Improving the Performance of High Temperature Piezopolymers for Magnetoelectric Applications

2013 ◽  
Vol 543 ◽  
pp. 439-442 ◽  
Author(s):  
Jon Gutiérrez ◽  
Andoni Lasheras ◽  
Jose Manuel Barandiaran ◽  
Jose Luis Vilas ◽  
Alberto Maceiras ◽  
...  

Piezoelectricity in amorphous polymers is mainly due to the orientation polarization of the molecular dipoles. Aromatic polyimides are high-performance polymeric materials possessing large molecular dipoles. We already reported good magnetoelectric performance of laminate composites with Vitrovac 4040®as magnetostrictive component and the 2,6(b-CN)APB/ODPA (poli 2,6) polyimide as the piezoelectric. Although the piezoelectric response of this polyimide is good, its mechanical properties can be improved. To combine the best mechanical and piezoelectric response in the same polymer, copolyimides have been synthesized by reaction of the 4,4-oxydiphtalic anhydride (ODPA) with a mixture of 1,3-Bis-2-cyano-3-(3-aminophenoxy) phenoxybenzene (diamine 2CN) and 1,3-Bis (3-aminophenoxy) benzene (diamine 0CN). We present the piezoelectric, mechanical and ME performance of laminate composites of these copolyimides.

2016 ◽  
Vol 711 ◽  
pp. 157-162 ◽  
Author(s):  
David Citek ◽  
Milan Rydval ◽  
Stanislav Rehacek ◽  
Jiří Kolísko

The Ultra High Performance Concrete (UHPC) is a very promising material suitable for application in special structures. However, the knowledge of performance of this relatively new material is rather limited. The exceptional mechanical properties of UHPC allow for a modification of the design rules, which are applicable in ordinary or high strength concrete. This paper deals in more detail with impact of thermal stress on bond properties between prestressing strands and UHPC and an influence of high temperature to final material properties of different UHPC mixtures. Specimens in the first experimental part were subjected to the cycling freeze-thaw testing. The relationship between bond behavior of both type of material (UHPC and ordinary concrete) and effect of cycling freeze-thaw tests was investigated. The second part of experimental work was focused on mechanical properties of UHPC exposure to the high temperature (Tmax = 200°C to Tmax = 1000°C). Tested mechanical properties were compressive and flexural strengths, the fracture properties will be presented in the next paper. The obtained experimental data serve as a basis for further systematic experimental verification and more accurate information about the significantly higher material properties of UHP(FR)C and its behavior in extreme conditions.


2013 ◽  
Vol 368-370 ◽  
pp. 1052-1055
Author(s):  
Seung Jo Lee ◽  
Jung Min Park

The aim of the study is to improve the understanding of the influence of reinforcing fiber types on the mechanical properties of high performance concretes (HPC) subjected to high temperature. The mechanical properties measured include residual compressive strength, weight reduction ratio, outward appearance property, and failure mode. Nylon, polypropylene, and steel fiber were added to enhance mechanical property of the concretes. After exposure to high temperatures ranged from 100 to 800°C, mechanical properties of fiber-toughened HPC were investigated. For HPC, although residual compressive strength was decreased by exposure to high temperature over 500°C, weight reduction ratio was significantly higher than that before heating temperature.


2010 ◽  
Vol 146-147 ◽  
pp. 666-669 ◽  
Author(s):  
Xin E Li

Basalt filament yarn is a new type of high-performance fibers, which is formed by the direct drawing of basalt rock at high temperatures. It is a natural and environmentally friendly textile material. This paper mainly focuses on thermal resistance research of basalt filament yarn that is heated at various temperatures. The change of color and appearance of heated basalt filament yarn was described. The mechanical properties of heated basalt filament yarn were tested. The results showed that although the mechanical properties of basalt filament yarn decreased with the temperature rising, still remained high tensile strength within a certain temperature range. Basalt filament yarn possess higher tenacity under 325°C. Basalt filament yarns still possess certain tenacity when they were placed at 500°C condition. So basalt filament yarn can be used as heat-resistant materials, such as filtration materials for high-temperature gas and liquid, fire-proof fabrics and so on.


2011 ◽  
Vol 45 (24) ◽  
pp. 2587-2592 ◽  
Author(s):  
Jian Yang ◽  
Jiachun Zhong ◽  
Rui Zhao ◽  
Xiaobo Liu

The continuous glass fiber-reinforced polyarylene ether nitriles (PEN) composites were successfully fabricated from PEN pre-impregnated glass fabric mates and PEN films using a film-stacking method. The work involved heat treatment for crosslinking reaction of PEN, and so it provided an interesting comparison of how heat treatment can influence the properties of composites. Detailed study on heat treatments for crosslinking reaction of PEN in the catalysis of the ZnCl2 at high temperature promoting the thermal and mechanical properties of composites were also investigated. The results showed that the thermal and mechanical properties of composites were enhanced by heat treatment, which is due to the fact that PEN resins could be crosslinked by the catalytic action of ZnCl2 at high temperature and formed triazine rings with a more thermally stable structure.


