Investigating the Pitting Resistance of 316 Stainless Steel in Ringer's Solution Using the Cyclic Polarization Technique

2013 ◽  
Vol 344 ◽  
pp. 1-7 ◽  
Author(s):  
Muhammad Kamran ◽  
F. Hussain ◽  
R. Ahmad ◽  
Tahir Ahmad ◽  
Fahad Riaz

Corrosion rate, corrosion potential and susceptibility to pitting corrosion of a metal are measured using cyclic polarization Direct Current (DC) electrochemical technique. The aim of the present research is to investigate the pit nucleation resistance of polished, ground and passivated surfaces of 316 stainless steels in Ringers solution. The electrochemical cyclic polarization results showed that polished surface gave better pitting resistance as compared to ground surface. It was also observed that passivation treatment gave better pitting resistance to both polished and ground surface of 316 stainless steels in Ringers solution.

Wear ◽  
2006 ◽  
Vol 261 (9) ◽  
pp. 987-993 ◽  
Author(s):  
A. Berradja ◽  
F. Bratu ◽  
L. Benea ◽  
G. Willems ◽  
J.-P. Celis

Metals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 686 ◽  
Author(s):  
Asunción Bautista ◽  
Francisco Velasco ◽  
Manuel Torres-Carrasco

The durability of two lean corrugated duplex stainless steel (UNS S32304 and S32001) bars manufactured for concrete reinforcement was studied in four different corrosive conditions. These duplex stainless steels are more economical than the most traditional, well-known duplex grade steels (UNS S32205). The research was carried out in mortar samples for six years. In half of the samples, the alkaline reserve had been previously decreased, and their pH was slightly below 12, while in the other half, the pH close to the bars remained as-manufactured. Moreover, there were samples with modified and non-modified alkaline reserve where chlorides had been previously added to the mortar which were exposed to high relative humidity. In other samples—which were partially immersed in 3.5% NaCl—the chlorides entered through the mortar by natural diffusion. The electrochemical behavior of the reinforcements in these conditions was periodically monitored through corrosion potential (Ecorr) and electrochemical impedance spectroscopy (EIS) measurements during the whole testing period. The samples were anodically polarized at the end of the exposure. The results prove that the decrease in the alkaline reserve of the mortars can affect the corrosion behavior of the studied lean duplex in environments with high chloride concentrations. The duplex microstructure of the reinforcements makes it so that the corrosion proceeds by selective attack of the phases.


Metals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1248
Author(s):  
Marc Vankeerberghen ◽  
Michel De Smet ◽  
Christian Malekian

We performed environmental fatigue testing in simulated primary water reactor (PWR) primary water and reference fatigue testing in air in the framework of an international, collaborative project (INCEFA-PLUS), where the effects of mean strain and stress, hold time, strain amplitude and surface finish on fatigue life of austenitic stainless steels in light water reactor environments are being studied. Our fatigue lives obtained on machined specimens in air at 300 °C lie close to the NUREG/CR6909 mean air fatigue curve and are in line with INCEFA-PLUS air fatigue lives. Our environmental fatigue lives obtained in simulated PWR primary water at 300 °C lie relatively close to the NUREG/CR6909 mean fatigue curve; derived from the NUREG/CR6909 mean air fatigue curve and the applicable environmental correction factor (Fen). The PWR results show that (1) a polished surface finish has a slightly higher and a ground surface finish a slightly lower fatigue life than the NUREG/CR6909 prediction; (2) the ratio of polished to ground specimen life is ~1.37 at 300 °C and ~1.47 at 230 °C; (3) holds—at zero strain after a positive strain-rate—have a slightly detrimental effect on fatigue life. These results are in line with the INCEFA-PLUS PWR fatigue lives. A novel gauge-strain extensometer was deployed in order to perform a true gauge-strain-controlled fatigue test in simulated PWR primary water.


Author(s):  
Thomas Métais ◽  
Andrew Morley ◽  
Laurent de Baglion ◽  
David Tice ◽  
Gary L. Stevens ◽  
...  

