ◽  
Mariyam Jameelah Ghazali

This study aims to evaluate the effects of sintering temperature on the density and hardness of tetragonal zirconia polycrystals stabilized with 3 mol% 3Y-TZP dental ceramic type. Five cylindrical specimens were fabricated from zirconia powder of particle size 50 nm via colloidal processing. The specimens were sintered densely at the final sintering temperatures of 1000, 1100, 1200, and 1300 °C, respectively. The sintered density and hardness of the sintered specimen were then examined. The results showed that the sintered densities and hardness of the specimen increased as the temperature increased from 1000 °C to 1300 °C. Zirconia 3Y-TZP could gain near full density and reach hardness of as high as 11.30 GPa at the final sintering temperature of 1300 °C. The density and hardness of zirconia structured from 3Y-TZP can be improved by controlling the final sintering temperature.


2013 ◽  
Vol 842 ◽  
pp. 104-109
Author(s):  
Yan Zou ◽  
Qiang Bai ◽  
Jia Wang ◽  
Wei Wang ◽  
Xiang Feng Kong

The galvanic and potential distributions of carbon steel immersed in seawater were studied by wire beam electrode (WBE) technique. Results indicated that the corrosion of carbon steel in seawater tended to local corrosion. With immersion time increasing, local corrosion was more and more serious. During the initial immersion period, the top of the coupon near the water surface was main cathode. With the corrosion extended, corrosion products gradually gathered on the surface of the carbon steel. Potential differences between cathode and anode gradually became small. Cathode and anode redistributed on the surface of carbon steel. At last, the top and the bottom were cathode while the middle was anode. The areas of anode first increased and then decreased. The areas of cathode were in contrast.


2012 ◽  
Vol 488-489 ◽  
pp. 592-596
Author(s):  
Jong Kook Lee ◽  
Heong Jun Kim ◽  
Woo Yang Jang

Hydroxyapatite (HA) ceramics were prepared from the bone ash which is mostly used as animal feeds or raw materials. Dissolving behaviors of the HA in buffered water were investigated and compared with commercial HA for further use as biomaterials. HA ceramics were prepared by soaking the bone ash in 0.1 M of NaOH solution at 80°C for 4 h. The ash was calcined at 800°C for 1 h to completely remove organics, and then sintered at 1200°C for 1 h under moisture protection. The bone ash derived-HA consists of mostly HA and small amounts of α-tricalcium phosphate, calcium oxide phosphate, magnesium oxide and calcium oxide. After polishing the HA ceramics, they were immersed in buffered water at 37°C for 3 and 7 days. We previously found that grain boundaries of synthetic HA were intensively dissolved in buffered water. On the other hand, the bone ash derived-HA shows high stability in liquid environment with immersion time compared with commercial HA.


2020 ◽  
Vol 321 ◽  
pp. 03016
Author(s):  
Masashi Hayakawa ◽  
Hideki Fujii ◽  
Matsuhide Horikawa ◽  
Yosuke Inoue ◽  
Masahiro Morita

To narrow down the candidates of the alloying element powders for Ti-5Al-1Fe products manufactured with BE/PM, two master alloy powders, atomized spherical 5Al-1Fe and crushed-andground polyhedron 5Al-1Fe-4Ti ternary powders, were investigated with emphasizing on homogeneity of alloying elements, Al and Fe, in sintered Ti-5Al-1Fe. Intense Al segregation is recognized in the sintered specimen manufactured using 5Al-1Fe atomized powders, while strong segregation is not observed in the specimen manufactured using 5Al-1Fe-4Ti crushed-and-ground powders. Density of sintered specimen manufactured using 5Al-1Fe atomized powders is lower than that manufactured using 5Al-1Fe-4Ti crushed-and-ground powders. Al segregation and lower sintered density are probably caused by lower density of the powder substance, high flowability of spherical powders and phase constitutions some of which have low melting points. Those factors have to be taken into account to manufacture sintered titanium alloys with high homogeneity by BE/PM.


HortScience ◽  
2005 ◽  
Vol 40 (6) ◽  
pp. 1846-1849 ◽  
Author(s):  
Thomas H. Boyle ◽  
Kristen Hladun