2012 ◽  
Vol 226-228 ◽  
pp. 1709-1713
Author(s):  
Lan Yan ◽  
Y.M. Xing ◽  
Ji Jun Li

This paper investigated the high temperature mechanical properties of the hybrid fiber reinforced high performance concrete (HFHPC) and normal concrete (NC) .After being subjected to different elevated heating temperatures, two kinds of concretes have been tested for the compressive strength, splitting tensile strength and flexural strength of test specimen at room temperature and 200 °C,400 °C,600 °C,800 °C.Microstructure changes of concrete were also observed by using Scanning Electron Microscopy (SEM) after high temperature. The results show that the hybrid fiber can significantly increase mechanical properties of the concrete at room temperature and high temperature. SEM and XRD analysis shows that there is a permeable diffusion layer in the steel fiber surface because of solid state reaction in the Interfacial Transition Zone of steel fiber and concrete. This permeable diffusion layer is white, bright, serrated and mainly consist of FeSi2 and the complex hydrated calcium silicate. The compounds of this layer change the Interfacial Transition Zone structure, enhance bonding capacity of the steel fiber and matrix, and increase the high temperature mechanical properties of concrete.


2021 ◽  
Vol 27 (2) ◽  
pp. 429-451
Author(s):  
Chrysoula Pandelidi ◽  
Tobias Maconachie ◽  
Stuart Bateman ◽  
Ingomar Kelbassa ◽  
Sebastian Piegert ◽  
...  

Purpose Fused deposition modelling (FDM) is increasingly being explored as a commercial fabrication method due to its ability to produce net or near-net shape parts directly from a computer-aided design model. Other benefits of technology compared to conventional manufacturing include lower cost for short runs, reduced product lead times and rapid product design. High-performance polymers such as polyetherimide, have the potential for FDM fabrication and their high-temperature capabilities provide the potential of expanding the applications of FDM parts in automotive and aerospace industries. However, their relatively high glass transition temperature (215 °C) causes challenges during manufacturing due to the requirement of high-temperature build chambers and controlled cooling rates. The purpose of this study is to investigate the mechanical properties of ULTEM 1010, an unfilled polyetherimide grade. Design/methodology/approach In this research, mechanical properties were evaluated through tensile and flexural tests. Analysis of variance was used to determine the significance of process parameters to the mechanical properties of the specimens, their main effects and interactions. The fractured surfaces were analysed by scanning electron microscopy and optical microscopy and porosity was assessed by X-ray microcomputed tomography. Findings A range of mean tensile and flexural strengths, 60–94 MPa and 62–151 MPa, respectively, were obtained highlighting the dependence of performance on process parameters and their interactions. The specimens were found to fracture in a brittle manner. The porosity of tensile samples was measured between 0.18% and 1.09% and that of flexural samples between 0.14% and 1.24% depending on the process parameters. The percentage porosity was found to not directly correlate with mechanical performance, rather the location of those pores in the sample. Originality/value This analysis quantifies the significance of the effect of each of the examined process parameters has on the mechanical performance of FDM-fabricated specimens. Further, it provides a better understanding of the effect process parameters and their interactions have on the mechanical properties and porosity of FDM-fabricated polyetherimide specimens. Additionally, the fracture surface of the tested specimens is qualitatively assessed.


1989 ◽  
Vol 153 ◽  
Author(s):  
T. H. Yoon ◽  
C. A. Arnold ◽  
J. E. McGrath

Polyimides are attractive candidates for advanced electronic and space applications due to their high performance thermal and mechanical properties. However, the typical intractability and insolubility of polyimides has been a disadvantage. Utilization of the soluble intermediate amic acid can, to some extent, circumvent this problem. However, drawbacks to this approach include the hydrolytic instability of the amic acid and the liberation of water during its subsequent thermal cyclization. Residual stress build-up at the imide-substrate interface may occur due to swelling and drying cycles caused by the loss of water and solvent. In addition, the liberation of volatiles from a polyimide adhesive or coating can lead to the creation of voids which may significantly detract from mechanical properties. Polymeric adhesives must flow in order to provide good wetting of adherend surfaces and consolidation of the bond components. Thus, fully imidized, melt and solution processable, high Tg aromatic polyimides are of great interest.


2008 ◽  
Vol 368-372 ◽  
pp. 849-851
Author(s):  
Chang Cheng Zhou ◽  
Chang Rui Zhang ◽  
Hai Feng Hu ◽  
Yu Di Zhang ◽  
Zhi Yi Wang

2D-C/SiC composites with high performance were prepared at temperatures as low as 900 °C. The flexural strength of the composites reached 329.61MPa, the same level as the composites prepared at 1200°C, and shear strength and fracture toughness were 32.14MPa and 14.65MPa·m1/2, respectively. The microstructure and mechanical properties of the composites after heat-treatment at 1600°C were also investigated to determine the potential applications at high temperature.


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