Effect of Inorganic Salts on Pore Structure of Cement Paste

2009 ◽  
Vol 405-406 ◽  
pp. 378-383
Author(s):  
Wen Cui Yang ◽  
Yong Ge ◽  
Jie Yuan ◽  
Bao Sheng Zhang
Keyword(s):  
Pore Structure ◽  
Cement Paste ◽  
Mercury Intrusion Porosimetry ◽  
Cold Weather ◽  
Inorganic Salts ◽  
Early Age ◽  
Concrete Durability ◽  
Mercury Intrusion ◽  
Concrete Shrinkage ◽  
Concrete Property

Inorganic salts are important admixtures usually used in cold weather concrete. As research basic of influence of salts on concrete durability, effects of inorganic salts on pore structure of cement paste were studied in this paper, and possible implications of concrete property with pore structure was also analyzed. Pore structure of paste added CaCl2, NaCl, Na2SO4, NaNO2, Ca(NO3)2 and Ca(NO2)2 curing for 3 days and 28 days were tested through mercury intrusion porosimetry (MIP). The results showed that no matter 0.3 or 0.5 water-cement ratio, the pores whose diameter <50nm in paste with salts increased at 3 days, which was harmful for the control of concrete shrinkage and cracking at early age. Adding Ca (NO3)2 increased coarse pores (>200nm) of paste at 3 days, but these coarse pores turned into fine pores and reduced significantly at 28 days. Adding NaCl and Na2SO4 into cement paste raised coarse pores with size>1000nm at 3 days and 28days, which were harmful for the pore structure.

Modelling Pore Structure of Cement Based Material According to Continuous Network System

2014 ◽  
Vol 578-579 ◽  
pp. 1531-1537
Author(s):  
Sung In Hong ◽  
Joon Woo Park ◽  
Young Hee Jung ◽  
Ki Yong Ann
Keyword(s):  
Pore Structure ◽  
Cement Paste ◽  
Mercury Intrusion Porosimetry ◽  
Cement Matrix ◽  
Network System ◽  
Air Voids ◽  
Mercury Intrusion ◽  
Entrapped Air ◽  
Entrained Air

In this study, a modified pore structure of cement based material with respect to a path for ingressive ions was established. Of pores in a concrete, gel pores and other entrapped air voids were excluded from modelling the pore structure as no interests are given due to the ions immobilization of cement paste media. To setup the pore structure, the linear traverse method (LTM) was used to distribute air voids along the traverse line in a hexahedron cement paste structure, followed by including entrained air voids to fill up the least space of the cement matrix and making a network of the air voids through capillary pores at the variation in the diameters. Then the mercury intrusion porosimetry (MIP) was used to iteratively approach an accordance rate with calculated one from the above way to get into appropriate convergence value. As a result, for the OPC specimen the developed model shows a somewhat relevant value of 42.4 % of the accordance rate compared to empirical one and 64.24 of the ratio of ionic path to original distance within a concrete.

Damage to the Pore Structure of Hardened Portland Cement Paste by Mercury Intrusion

2005 ◽  
Vol 80 (9) ◽  
pp. 2454-2458 ◽  
Author(s):  
Rudolph A. Olson ◽  
Christopher M. Neubauer ◽  
Hamlin M. Jennings
Keyword(s):  
Portland Cement ◽  
Pore Structure ◽  
Cement Paste ◽  
Mercury Intrusion ◽  
Portland Cement Paste

scholarly journals Ink-bottle Effect and Pore Size Distribution of Cementitious Materials Identified by Pressurization–Depressurization Cycling Mercury Intrusion Porosimetry

Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1454 ◽  
Author(s):  
Yong Zhang ◽  
Bin Yang ◽  
Zhengxian Yang ◽  
Guang Ye
Keyword(s):  
Pore Structure ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Mercury Intrusion Porosimetry ◽  
Cementitious Materials ◽  
Limestone Powder ◽  
Accurate Estimation ◽  
Mercury Intrusion ◽  
Pore Size Distributions

Capturing the long-term performance of concrete must be underpinned by a detailed understanding of the pore structure. Mercury intrusion porosimetry (MIP) is a widely used technique for pore structure characterization. However, it has been proven inappropriate to measure the pore size distribution of cementitious materials due to the ink-bottle effect. MIP with cyclic pressurization–depressurization can overcome the ink-bottle effect and enables a distinction between large (ink-bottle) pores and small (throat) pores. In this paper, pressurization–depressurization cycling mercury intrusion porosimetry (PDC-MIP) is adopted to characterize the pore structure in a range of cementitious pastes cured from 28 to 370 days. The results indicate that PDC-MIP provides a more accurate estimation of the pore size distribution in cementitious pastes than the standard MIP. Bimodal pore size distributions can be obtained by performing PDC-MIP measurements on cementitious pastes, regardless of the age. Water–binder ratio, fly ash and limestone powder have considerable influences on the formation of capillary pores ranging from 0.01 to 0.5 µm.

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