Development of New Polymers from Thevetia peruviana Oil

2020 ◽  
Vol 48 ◽  
pp. 9-23 ◽  
Author(s):  
Adebayo F. Owa ◽  
Isiaka O. Oladele ◽  
Adeolu Adesoji Adediran ◽  
Joseph A. Omotoyinbo
Keyword(s):  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Cationic Polymerization ◽  
Boron Trifluoride ◽  
Seed Oil ◽  
Polymeric Materials ◽  
Boron Trifluoride Etherate ◽  
Elongation At Break ◽  
Synthesized Materials ◽  
The Impact

Three novel bio-polymers were synthesized by cationic polymerization of Thevetia peruviana seed oil with styrene and divinylbenzene using modified boron trifluoride etherate as initiator. The cured thermosets ranging from soft to hard, were found to contain between 74.8 to 85.5 % cross linked materials with crosslink densities ranging from 1.33 x 103 to 1.84 x 103 mol/m3. The ultimate tensile strength of the materials varied from 0.52 to 0.55 Mpa, the young moduli is between 38.4 to 53.9 Mpa, the elongation at break varied from 55 to 64 %, the density of the polymers ranged between 0.850 to 0.866 gcm-3, the impact strength is between 2.31 to 2.81 J, while hardness ranged between 3.40 to 3.90 BHN. Overall, the newly synthesized materials from Thevetia peruviana oil have many potentials as new polymeric materials.

scholarly journals The Impact of Slicing Softwares on the Mechanical Properties of 3D Printed Parts

2020 ◽  
Vol 9 (2) ◽  
pp. 487-494
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
3D Printer ◽  
Stl File ◽  
3D Printed ◽  
Intersection Curves ◽  
The Impact

“Slicing tool” or “Slicing Software” computes the intersection curves of models and slicing planes. They improve the quality of the model being printed when given in the form of STL file. Upon analyzing a specimen that has been printed using two different slicing tools, there was a drastic variation on account of the mechanical properties of the specimen. The ultimate tensile strength and the surface roughness of the material vary from one tool to another. This paper reports an investigation and analysis of the variation in the ultimate tensile strength and the surface roughness of the specimen, given that the 3D printer and the model being printed is the same, with a variation of usage of slicing software. This analysis includes ReplicatorG, Flashprint as the two different slicing tools that are used for slicing of the model. The variation in the ultimate tensile strength and the surface roughness are measured and represented statistically through graphs. An appropriate decisive conclusion was drawn on the basis of the observations and analysis of the experiment on relevance to the behavior and mechanical properties of the specimen.

Mechanical Properties of Herbal Patches from Chitosan-Based Polymer Blends for Medical Applications

2018 ◽  
Vol 917 ◽  
pp. 52-56
Author(s):  
Jirapornchai Suksaeree
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Polymer Blends ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Hydroxypropyl Methylcellulose ◽  
Peel Strength ◽  
Elongation At Break ◽  
Zingiber Cassumunar

Recently, Thai herbs are widely used as medicine to treat some illnesses. Zingiber cassumunar Roxb., known by the Thai name “Plai”, is a popular anti-inflammatory, antispasmodic herbal body and muscle treatment. This research aimed to prepare herbal patches that incorporated the 3 g of crude Z. cassumunar oil. The herbal patches made from different polymer blends were 2 g of 3.5%w/v chitosan and 5 g of 20%w/v hydroxypropyl methylcellulose (HPMC), or 2 g of 3.5%w/v chitosan and 5 g of 20%w/v polyvinyl alcohol (PVA) using 2 g of glycerin as a plasticizer. They were prepared by mixing all ingredients in a beaker and produced by solvent casting method in hot air oven at 70±2oC. The completed herbal patches were evaluated for their mechanical properties including Young’s modulus, ultimate tensile strength, elongation at break, T-peel strength, and tack adhesion. The thickness of blank and herbal patches was 0.263-0.282 mm and 0.269-0.275 mm, respectively. Young’s modulus, ultimate tensile strength, elongation at break, T-peel strength, and tack adhesion were 104.73-142.71 MPa, 87.92-93.28 MPa, 154.39-174.98 %, 3.43-4.88 MPa, and 5.29-7.02 MPa, respectively, for blank patches, and 116.83-147.28 MPa, 89.49-100.47 MPa, 133.78-159.27 %, 2.01-3.98 MPa, and 4.03-5.19 MPa, respectively, for herbal patches. We prepared herbal blended patches made from chitosan/PVA or chitosan/HPMC polymer matrix blends incorporating the crude Z. cassumunar oil. They had good mechanical properties that might be developed for herbal medicinal application.