A series of experiments was performed to examine the germination responses of Baptisia australis (L.) R. Br. seeds. Germination tests were conducted at 23 °C and numbers of germinated seed were counted daily for 21 days. Seeds were separated into two size fractions using standard sieves. Seeds in the large-seeded fraction were heavier than those in the small-seeded fraction, but seed size/weight did not affect the germination percentage at 21 days (G21), the number of days to 50% of final germination (T50), or the number of days between 10% and 90% germination (T90 – T10). Seeds were classified into two groups based on testa color. Light-brown seeds (17% of total) were heavier and had lower G21 and higher T50 and T90 – T10 values than medium- to dark-brown seeds (83% of total). Seeds scarified mechanically germinated nearly 100% and had lower T50 and T90 – T10 values than untreated seeds. Untreated seeds had a higher T50 value than seeds soaked overnight in 20°C water, but the G21 and T90-T10 values were similar for the two treatments. Mechanical scarification followed by overnight soaking in 20 °C water yielded a G21 value of only 12%, and the low germination percentage was attributed to imbibition damage. When seeds were scarified in concentrated H2SO4 for 0, 1, 5, 20, 40, or 80 min, G21 values increased quadratically while T50 and T90 – T10 values decreased quadratically as the immersion time increased. To test the effects of moist heat on germination responses, seeds were immersed for 0, 0.5, 1, 2, 4, or 8 minutes in 85 °C water. G21 values increased linearly as the immersion period increased from 0 to 2 min but remained similar when the immersion time exceeded 2 min. The duration of immersion in hot water did not affect the T50 values whereas T90 – T10 values decreased linearly as the immersion period increased. We conclude that physical dormancy is responsible for temporal variation in germination of B. australis seeds. Scarifying seed in concentrated H2SO4 for 20 to 80 minutes may be the most practical means of treating bulk lots of B. australis seeds to obtain rapid and uniform (≥85%) germination.


2020 ◽  
Vol 27 (3) ◽  
Author(s):  
Yosi Kusuma Eriwati ◽  
◽  
Muhammad Dhiaulfikri ◽  
Ellyza Herda ◽  
◽  
...  

The influence of immersion period and liquid pH on water absorption capacity and solubility of the resin-modified glass ionomer cement (RMGIC) raises the question of whether the critical pH of hydroxyapatite and fluoroapatite influences the water absorption capacity and solubility of enhanced resin-modified glass ionomer (ERMGI). Objective: This study was designed to investigate the effects of immersion periods and various pH levels of artificial saliva on the water absorption and solubility of RMGIC and ERMGI. Methods: Fifty-four disc-shaped specimens (15 mm x 1 mm) of enhanced RMGI (ACTIVATM BioACTIVE-RESTORATIVE, Pulpdent, Watertown, MA, USA) and 54 disc-shaped specimens (15 mm x 1 mm) of RMGIC (Fuji II LC Capsules, GC Corp, Tokyo, Japan) were prepared. Both materials were divided into 9 groups based on artificial saliva pH (pH 7, pH 5.5, and pH 4.5) and immersion time (1, 7, and 14 days). Water absorption and solubility were measured based on ISO 4049: 2009. Data were analyzed statistically using one-way ANOVA. Results: The results showed significant differences in water absorption and solubility value between RMGIC and enhanced RMGI for all the groups. Both materials showed increased water absorption and solubility when immersed in artificial saliva that exhibited a lower pH level and under higher immersion period. Conclusion: Lower pH levels and longer immersion time influence the water absorption and solubility of enhanced RMGI and RMGIC.


2011 ◽  
Vol 493-494 ◽  
pp. 49-54 ◽  
Author(s):  
George S. Polymeris ◽  
Ourania Menti Goudouri ◽  
Konstantinos M. Paraskevopoulos ◽  
George Kitis

Results of the present study provide strong indications towards the effective application of the 110oC Thermoluminescence (TL) peak in discriminating between different bioactive responses for the case of the 58S bioactive glass. The in vitro bioactivity of this glass in the form of powder in SBF solution was tested for various immersion times, ranging between 0 and 6 days. This TL peak is ubiquitously present in all 58S samples, for all immersion times. The intensity of the110oC TL peak was proven to be very sensitive to the different bioactive responses, indicating a strongly decreasing pattern with increasing immersion time in SBF, easily identifying thus the loss of silica. This loss is reflected to the decrease of the 110oC TL peak intensity, which appears to be fast even for the shorter immersion times. The 110oC TL glow peak intensity and sensitization could also be yielding a time scale regarding the beginning of some among the several stages included in the bioactivity sequence.


Author(s):  
Jussara Cristina Firmino Da Costa ◽  
Rejane Maria Nunes Mendonça ◽  
Gerciane Cabral Da Silva ◽  
Silvanda De Melo Silva ◽  
Walter Esfrain Pereira ◽  
...  

In the rhizogenic process, the immersion time of the base of the cuttings to be propagated in plant regulators depends on the concentration of the solutions, the cultivar to be used and the type of cutting required. Therefore, this research work has as objective to investigate which immersion time, in solution with indolebutyric acid promotes a greater rooting in herbaceous cuttings of guava cultivar Século XXI. The experiment was distributed in the completely randomized design, being defined as treatments the immersion times (5, 10, 15 and 20 seconds) of the base of the cuttings in the solution of indolebutyric acid - IBA at the concentration of 2000 mg L-1, with three replicates and 10 cuttings per plot. In relation the variable dry mass of the aerial part, this presents a favorable response to the different immersion times in indolebutyric acid. Diverging of the variables cuttings rooted, live without root, number of roots, root length, callus, sprout, leaf retention and mortality which were not influenced by the different immersion times of the base of the cuttings in the plant regulator. Concluding that the different times of immersion of the base of the cuttings do not influence in the rhizogenic process of herbaceous cuttings of guava cultivar Século XXI. For the variable dry mass of aerial part, the immersion time of 5 seconds in the concentration of 2000 mg L-1 in AIB, present the better results when compared to the other concentrations.


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