Additional fatigue rules within the ASME Boiler and Pressure Vessel Code have been developed over the past decade or so, such as those in Code Case N-792-1 [1], which provides an acceptable method to describe the effects of BWR and PWR environments on the fatigue life of components. The incorporation of environmental effects into fatigue calculations is performed via an environmental factor, Fen, and depends on factors such as the temperature, dissolved oxygen and strain rate. In the case of strain rate, lower strain rates (i.e., from slow transients) aggravate the Fen factor which counters the long-held notion that step (fast) transients cause the highest fatigue usage. A wide range of other factors, such as surface finish, can have a deleterious impact on fatigue life, but their impact on fatigue life is typically considered by including transition sub-factors to construct the fatigue design curve from the mean behavior air curve rather than in an explicit way, such as the Fen factor. An extensive amount of testing and evaluation has been conducted and reported in References [2] [3] [4] [5] [6] [7] and [8] that were used to both revise the transition factors and devise the Fen equations contained in Code Case N-792-1. The testing supporting the definition of Fen was performed on small-scale laboratory specimens with a polished surface finish on the basis that the Fen factor is applicable to the design curve without any impact on the transition factors. The work initiated by AREVA in 2005 [4] [5] [6] suggested, in testing of austenitic stainless steels, an interaction between the two aggravating effects of surface finish and PWR environment on fatigue damage. These results have been supported by testing carried out independently in the UK by Rolls-Royce and AMEC Foster Wheeler (now Wood Group) [7], also on austenitic stainless steels. The key finding from these investigations is that the combined detrimental effects of a PWR environment and a rough surface finish are substantially less than the sum of the two individual effects. These results are all the more relevant as most nuclear power plant (NPP) components do not have a polished surface finish. Most NPP component surfaces are either industrially ground or installed as-manufactured. The previous studies concluded that explicit consideration of the combined effects of environment and surface finish could potentially be applicable to a wide range of NPP components and would therefore be of interest to a wider community: EDF has therefore authored a draft Code Case introducing a factor, Fen-threshold, which explicitly quantifies the interaction between PWR environment and surface finish, as well as taking some credit for other conservatisms in the sub-factors that comprise the life transition sub-factor used to build the design fatigue curve . The contents of the draft Code Case were presented last year [9]. Since then, other international organizations have also made progress on these topics and developed their own views. The work performed is applicable to Austenitic Stainless Steels only for the time being. This paper aims therefore to present an update of the draft Code Case based on comments received to-date, and introduces some of the research and discussions which have been ongoing on this topic as part of an international EPRI collaborative group on environmental fatigue issues. It is intended to work towards an international consensus for a final version of the ASME Code Case for Fen-threshold.


Scanning ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Kewei Fang ◽  
Chengtao Li ◽  
Shuai Dong ◽  
Dubao Zhang ◽  
Xiangfeng Wu ◽  
...  

The corrosion behaviors of A106B carbon steel and 304L stainless steel (SS) in seawater with different Cu2+ concentrations were studied by the immersion test and the potentiodynamic polarization test. The results showed that with the increasing Cu2+ concentration, the mass lot rates of A106B and 304L SS all increased in the immersion test, and compared with A106B, the mass lot rates of 304L SS were all smaller. In the potentiodynamic polarization test, following the concentration of Cu2+ increased, the corrosion potential of A106B firstly shifted negatively; then, when Cu2+ increased to 100 ppm, the polarization curve moved to the upper right direction; namely, both the corrosion potential and corrosion electrical density increased. The corrosion potential of 304L SS increased with the increasing Cu2+, and the passive region was reduced; the pitting sensitivity improved.


2018 ◽  
Vol 10 (10) ◽  
pp. 3677 ◽  
Author(s):  
Andrzej Bak ◽  
Violetta Kozik ◽  
Paulina Dybal ◽  
Slawomir Kus ◽  
Aleksandra Swietlicka ◽  
...  

The sulfur-containing derivatives and their metabolites, regarded as ‘old devils of green’ chemistry, constitute a relevant class of air/water/soil contaminants in over-polluted world. In fact, some industrially-engineered solvents have become environmentally unfavorable. An attractive alternative to commonly used industrial liquids is sulfolane (C4H8SO2), an anthropogenic medium. The main objective of this paper is the comprehensive review focusing mainly on the state-of-the-art aspects of the sulfolane synthesis, application of sulfolane as an extractive solvent due to its ‘unique’ physicochemical properties as well as the potential of sulfolane to cause equipment corrosion and subsequent spills. The potential risk for groundwater contamination, danger for human health and ways of sulfolane biodegradation were briefly reviewed as well. Interestingly, the analysis performed on data stored in the Reaxys database revealed an alternating tendency of waxing and waning interest in sulfolane during the space of the last fifty years. Moreover, the primary goal of the presented case study was to verify applicability of industrial, multi-electrochemical technique for reliable detection of corrosion in low conductive process fluids. Several aspects of corrosion measurement including the impact of process parameters (temperature) and impurities (oxygen and chlorides) on stainless steel corrosion in pure sulfolane were investigated briefly.


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