Impact of Process Parameters on the Tensile Properties of DLP Additively Manufactured ELAST-BLK 10 UV-Curable Elastomer

2021 ◽  
Author(s):  
Asma Ul Hosna Meem ◽  
Kyle Rudolph ◽  
Allyson Cox ◽  
Austin Andwan ◽  
Timothy Osborn ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Elastic Modulus ◽  
Ultimate Tensile Strength ◽  
Tensile Properties ◽  
Process Parameters ◽  
Uv Light ◽  
Uv Curable ◽  
Build Orientation ◽  
Static Tensile ◽  
The Impact

Abstract Digital light processing (DLP) is an emerging vatphotopolymerization-based 3D-printing technology where full layers of photosensitive resin are irradiated and cured with projected ultraviolet (UV) light to create a three-dimensional part layer-by-layer. Recent breakthroughs in polymer chemistry have led to a growing number of UV-curable elastomeric photoresins developed exclusively for vat photopolymerization additive manufacturing (AM). Coupled with the practical manufacturing advantages of DLP AM (e.g., industry-leading print speeds and sub-micron-level print resolution), these novel elastomeric photoresins are compelling candidates for emerging applications requiring extreme flexibility, stretchability, conformability, and mechanically-tunable stiffness (e.g., soft robotic actuators and stretchable electronics). To advance the role of DLP AM in these novel and promising technological spaces, a fundamental understanding of the impact of DLP manufacturing process parameters on mechanical properties is requisite. This paper highlights our recent efforts to explore the process-property relationship for ELAST-BLK 10, a new commercially-available UV-curable elastomer for DLP AM. A full factorial design of experiments is used to investigate the effect of build orientation and layer thickness on the quasi-static tensile properties (i.e., small-strain elastic modulus, ultimate tensile strength, and elongation at fracture) of ELAST-BLK 10. Statistical results, based on a general linear model via ANOVA methods, indicate that specimens with a flat build orientation exhibit the highest elastic modulus, ultimate tensile strength, and elongation at fracture, likely due to a larger surface area that enhances crosslink density during the curing process. Several popular hyperelastic constitutive models (e.g., Mooney-Rivlin, Yeoh, and Gent) are calibrated to our quasi-static tensile data to facilitate component-level predictive analyses (e.g., finite-element modeling) of soft robotic actuators and other emerging soft-matter applications.

scholarly journals Microstructure and Mechanical Properties of Tempered Ausrolled Nanobainite Steel

Crystals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 573
Author(s):  
Jing Zhao ◽  
Dezheng Liu ◽  
Yan Li ◽  
Yongsheng Yang ◽  
Tiansheng Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Retained Austenite ◽  
Volume Fraction ◽  
Bainitic Ferrite ◽  
Energy Yield ◽  
Partial Recovery ◽  
Fracture Appearance ◽  
The Impact

The microstructures and mechanical properties of ausrolled nanobainite steel, after being tempered at temperatures in the range of 200−400 °C, were investigated in this study. After being tempered, bainitic ferrite is coarsened and the volume fraction of retained austenite is reduced. The hardness and ultimate tensile strength decrease sharply. The impact energy, yield strength, and elongation increase with elevated tempered temperature at 200–300 °C but decrease with elevated tempered temperature when the samples are tempered at 350 °C and 400 °C. The fracture appearance of all the samples after impact tests is a brittle fracture. The variation of the mechanical properties may be due to partial recovery and recrystallization.

Comparison of Mechanical and Frictional Properties of PTFE Matrix Composites Reinforced by Different Fibers and Graphite

2013 ◽  
Vol 575-576 ◽  
pp. 203-208
Author(s):  
Hong Xing Xu ◽  
Xin Hua Yuan ◽  
En Bo Zhu ◽  
Shuang Lian Li ◽  
Ling Chen ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Tribological Properties ◽  
Polyphenylene Sulfide ◽  
Matrix Composites ◽  
Load Bearing Capacity ◽  
Elongation At Break ◽  
Frictional Properties ◽  
Mass Fractions ◽  
The Impact

The polytetrafluoroethylene (PTFE) matrix composites which filled with polyphenylene sulfide (PPS) fiber, poly-p-phenelenferephthalamide (PPTA) fibre or glass fiber (GF)) and graphite at various mass fractions were prepared by the processes of mechanical blending, compression molding and sintering. The mechanical properties of the composites, such as tensile strength, impact strength and hardness were investigated. The results show that tensile strength and elongation at break markedly decrease but elasticity increases by filling with fibers. Impact strength decreases by filling with PPS and GF, and the composite displays brittle characteristic. However, the impact strength rapidly increases by filling with PPTA fiber. Hardness increases with the fibers content increases, and decreases with graphite content increases. Filling graphite into PTFE has light effect on the impact and tensile strength of composites. The tribological properties of the composites were investigated on M-2000 wear tester at dry friction condition. The wear mechanism was also discussed and the wear surfaces were examined by SEM. The result indicates that fibers which diffused in PTFE matrix wind with PTFE molecule chain, and then form grid structure. The load-bearing capacity of composites can be obviously enhanced and the trend of block fragmentations slide is inhibited, so that the tribological properties are improved markedly.

Multiple Reprocessing of Gear Using Recycled Polypropylene

2014 ◽  
Vol 660 ◽  
pp. 204-208
Author(s):  
Nik Mizamzul Mehat ◽  
Amirul Aliff Jamaludin ◽  
Shahrul Kamaruddin
Keyword(s):  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Tensile Properties ◽  
Spur Gear ◽  
Spur Gears ◽  
Elongation At Break ◽  
Recycled Polypropylene ◽  
Gear Manufacturing ◽  
Multiple Processing ◽  
Satisfactory Quality

The reprocessing ability of recycled polypropylene (PP) has been investigated to evaluate the recycling feasibility in spur gear production. Up to 15 reprocessing cycles have been performed by injection moulding, and the effects on tensile properties including ultimate tensile strength, Young’s modulus and elongation at break have been studied. Results revealed that reprocessing ability of recycled PP spur gears could yield satisfactory quality as attractive as that corresponding to the virgin PP spur gear. The recycled PP gears resulted in more 10% variation in tensile properties during multiple processing. This effort might be a contribution to convince the industry to apply recycling of PP by means of multiple reprocessing in gear manufacturing.

scholarly journals Effects of Vehicle-Induced Vibrations on the Tensile Performance of Early Age PVA-ECC

2019 ◽  
Author(s):  
Xiaodong Zhang ◽  
Shuguang Liu ◽  
Changwang Yan ◽  
Xiaoxiao Wang ◽  
Huiwen Wang
Keyword(s):  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Correlation Analysis ◽  
Uniaxial Tensile ◽  
Uniaxial Tensile Test ◽  
Early Age ◽  
Grey Correlation ◽  
Tensile Performance ◽  
Grey Correlation Analysis ◽  
The Impact

The purpose of this study was to conduct laboratory test programs on how much vehicle-induced vibrations during early ages affected the tensile performance of Polyvinyl alcohol-engineering cementitious composites (PVA-ECC). A self-improved device was used to simulate the vehicle-induced vibrations, and after vibrating with the designed variables, both a uniaxial tensile test and a grey correlation analysis were performed. The results indicated that: the effects of vehicle-induced vibrations on the tensile performance of early age PVA-ECC were significant, and they generally tended to be negative in this investigation. In particular, for all of the vibrated PVA-ECC specimens, the most negative age when vibrated occurred during the period between the initial set and the final set. In this period, the effects of the vibration duration on the tensile performance of the PVA-ECC tended to be negative overall, but the impact trend and the degree varied for the corresponding lengths of duration and levels of frequency. The cracking strength was the most sensitive to the variables in this investigation, and then it followed the ultimate tensile strength and strain. The grey correlation analysis was applicable in analyzing the effects of vehicle-induced vibrations on the tensile performance of early age PVA-ECC.

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